IL54540A - Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cells - Google Patents
Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cellsInfo
- Publication number
- IL54540A IL54540A IL54540A IL5454078A IL54540A IL 54540 A IL54540 A IL 54540A IL 54540 A IL54540 A IL 54540A IL 5454078 A IL5454078 A IL 5454078A IL 54540 A IL54540 A IL 54540A
- Authority
- IL
- Israel
- Prior art keywords
- ion exchange
- separators
- base layer
- polymer containing
- fluorinated ion
- Prior art date
Links
- 229920003303 ion-exchange polymer Polymers 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F16/14—Monomers containing only one unsaturated aliphatic radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Laminated Bodies (AREA)
Abstract
Fluorinated ion exchange polymers which have pendant side chains which contain groups wherein W is F or CF3, and R is an inonizable group, or which have such pendant side chains and also pendant side chains which contain sulfonyl groups, when used in the form of membranes to separate the anode and cathode compartments of an electrolysis cell, permit operation at high current efficiency. They can be made by copolymerization of a mixture of monomers, one of which is a vinyl monomer which contains the indicated carboxylic funtional group.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78972577A | 1977-04-20 | 1977-04-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL54540A0 IL54540A0 (en) | 1978-07-31 |
| IL54540A true IL54540A (en) | 1981-09-13 |
Family
ID=25148505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL54540A IL54540A (en) | 1977-04-20 | 1978-04-19 | Laminar structures having a base layer of a fluorinated ion exchange polymer containing carboxylic groups and their use as separators in chloralkali electrolytic cells |
Country Status (15)
| Country | Link |
|---|---|
| JP (2) | JPS53132089A (en) |
| AU (2) | AU525335B2 (en) |
| BE (1) | BE866121A (en) |
| BR (1) | BR7802433A (en) |
| CA (1) | CA1133425A (en) |
| DE (1) | DE2817344A1 (en) |
| FR (1) | FR2388012A1 (en) |
| GB (1) | GB1604102A (en) |
| IL (1) | IL54540A (en) |
| IT (1) | IT1094102B (en) |
| MX (1) | MX151031A (en) |
| NL (1) | NL7804221A (en) |
| NZ (1) | NZ187023A (en) |
| SU (1) | SU1165239A3 (en) |
| ZA (1) | ZA782225B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4329435A (en) * | 1979-05-31 | 1982-05-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Novel fluorinated copolymer with tridihydro fluorosulfonyl fluoride pendant groups and preparation thereof |
| US4329434A (en) | 1979-05-31 | 1982-05-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Novel fluorinated cation exchange membrane and process for producing the same |
| DE3050931C2 (en) * | 1979-05-31 | 1994-06-09 | Asahi Chemical Ind | Fluorinated carboxylic acid derivatives and process for their preparation |
| DE3036066A1 (en) * | 1980-09-25 | 1982-05-06 | Hoechst Ag, 6000 Frankfurt | Bonding electrode to fluorine contg. copolymer electrolysis membrane - by applying electrode powder to membrane and pressing opt. with heating |
| JPS5792028A (en) * | 1980-11-29 | 1982-06-08 | Asahi Chem Ind Co Ltd | Fluorocarbon cation exchange membrane |
| JPS58189210A (en) * | 1982-04-30 | 1983-11-04 | Daikin Ind Ltd | Production of tetrafluoroethylene/fluorinated alkyl vinyl ether copolymer |
| US4954256A (en) * | 1989-05-15 | 1990-09-04 | Pall Corporation | Hydrophobic membranes |
| US5595676A (en) * | 1992-07-30 | 1997-01-21 | Imperial Chemical Industries Plc | Fluorinated polymers |
| JP2003246906A (en) * | 2002-02-25 | 2003-09-05 | Asahi Kasei Corp | Fluorine copolymer-containing composition |
| US7071271B2 (en) * | 2003-10-30 | 2006-07-04 | 3M Innovative Properties Company | Aqueous emulsion polymerization of functionalized fluoromonomers |
| RU2267498C1 (en) * | 2004-07-20 | 2006-01-10 | Открытое акционерное общество "Пластполимер" (ОАО "Пластполимер") | Linear statistical tetrafluoroethylene terpolymer with functional perfluorinated co-monomers and method for its preparing |
| DK2376541T3 (en) * | 2008-12-11 | 2013-01-28 | Solvay Specialty Polymers It | Purification of fluorine ionomer compositions |
| RU2412948C1 (en) * | 2009-09-15 | 2011-02-27 | Федеральное государственное унитарное предприятие "Российский научный центр "Прикладная химия" | Method of producing perfluorinated copolymer with sulfo-groups |
| JP5799926B2 (en) * | 2012-09-27 | 2015-10-28 | 旭硝子株式会社 | Method for producing fluorine-containing copolymer |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3282875A (en) * | 1964-07-22 | 1966-11-01 | Du Pont | Fluorocarbon vinyl ether polymers |
| FR1527816A (en) * | 1966-02-16 | 1968-06-07 | Du Pont | Perfluorinated alkyl-vinyl ethers bearing substituents, preparation of these ethers by pyrolysis of the corresponding salts, and their use as components of copolymers |
| US3784399A (en) * | 1971-09-08 | 1974-01-08 | Du Pont | Films of fluorinated polymer containing sulfonyl groups with one surface in the sulfonamide or sulfonamide salt form and a process for preparing such |
| US3849243A (en) * | 1971-11-08 | 1974-11-19 | Du Pont | Laminates of support material and fluorinated polymer containing pendant side chains containing sulfonyl groups |
| AU464313B2 (en) * | 1971-12-27 | 1975-08-21 | Hooker Chemicals And Plastics Coup | Electrolysis method and apparatus |
| JPS551351B2 (en) * | 1974-03-07 | 1980-01-12 | ||
| JPS5224176A (en) * | 1975-07-09 | 1977-02-23 | Asahi Chem Ind Co Ltd | Cathion exchange membrane |
| JPS5223192A (en) * | 1975-08-15 | 1977-02-21 | Asahi Glass Co Ltd | Preparation of improved fluoropolymer bearing cation exchange groups |
| JPS5228587A (en) * | 1975-08-29 | 1977-03-03 | Asahi Glass Co Ltd | Method for manufacturing an improved fluoropolymer having cation excha nge groups |
| GB1518387A (en) * | 1975-08-29 | 1978-07-19 | Asahi Glass Co Ltd | Fluorinated cation exchange membrane and use thereof in electrolysis of an alkali metal halide |
| JPS5228586A (en) * | 1975-08-29 | 1977-03-03 | Asahi Glass Co Ltd | Method for manufacturing an improved fluoropolymer having cation excha nge groups |
| JPS52120999A (en) * | 1976-04-05 | 1977-10-11 | Asahi Chem Ind Co Ltd | Electrolysis of alkali metal halides |
-
1978
- 1978-03-15 FR FR7807444A patent/FR2388012A1/en active Pending
- 1978-04-17 AU AU35164/78A patent/AU525335B2/en not_active Ceased
- 1978-04-18 CA CA301,559A patent/CA1133425A/en not_active Expired
- 1978-04-18 JP JP4490778A patent/JPS53132089A/en active Granted
- 1978-04-19 NZ NZ187023A patent/NZ187023A/en unknown
- 1978-04-19 GB GB15537/78A patent/GB1604102A/en not_active Expired
- 1978-04-19 BE BE186898A patent/BE866121A/en not_active IP Right Cessation
- 1978-04-19 MX MX173172A patent/MX151031A/en unknown
- 1978-04-19 IL IL54540A patent/IL54540A/en unknown
- 1978-04-19 BR BR787802433A patent/BR7802433A/en unknown
- 1978-04-19 SU SU782605603A patent/SU1165239A3/en active
- 1978-04-19 ZA ZA00782225A patent/ZA782225B/en unknown
- 1978-04-19 IT IT22494/78A patent/IT1094102B/en active
- 1978-04-20 DE DE19782817344 patent/DE2817344A1/en active Granted
- 1978-04-20 NL NL7804221A patent/NL7804221A/en not_active Application Discontinuation
-
1983
- 1983-11-16 JP JP58214233A patent/JPS59211583A/en active Pending
-
1988
- 1988-03-11 AU AU13048/88A patent/AU1304888A/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BR7802433A (en) | 1979-01-16 |
| ZA782225B (en) | 1979-04-25 |
| AU1304888A (en) | 1988-06-16 |
| DE2817344A1 (en) | 1978-10-26 |
| AU3516478A (en) | 1979-10-25 |
| NZ187023A (en) | 1980-11-28 |
| JPS6356257B2 (en) | 1988-11-07 |
| IL54540A0 (en) | 1978-07-31 |
| FR2388012A1 (en) | 1978-11-17 |
| JPS53132089A (en) | 1978-11-17 |
| IT7822494A0 (en) | 1978-04-19 |
| SU1165239A3 (en) | 1985-06-30 |
| MX151031A (en) | 1984-09-12 |
| NL7804221A (en) | 1978-10-24 |
| GB1604102A (en) | 1981-12-02 |
| AU525335B2 (en) | 1982-11-04 |
| CA1133425A (en) | 1982-10-12 |
| JPS59211583A (en) | 1984-11-30 |
| BE866121A (en) | 1978-10-19 |
| IT1094102B (en) | 1985-07-26 |
| DE2817344C2 (en) | 1990-11-15 |
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