IL33093A - Semi-permeable polyamide membrane for use in reverse osmosis - Google Patents
Semi-permeable polyamide membrane for use in reverse osmosisInfo
- Publication number
- IL33093A IL33093A IL33093A IL3309369A IL33093A IL 33093 A IL33093 A IL 33093A IL 33093 A IL33093 A IL 33093A IL 3309369 A IL3309369 A IL 3309369A IL 33093 A IL33093 A IL 33093A
- Authority
- IL
- Israel
- Prior art keywords
- membrane
- reverse osmosis
- carbon
- semi
- solution
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title claims description 26
- 239000004952 Polyamide Substances 0.000 title claims description 6
- 229920002647 polyamide Polymers 0.000 title claims description 6
- 238000001223 reverse osmosis Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- 238000010612 desalination reaction Methods 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 11
- 239000002253 acid Substances 0.000 description 8
- 125000003277 amino group Chemical group 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000006068 polycondensation reaction Methods 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 2
- VJEZYZLITKUTFH-UHFFFAOYSA-N 2-(hydrazinecarbonyl)benzoic acid Chemical compound NNC(=O)C1=CC=CC=C1C(O)=O VJEZYZLITKUTFH-UHFFFAOYSA-N 0.000 description 1
- NYQDCVLCJXRDSK-UHFFFAOYSA-N Bromofos Chemical compound COP(=S)(OC)OC1=CC(Cl)=C(Br)C=C1Cl NYQDCVLCJXRDSK-UHFFFAOYSA-N 0.000 description 1
- 238000012696 Interfacial polycondensation Methods 0.000 description 1
- MPCRDALPQLDDFX-UHFFFAOYSA-L Magnesium perchlorate Chemical compound [Mg+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O MPCRDALPQLDDFX-UHFFFAOYSA-L 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- FYXKZNLBZKRYSS-UHFFFAOYSA-N benzene-1,2-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC=C1C(Cl)=O FYXKZNLBZKRYSS-UHFFFAOYSA-N 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- DTLKWZKUAHYQGX-UHFFFAOYSA-N polyanine Natural products CC1CCC2(NC1)OC3CC4C5CCC6CC(CCC6(C)C5CCC4(C)C3C2C)OC7OC(CO)C(O)C(OC8OCC(O)C(O)C8O)C7OC9OCC(O)C(O)C9O DTLKWZKUAHYQGX-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 125000006239 protecting group Chemical group 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/56—Polyamides, e.g. polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR168446 | 1968-10-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL33093A0 IL33093A0 (en) | 1969-11-30 |
| IL33093A true IL33093A (en) | 1972-09-28 |
Family
ID=8655196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL33093A IL33093A (en) | 1968-10-02 | 1969-09-29 | Semi-permeable polyamide membrane for use in reverse osmosis |
Country Status (11)
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2193634A1 (en) * | 1972-07-20 | 1974-02-22 | Du Pont | Polyimide semi-permeable membranes |
| US3822202A (en) * | 1972-07-20 | 1974-07-02 | Du Pont | Heat treatment of membranes of selected polyimides,polyesters and polyamides |
| US3993625A (en) * | 1973-05-28 | 1976-11-23 | Toray Industries, Inc. | Permselective polymeric membranes of organic polyamide or polyhydrazide |
| US3951789A (en) * | 1973-10-11 | 1976-04-20 | Allied Chemical Corporation | Novel high diffusivity membranes |
| DE2418996A1 (de) * | 1974-04-19 | 1975-10-30 | Bayer Ag | Asymmetrische, semipermeable membranen aus polybenz-1,3-oxazindionen-2,4 |
| DE2602493A1 (de) * | 1975-01-27 | 1976-07-29 | Ramot Plastics | Verfahren zur entfernung von harnstoff aus waessrigen loesungen |
| JPS5193786A (en) * | 1975-02-15 | 1976-08-17 | Makurokagatano chukuseni | |
| GB1586167A (en) * | 1976-09-24 | 1981-03-18 | Bfg Glassgroup | Moulding solid layers |
| DE2704600C3 (de) * | 1977-02-04 | 1988-05-26 | Hoechst Ag, 6230 Frankfurt | Permselektive, asymmetrische Hämofiltrationsmembran mit heteroporöser Struktur auf Basis von Polyamid |
| JPS5443882A (en) * | 1977-09-14 | 1979-04-06 | Nippon Zeon Co Ltd | Preparation of semipermeable membrane |
| FI913567A7 (fi) * | 1989-01-31 | 1991-07-25 | Du Pont | Huokoisia substraatteja, joissa amiiniryhmien tiheys on suuri |
| US5352273A (en) * | 1993-04-14 | 1994-10-04 | E. I. Du Pont De Nemours And Company | Alkyl substituted aromatic polyester gas separation membranes |
| US8181794B2 (en) | 2009-08-24 | 2012-05-22 | Oasys Water, Inc. | Forward osmosis membranes |
| WO2011069050A1 (en) | 2009-12-03 | 2011-06-09 | Yale University | High flux thin-film composite forward osmosis and pressure-retarded osmosis membranes |
| KR20130101533A (ko) | 2010-10-04 | 2013-09-13 | 오아시스 워터, 인크. | 박막 필름 복합 열 교환기 |
| CN103328081B (zh) | 2011-01-24 | 2015-08-19 | 陶氏环球技术有限责任公司 | 复合聚酰胺膜 |
| JP6054968B2 (ja) | 2011-08-31 | 2016-12-27 | ダウ グローバル テクノロジーズ エルエルシー | アミン−反応性およびリン−含有官能基を含むモノマーから誘導された複合ポリアミド膜 |
| WO2013048764A1 (en) | 2011-09-29 | 2013-04-04 | Dow Global Technologies Llc | Method for preparing high purity mono-hydrolyzed acyl halide compound |
| US9073015B2 (en) | 2012-01-06 | 2015-07-07 | Dow Global Technologies Llc | Composite polyamide membrane |
| WO2014014664A1 (en) | 2012-07-19 | 2014-01-23 | Dow Global Technologies Llc | Composite polyamide membrane with increased carboxylic acid functionality |
| US10137418B2 (en) | 2013-01-14 | 2018-11-27 | Dow Global Technologies Llc | Composite polyamide membrane made via interfacial polymerization using a blend of non-polar solvents |
| CN104918688B (zh) | 2013-01-14 | 2016-12-14 | 陶氏环球技术有限责任公司 | 包含经取代苯甲酰胺单体的复合聚酰胺膜 |
| US9289729B2 (en) | 2013-03-16 | 2016-03-22 | Dow Global Technologies Llc | Composite polyamide membrane derived from carboxylic acid containing acyl halide monomer |
| US9051417B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | Method for solubilizing carboxylic acid-containing compound in hydrocarbon solvent |
| US9051227B2 (en) | 2013-03-16 | 2015-06-09 | Dow Global Technologies Llc | In-situ method for preparing hydrolyzed acyl halide compound |
| US9387442B2 (en) | 2013-05-03 | 2016-07-12 | Dow Global Technologies Llc | Composite polyamide membrane derived from an aliphatic acyclic tertiary amine compound |
| US9452391B1 (en) | 2013-12-02 | 2016-09-27 | Dow Global Technologies Llc | Composite polyamide membrane treated with dihyroxyaryl compounds and nitrous acid |
| WO2015084511A1 (en) | 2013-12-02 | 2015-06-11 | Dow Global Technologies Llc | Composite polyamide membrane post treated with nitrious acid |
| US9616392B2 (en) | 2014-01-09 | 2017-04-11 | Dow Global Technologies Llc | Composite polyamide membrane having high acid content and low azo content |
| KR102273550B1 (ko) | 2014-01-09 | 2021-07-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 아조 함량 및 높은 산 함량을 갖는 복합 폴리아미드 막 |
| ES2677994T3 (es) | 2014-01-09 | 2018-08-08 | Dow Global Technologies Llc | Membrana de poliamida de material compuesto con contenido azoico preferido |
| WO2015167759A1 (en) | 2014-04-28 | 2015-11-05 | Dow Global Technologies Llc | Composite polyamide membrane post-treated with nitrous acid |
| KR102359211B1 (ko) | 2014-05-14 | 2022-02-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 아질산으로 후처리된 복합 폴리아미드 막 |
-
1968
- 1968-10-02 FR FR168446A patent/FR1587787A/fr not_active Expired
-
1969
- 1969-09-02 BR BR212815/69A patent/BR6912815D0/pt unknown
- 1969-09-24 NL NL6914496A patent/NL6914496A/xx unknown
- 1969-09-29 IL IL33093A patent/IL33093A/en unknown
- 1969-09-30 US US862522A patent/US3686116A/en not_active Expired - Lifetime
- 1969-10-01 GB GB1227280D patent/GB1227280A/en not_active Expired
- 1969-10-01 BE BE739700D patent/BE739700A/xx unknown
- 1969-10-01 CH CH1478169A patent/CH511916A/fr not_active IP Right Cessation
- 1969-10-01 LU LU59552D patent/LU59552A1/xx unknown
- 1969-10-02 ES ES372085A patent/ES372085A1/es not_active Expired
- 1969-10-02 DE DE19691949847 patent/DE1949847A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| NL6914496A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-04-06 |
| GB1227280A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1971-04-07 |
| FR1587787A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-03-27 |
| DE1949847A1 (de) | 1970-04-09 |
| ES372085A1 (es) | 1971-09-01 |
| BR6912815D0 (pt) | 1973-01-09 |
| US3686116A (en) | 1972-08-22 |
| CH511916A (fr) | 1971-08-31 |
| LU59552A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-04-01 |
| IL33093A0 (en) | 1969-11-30 |
| BE739700A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-04-01 |
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