IL32928A - Cartridge-less moulded propellant charge - Google Patents
Cartridge-less moulded propellant chargeInfo
- Publication number
- IL32928A IL32928A IL32928A IL3292869A IL32928A IL 32928 A IL32928 A IL 32928A IL 32928 A IL32928 A IL 32928A IL 3292869 A IL3292869 A IL 3292869A IL 32928 A IL32928 A IL 32928A
- Authority
- IL
- Israel
- Prior art keywords
- cartridge
- moulded
- less
- propellant charge
- protective coating
- Prior art date
Links
- 239000003380 propellant Substances 0.000 title claims description 9
- 238000000465 moulding Methods 0.000 claims description 8
- 239000011241 protective layer Substances 0.000 claims description 5
- 238000010422 painting Methods 0.000 claims description 4
- 239000011253 protective coating Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000002360 explosive Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 239000000020 Nitrocellulose Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 238000011109 contamination Methods 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 238000007654 immersion Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920001220 nitrocellulos Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims 1
- 239000005062 Polybutadiene Substances 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- -1 e.g. Polymers 0.000 claims 1
- 239000011888 foil Substances 0.000 claims 1
- 238000003780 insertion Methods 0.000 claims 1
- 230000037431 insertion Effects 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 229920001004 polyvinyl nitrate Polymers 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004200 deflagration Methods 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- SNFOERUNNSHUGP-ZXZARUISSA-N erythrityl tetranitrate Chemical compound [O-][N+](=O)OC[C@@H](O[N+]([O-])=O)[C@@H](O[N+]([O-])=O)CO[N+]([O-])=O SNFOERUNNSHUGP-ZXZARUISSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000000479 mixture part Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/18—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component
- C06B45/20—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an organic explosive or an organic thermic component
- C06B45/22—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component the component base containing an organic explosive or an organic thermic component the coating containing an organic compound
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0083—Treatment of solid structures, e.g. for coating or impregnating with a modifier
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/18—Compositions or products which are defined by structure or arrangement of component of product comprising a coated component
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B5/00—Cartridge ammunition, e.g. separately-loaded propellant charges
- F42B5/02—Cartridges, i.e. cases with charge and missile
- F42B5/18—Caseless ammunition; Cartridges having combustible cases
- F42B5/192—Cartridge cases characterised by the material of the casing wall
- F42B5/196—Coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Portable Nailing Machines And Staplers (AREA)
- Paints Or Removers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
moulded propellant charge NOBEL 31074 The invention relates to a moulded propellant charge of an explosive which is or decomposes by deflagration without tending to such as olyvinyl erythritol tetranitrate or the or mixtures particularly for apparatus in commercial such as nail driving impact control quick break switches and the While such moulded propellant charges have great advantages owing to the absence of the conventional ridge they have the considerable disadvantage that the surface of the mouldings is unprotected and consequently so that the mouldings can catch fire or even be unintentionally owing to the high inflammability of the explosives of which they are Accordingly the storage and use of these mouldings require certain because of the absorptivity of the materials used and the substantially porous structure of the their unprotected surface tends to admit water or other liquids as well as such as in addition to the particularly careful handling of these moulded charges from the point of view of safety they must also be carefully manipulated in the course of their usually rough handling in practical It is the of the present invention to ate the above mentioned According to the invention this is achieved by providing the moulded charges with a firmly 5 preferably protective layer which protects the charges unintentional ignition or combustio and from nation and absorption of an advantageous embodiment of the invention this protective layer is created by denitration of the moulding by the of the nitro or nitrate groups in the of the nitro or nitrate groups in surface of the starting material can be carried in a simple by the treatment of the moulded charges in a bath containing suitable such as sulfides or and the followed by the removal of the split products by In addition to this surface or in its there may be according to another ment of the a protective of synthetic for polyglycidyl ethers and the or of soluble resins such as polyvinyl acetate and mixed polyacrylates or of dispersions of polyvinyl Yet another embodiment of Invention provides the use of such as methyl cellulose glycolate or the in forming the protective The protective layer may be formed by painting or precipitation from a depending on the nature of the starting material Suitable for cation by immersion or painting are polyurethane which may be used either as prepolymerisates with subsequent as finished as well tional aromatic glyeidyl mixed vinyl acetate polyacrylle dispersions of polyvinyl mixed polymerisates of or of for cellulose colatee are advantageously used for application by Where a this too ma be and possibly secured in its by the protective Since the porous structure of the moulded charge is not altered in the method according to invention and the protective coating may accordingly be made very of the mouldings is not while the danger in handling the mouldings is reduced to an able deeply penetrating contaminations are largely and lastly the resistance to mechanical stresses is improved and the wear by friction is All this without significant residue Pellets of 6 diamete and thickness were prepared in a die by means of a hydraulic press from a wet fibrous nitrocellulose having a nitrogen content of and being covered with of eentralite and o One surface of these pellets had a slanting upper depression of 2 mm depth and pellets had smooth surfaces and were sufficiently strong mechanicall not to in Their porous structure was still evident by the ct that of liquids were pellets dried before being further then of a moist detonato was into the depression and the pellets were from al moisture by fhe pellets were t passed through bath a mixture parts by weight of a of molecular weight 1200 parts of diisocyanate 3 parts of phtha and 70 parts of methylene On the surface there remained a liquid the solvent evaporated very coating fied by subsequent warming and formed a firmly thin layer which protected the body of the charge on sides and not impai the of the Ho formation of residue detonation resulted insufficientOCRQuality
Claims (6)
1. , A cartridge-leas moulded propellant charge of an explosive material such aa nitrocellulose, polyvinyl nitrate, nitroguanldine, pentaerythrltol tetranitrate and the like, o of mixtures thereof, particularly for use in commercial apparatus such as nail driving tools, impact tools, control elements, quick break switches and the like, which charge is provided on its surface with a firmly adhering, preferably thin layer protecting it from unintentional ignitio or combustion and from contamination and absorption of moisture,
2. A cartridge-less moulded propellant charge according to Claim 1, wherein the protective layer is created by the splitting-otf of the nitro or nitrate groups in the surface of the moulding*
3. · A cartridge-less moulded propellant charge according to Claim 1 or 2, wherein a protective coating is formed rom synthetic resins, e.g., polyurethanes, polyglyeidyl ethers and the like, or soluble resins such as polyvinyl acetate and mixed polymerisates, polyacrylates or dispersions based on polybutadiene, polyvinyl acetate and polyacrylates.
4. A cartridge-less moulded propellant charge according to Claim 1 or 2, wherein a protective layer is formed from methyl cellulose, cellulose glycolates or the like,
5. * A process for the manufacture of cartridge-less moulde propellent charges according to Claims 3 or 4» wherein the protective coating is applied by immersion, painting or precipitation from a solution.
6. A process for the manufacture of cartridge-less moulded propellant charges according to Claims 3 or 4» wherein the protective coating is formed by prior spraying, painting or similar treatment of the press-die with a lacquer component, or by the insertion of the lacquer component in the form of a foil into the die in the moulding operation. For the Applicants PARTNERS iffi/rb
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1796118A DE1796118C3 (en) | 1968-09-04 | 1968-09-04 | Caseless propellant charge compact and process for its manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL32928A0 IL32928A0 (en) | 1970-12-24 |
| IL32928A true IL32928A (en) | 1973-07-30 |
Family
ID=5708368
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL32928A IL32928A (en) | 1968-09-04 | 1969-09-02 | Cartridge-less moulded propellant charge |
Country Status (16)
| Country | Link |
|---|---|
| JP (1) | JPS4942531B1 (en) |
| AT (1) | AT290362B (en) |
| BE (1) | BE738397A (en) |
| BR (1) | BR6912030D0 (en) |
| CA (1) | CA936697A (en) |
| CH (1) | CH500053A (en) |
| DE (1) | DE1796118C3 (en) |
| DK (1) | DK135678C (en) |
| ES (1) | ES370815A1 (en) |
| FR (1) | FR2017366A1 (en) |
| GB (1) | GB1277247A (en) |
| IL (1) | IL32928A (en) |
| NL (1) | NL6913424A (en) |
| NO (1) | NO122518B (en) |
| PL (1) | PL80202B1 (en) |
| YU (1) | YU34107B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2709037A1 (en) * | 1977-03-02 | 1978-09-07 | Dynamit Nobel Ag | FIRM-WEATHER-PROOF DRIVE KIT FOR BOLT DRIVE CARTRIDGES |
| DE2710451C2 (en) * | 1977-03-10 | 1990-11-15 | Rheinmetall GmbH, 4000 Düsseldorf | Surface protection coating for ammunition with a combustible case or caseless ammunition |
| FR2444251A1 (en) * | 1978-12-15 | 1980-07-11 | Poudres & Explosifs Ste Nale | COMBUSTIBLE OBJECTS, AND IN PARTICULAR COMBUSTIBLE SOCKETS, RESISTANT TO HEAT |
| DE3006475C2 (en) * | 1980-02-21 | 1986-10-30 | Société Anonyme PRB, Brüssel / Bruxelles | Fuel for base-bleed gas generators, process for its production and for the production of a propellant from this fuel |
| FR2590360B1 (en) * | 1985-11-19 | 1989-06-30 | Poudres & Explosifs Ste Nale | MIXED LOADS FOR AMMUNITION WITH SOCKET COMPRISING FRAGMENTABLE SPHERICAL LOADS |
| WO2001019759A1 (en) * | 1999-09-15 | 2001-03-22 | Dynamit Nobel Gmbh Explosivstoff- Und Systemtechnik | Propellant charge powder having low temperature dependency |
-
1968
- 1968-09-04 DE DE1796118A patent/DE1796118C3/en not_active Expired
-
1969
- 1969-07-02 BR BR212030/69A patent/BR6912030D0/en unknown
- 1969-08-06 YU YU2036/69A patent/YU34107B/en unknown
- 1969-08-25 ES ES370815A patent/ES370815A1/en not_active Expired
- 1969-08-26 DK DK456969A patent/DK135678C/en active
- 1969-08-29 CH CH1317469A patent/CH500053A/en not_active IP Right Cessation
- 1969-09-01 JP JP44069042A patent/JPS4942531B1/ja active Pending
- 1969-09-02 NO NO3510/69A patent/NO122518B/no unknown
- 1969-09-02 CA CA060962A patent/CA936697A/en not_active Expired
- 1969-09-02 IL IL32928A patent/IL32928A/en unknown
- 1969-09-03 NL NL6913424A patent/NL6913424A/xx not_active Application Discontinuation
- 1969-09-03 AT AT838769A patent/AT290362B/en not_active IP Right Cessation
- 1969-09-03 FR FR6930084A patent/FR2017366A1/fr not_active Withdrawn
- 1969-09-03 GB GB43698/69A patent/GB1277247A/en not_active Expired
- 1969-09-03 BE BE738397D patent/BE738397A/xx unknown
- 1969-09-04 PL PL1969135672A patent/PL80202B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL32928A0 (en) | 1970-12-24 |
| FR2017366A1 (en) | 1970-05-22 |
| GB1277247A (en) | 1972-06-07 |
| CH500053A (en) | 1970-12-15 |
| DE1796118C3 (en) | 1978-08-17 |
| PL80202B1 (en) | 1975-08-30 |
| YU34107B (en) | 1978-12-31 |
| BR6912030D0 (en) | 1973-03-20 |
| JPS4942531B1 (en) | 1974-11-15 |
| AT290362B (en) | 1971-05-25 |
| DK135678B (en) | 1977-06-06 |
| DK135678C (en) | 1977-11-14 |
| DE1796118B2 (en) | 1977-12-08 |
| BE738397A (en) | 1970-02-16 |
| NL6913424A (en) | 1970-03-06 |
| CA936697A (en) | 1973-11-13 |
| DE1796118A1 (en) | 1972-02-17 |
| YU203669A (en) | 1978-06-30 |
| ES370815A1 (en) | 1971-07-01 |
| NO122518B (en) | 1971-07-05 |
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