IL129329A - Chiral ferrocenyls - Google Patents

Chiral ferrocenyls

Info

Publication number
IL129329A
IL129329A IL12932997A IL12932997A IL129329A IL 129329 A IL129329 A IL 129329A IL 12932997 A IL12932997 A IL 12932997A IL 12932997 A IL12932997 A IL 12932997A IL 129329 A IL129329 A IL 129329A
Authority
IL
Israel
Prior art keywords
pct
ferrocenyls
chiral
sec
date
Prior art date
Application number
IL12932997A
Other languages
English (en)
Other versions
IL129329A0 (en
Original Assignee
Novartis Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novartis Ag filed Critical Novartis Ag
Publication of IL129329A0 publication Critical patent/IL129329A0/xx
Publication of IL129329A publication Critical patent/IL129329A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Catalysts (AREA)
  • Soft Magnetic Materials (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IL12932997A 1996-10-07 1997-10-06 Chiral ferrocenyls IL129329A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH244096 1996-10-07
CH244196 1996-10-07
PCT/EP1997/005480 WO1998015565A1 (en) 1996-10-07 1997-10-06 Chiral ferrocenyls

Publications (2)

Publication Number Publication Date
IL129329A0 IL129329A0 (en) 2000-02-17
IL129329A true IL129329A (en) 2003-05-29

Family

ID=25690448

Family Applications (1)

Application Number Title Priority Date Filing Date
IL12932997A IL129329A (en) 1996-10-07 1997-10-06 Chiral ferrocenyls

Country Status (13)

Country Link
US (1) US6133464A (pt)
EP (1) EP0929560B1 (pt)
JP (1) JP4043051B2 (pt)
AT (1) ATE211479T1 (pt)
AU (1) AU4944197A (pt)
BR (1) BR9712273A (pt)
CA (1) CA2263715C (pt)
CZ (1) CZ292412B6 (pt)
DE (1) DE69709883T2 (pt)
ES (1) ES2170942T3 (pt)
HU (1) HU222691B1 (pt)
IL (1) IL129329A (pt)
WO (1) WO1998015565A1 (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1006199A1 (en) 1998-12-03 2000-06-07 Kreatech Biotechnology B.V. Applications with and methods for producing selected interstrand crosslinks in nucleic acid
US6562989B2 (en) 2000-08-07 2003-05-13 Yale University Catalyst for aromatic C—O, C—N, and C—C bond formation
US20040030199A1 (en) * 2002-01-29 2004-02-12 Maughon Robert R. Process for reducing alpha-haloketones to secondary alpha-haloalcohols
US6620954B1 (en) * 2002-03-25 2003-09-16 Eastman Chemical Company Phosphinometallocenylamides as novel ligands for asymmetric catalysis
GB0400717D0 (en) * 2004-01-14 2004-02-18 Stylacats Ltd Ferrocene derivatives
GB0400719D0 (en) * 2004-01-14 2004-02-18 Stylacats Ltd Ligands for use in homogeneous catalysis
GB0400720D0 (en) 2004-01-14 2004-02-18 Stylacats Ltd Novel ferrocene-based phosphorus chiral phosphines
DE102010001364B4 (de) * 2010-01-29 2014-10-16 Technische Universität Chemnitz Neue P,O-Ferrocene, deren Herstellung und Verwendung in katalytischen Reaktionen
JP6455893B2 (ja) 2013-03-11 2019-01-23 ラトガース，ザ ステート ユニバーシティ オブ ニュー ジャージー 不斉転換のための有機金属の触媒作用
CN103772441B (zh) * 2013-12-26 2016-08-17 浙江中山化工集团股份有限公司 一种（s）-1-二茂铁基乙基二甲胺转化为（r）-1-二茂铁基乙基二甲胺的合成方法
US9308527B2 (en) * 2014-03-17 2016-04-12 Eastman Chemical Company Phosphorous compounds useful as ligands and compositions and methods regarding them
CN104761518B (zh) * 2014-12-01 2017-05-24 青岛科技大学 一种离子液体条件下不对称氢化合成d‑泛内酯的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE59201991D1 (de) * 1991-01-25 1995-06-01 Ciba Geigy Ag Silangruppen enthaltende Diphosphine, immobilisierte Diphosphine und deren Verwendung als Hydrierkatalysatoren.
SG43803A1 (en) * 1991-01-25 1997-11-14 Ciba Geigy Ag Diphosphines containing silane groups immobilised diphosphines and the use thereof as hydrogenation catalyst
EP0564406B1 (de) * 1992-04-02 1999-05-06 Novartis AG Ferrocenyldiphosphine als Liganden für homogene Katalysatoren
SG42938A1 (en) * 1993-02-26 1997-10-17 Ciba Geigy Ag Ferrocenc diphosphines as ligands for homogeneous catalysts
SG42925A1 (en) * 1993-10-01 1997-10-17 Ciba Geigy Ag Fluoroalkyl-substituted ferrocenyl diphosphines as ligands for homogeneous catalysts
ES2150653T3 (es) * 1995-02-24 2000-12-01 Novartis Ag Ferrocenildifosfinas sililadas, ferrocenildifosfinas sililadas unidas a soportes inorganicos o polimeros organicos, asi como complejos metalicos de estas, su obtencion y empleo.
CA2216153C (en) * 1995-04-11 2008-02-05 Novartis Ag Dihalogenated ferrocenes and processes for the preparation thereof
HRP960295A2 (en) * 1995-07-06 1997-08-31 Ciba Geigy Ag Process for the hydrogenation of imines in the presence of immobilized iridium-diphosphine catalysts

Also Published As

Publication number Publication date
DE69709883T2 (de) 2002-08-29
IL129329A0 (en) 2000-02-17
DE69709883D1 (de) 2002-02-28
HUP9904186A2 (hu) 2000-04-28
ES2170942T3 (es) 2002-08-16
EP0929560A1 (en) 1999-07-21
BR9712273A (pt) 1999-08-31
HU222691B1 (hu) 2003-09-29
CZ292412B6 (cs) 2003-09-17
HUP9904186A3 (en) 2001-11-28
EP0929560B1 (en) 2002-01-02
JP4043051B2 (ja) 2008-02-06
CZ117899A3 (cs) 1999-07-14
WO1998015565A1 (en) 1998-04-16
US6133464A (en) 2000-10-17
AU4944197A (en) 1998-05-05
CA2263715C (en) 2007-05-01
JP2001501638A (ja) 2001-02-06
ATE211479T1 (de) 2002-01-15
CA2263715A1 (en) 1998-04-16

Similar Documents

Publication Publication Date Title
IL129329A (en) Chiral ferrocenyls
ZA955868B (en) Substituted pyrimidine compounds and the use thereof
CA2356154A1 (en) Ligands and complexes for enantioselective hydrogenation
HK1023987A1 (en) Sulphinic acid derivatives, method for producing, and their use
ATE218859T1 (de) Liganden des neuropeptids y
BG102644A (en) Improved concentrated inoculation and infusion solutions for intravasal application
HU9700115D0 (en) Use of thiazole and thiadiazole compounds as d3 dopamine receptor ligands
BG105009A (en) Method for producing 4-carboxyamino-2-substituted 1,2,3,4-tetrahydroquinoline
GR3036305T3 (en) Chiral methyl phenyl oxazolidinones
BG103096A (en) Thrombin inhibitors
HU9700109D0 (en) Triazole compounds and their use as dopamine-d3-ligands
BG106019A (en) INHIBITORS OF LFA-1 BINDING TO ICAMs AND USES THEREOF
DE69823662D1 (de) 1,4,7,10-tetraazabicyclo(8.2.2)tetradecan-2-on, verfahren zu ihrer herstellung und ihrer verwendung für die herstellung von tetraazamacrocyclen
DK1047669T3 (da) Perfluor-N-alkylsulfonsyrederivater
BG104291A (en) 3-substituted tetrahydropyridopyrimidinone derivatives, method for producing the same, and their use
BG104232A (en) Substituted 1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazozocyn-10-ols, method for their preparation and application as medicamentous forms
BG105766A (en) New process for preparing pesticidal intermediates
AU8631698A (en) A process for the preparation of tetraazamacrocycles
GB2324091A (en) Metalloproteinase inhibitors
BG106002A (en) Process for preparing pesticidal intermediates
AU2001262510A1 (en) Chiral ligands for asymmetric catalysis
AU3344697A (en) Pseudopolyrotaxanes
BG103649A (en) Method for the preparation of eprosartan
BG103650A (en) Method for the preparation of eprosartan
GB9806409D0 (en) Processes for preparing intermediates

Legal Events

Date Code Title Description
FF Patent granted
KB Patent renewed
HP Change in proprietorship
KB Patent renewed
MM9K Patent not in force due to non-payment of renewal fees