IL129115A - Process for brominating polystyrenic resins - Google Patents
Process for brominating polystyrenic resinsInfo
- Publication number
- IL129115A IL129115A IL12911597A IL12911597A IL129115A IL 129115 A IL129115 A IL 129115A IL 12911597 A IL12911597 A IL 12911597A IL 12911597 A IL12911597 A IL 12911597A IL 129115 A IL129115 A IL 129115A
- Authority
- IL
- Israel
- Prior art keywords
- styrenic polymer
- mixture
- brominating agent
- reactor
- catalyst
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/727,341 US5677390A (en) | 1996-09-26 | 1996-09-26 | Process for brominating polystyrenic resins |
PCT/US1997/015624 WO1998013397A1 (fr) | 1996-09-26 | 1997-09-05 | Procede de bromuration de resines de polystyrene |
Publications (2)
Publication Number | Publication Date |
---|---|
IL129115A0 IL129115A0 (en) | 2000-02-17 |
IL129115A true IL129115A (en) | 2002-08-14 |
Family
ID=24922284
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IL12911597A IL129115A (en) | 1996-09-26 | 1997-09-05 | Process for brominating polystyrenic resins |
Country Status (7)
Country | Link |
---|---|
US (2) | US5677390A (fr) |
EP (1) | EP0928299B1 (fr) |
JP (1) | JP3806942B2 (fr) |
CA (1) | CA2265785C (fr) |
DE (1) | DE69701996T2 (fr) |
IL (1) | IL129115A (fr) |
WO (1) | WO1998013397A1 (fr) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5637650A (en) | 1996-06-14 | 1997-06-10 | Ferro Corporation | Brominated polysytrene having improved thermal stability and color and process for the preparation thereof |
US6518368B2 (en) | 1996-06-14 | 2003-02-11 | Albemarle Corporation | Brominated polystyrene having improved thermal stability and color and process for the preparation thereof |
US6521714B2 (en) | 1996-09-26 | 2003-02-18 | Albemarle Corporation | Brominated polystyrenic resins |
US6235831B1 (en) * | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Polymer compositions containing brominated polystyrenic resins |
US6133381A (en) * | 1996-09-26 | 2000-10-17 | Albelmarle Corporation | Brominated polystyrenic flame retardants |
US6232393B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Polymers flame retarded with brominated polystyrenic resins |
CA2265642C (fr) | 1996-09-26 | 2006-03-14 | Albemarle Corporation | Procede de bromuration de styrenes-polymeres |
US6232408B1 (en) | 1996-09-26 | 2001-05-15 | Albemarle Corporation | Brominated polstyrenic resins |
US6326439B1 (en) | 1996-09-26 | 2001-12-04 | Albemarle Corporation | Process for brominating polystyrenic resins |
US6235844B1 (en) | 1996-09-26 | 2001-05-22 | Albemarle Corporation | Brominated polystyrenic resins |
US6146555A (en) * | 1998-01-19 | 2000-11-14 | Ferro Corporation | Brominated copolymer flame retardant additives having improved color characteristics and related method |
EP1115756A1 (fr) * | 1998-09-10 | 2001-07-18 | Albemarle Corporation | Resines de polystyrene brome ameliorees, et leur utilisation |
WO2003055832A1 (fr) | 2001-12-21 | 2003-07-10 | Pabu Services, Inc. | Procede et dispositif pour produire des alcanes de decabromodiphenyle |
US20040072929A1 (en) * | 2002-06-27 | 2004-04-15 | De Schryver Daniel A. | Flame retardant compositions |
US6657028B1 (en) | 2002-08-01 | 2003-12-02 | Albemarle Corporation | Anionic polymerization process |
US7666944B2 (en) * | 2004-01-21 | 2010-02-23 | Albemarle Corporation | Flame retarded fibers and filaments and process of production therefor |
US20050159552A1 (en) * | 2004-01-21 | 2005-07-21 | Reed Jon S. | Flame retarded fibers and filaments and process of production therefor |
US7585443B2 (en) * | 2004-05-20 | 2009-09-08 | Albemarle Corporation | Pelletized brominated anionic styrenic polymers and their preparation and use |
DE602005018673D1 (de) * | 2004-09-30 | 2010-02-11 | Chemtura Corp | Verbesserte bromstyrol-polymere mit kontrolliertem molekülgewicht |
JP5116670B2 (ja) * | 2005-06-30 | 2013-01-09 | アルベマール・コーポレーシヨン | 臭素化スチレン系ポリマーおよびこれらの製造 |
JP5261190B2 (ja) * | 2005-12-21 | 2013-08-14 | アルベマール・コーポレーシヨン | 臭素化アニオン性スチレン性ポリマー及びそれらの製造 |
CA2629736C (fr) * | 2005-12-21 | 2014-07-08 | Albemarle Corporation | Elaboration de polymeres ou resines styreniques bromes |
HUE025498T2 (hu) | 2006-07-20 | 2016-04-28 | Albemarle Corp | Eljárási technológia brómozott sztirolpolimerek visszanyerésére reakcióelegyekbõl, amelyekben képzõdtek és/vagy ezen elegyek átalakítása pelletekké vagy granulátumokká vagy pasztillákká |
US8202945B2 (en) * | 2006-08-16 | 2012-06-19 | Dow Global Technologies Llc | Process for brominating butadieneninyl aromatic copolymers |
US8114943B2 (en) * | 2006-08-16 | 2012-02-14 | Dow Global Technologies Llc | Process for brominating butadiene/vinyl aromatic copolymers |
TW200817447A (en) | 2006-08-22 | 2008-04-16 | Albemarle Corp | Terminating bromination of styrenic polymer in a bromination reaction mixture |
MX2009005458A (es) | 2006-11-28 | 2009-06-01 | Albemarle Corp | Conversion de polimero estirenico anionico bromado en forma mas dura y larga para almacenamiento, envio y uso. |
US8802238B2 (en) * | 2007-03-29 | 2014-08-12 | Akron Polymer Systems, Inc. | Optical compensation films based on fluoropolymers |
US8435636B2 (en) * | 2007-03-29 | 2013-05-07 | Akron Polymer Systems, Inc. | Optical compensation films of brominated styrenic polymers and related methods |
US8889043B2 (en) | 2007-03-29 | 2014-11-18 | Akron Polymer Systems, Inc. | Optical films cast from styrenic fluoropolymer solutions |
US9011992B2 (en) | 2007-03-29 | 2015-04-21 | Akron Polymer Systems | Optical compensation films based on stretched polymer films |
ES2708852T3 (es) * | 2007-06-07 | 2019-04-11 | Albemarle Corp | Aductos, aductos y oligómeros, o aductos, oligómeros y polímeros de bajo peso molecular, y su preparación |
JP2011528380A (ja) * | 2008-03-06 | 2011-11-17 | ダウ グローバル テクノロジーズ エルエルシー | 水又は或る種の溶媒の添加によるブタジエンコポリマーの臭素化方法 |
WO2009126531A1 (fr) * | 2008-04-07 | 2009-10-15 | Dow Global Technologies, Inc. | Procédé de bromation de copolymères aromatiques de butadiène/vinyle |
US8410226B2 (en) * | 2008-05-01 | 2013-04-02 | Dow Global Technologies Llc | Two-step process for brominating butadiene copolymers |
EP2288628B1 (fr) | 2008-06-06 | 2018-12-19 | Albemarle Corporation | Polymères bromés de faible masse moléculaire, leurs procédés de fabrication et leur utilisation dans des préparations thermoplastiques |
US8993684B2 (en) | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
SG171741A1 (en) * | 2008-12-02 | 2011-07-28 | Albemarle Corp | Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom |
JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
EP2373697A1 (fr) * | 2008-12-02 | 2011-10-12 | Albemarle Corporation | Bromation de mélanges de télomères issus du toluène et du styrène |
WO2010065467A1 (fr) * | 2008-12-02 | 2010-06-10 | Albemarle Corporation | Polymères, télomères et produits d'addition du styrène ramifiés et ramifiés en étoile, leur synthèse, leur bromation et leurs utilisations |
MX2011011302A (es) | 2009-05-01 | 2011-11-18 | Albemarle Corp | Composiciones granuladas de polimeros aromaticos bromados de bajo peso molecular. |
JO3059B1 (ar) * | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
CN101701047B (zh) * | 2009-10-22 | 2011-09-07 | 国家海洋局天津海水淡化与综合利用研究所 | 喷雾干燥溴化聚苯乙烯制备方法 |
US9457496B2 (en) | 2011-03-23 | 2016-10-04 | Akron Polymer Systems, Inc. | Aromatic polyamide films for transparent flexible substrates |
US9856376B2 (en) | 2011-07-05 | 2018-01-02 | Akron Polymer Systems, Inc. | Aromatic polyamide films for solvent resistant flexible substrates |
CN103987763B (zh) | 2011-08-19 | 2017-12-29 | 阿克伦聚合物体系有限公司 | 热稳定的低双折射共聚聚酰亚胺膜 |
US8871882B2 (en) | 2012-02-14 | 2014-10-28 | Akron Polymer Systems, Inc. | Method for the preparation of styrenic fluoropolymers |
Family Cites Families (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1890772A (en) * | 1930-01-28 | 1932-12-13 | Du Pont | Chlorination of meta styrene |
US2199026A (en) * | 1937-04-01 | 1940-04-30 | Du Pont | Chlorinated aromatic resins |
US2823201A (en) * | 1952-03-10 | 1958-02-11 | Dow Chemical Co | Halogenated polymers of nuclear methylated aromatic hydrocarbons, their quaternary ammonium salts and method of making the same |
US3009906A (en) * | 1957-05-09 | 1961-11-21 | Dow Chemical Co | Halogenation of solid resinous polymers of alkenylaromatic compounds with gaseous halogens |
US3050476A (en) * | 1958-12-08 | 1962-08-21 | Koppers Co Inc | Method of making a self extinguishing expandable polymer of styrene by bromination |
US3039977A (en) * | 1959-12-03 | 1962-06-19 | Koppers Co Inc | Method of producing self-extinguishing foamable polystyrene by brominating foamable polystyrene in aqueous suspension |
US3132045A (en) * | 1961-10-26 | 1964-05-05 | Dow Chemical Co | Method of impregnating film materials with ammonium bromide |
NL128916C (fr) * | 1965-02-18 | 1900-01-01 | ||
US3506741A (en) * | 1966-01-10 | 1970-04-14 | Phillips Petroleum Co | Halogenated polymers and block copolymers produced therefrom |
US3534012A (en) * | 1969-05-01 | 1970-10-13 | Dow Chemical Co | Anionic polymerization of nuclear halogenated styrenes |
CH584731A5 (fr) * | 1973-12-17 | 1977-02-15 | Ciba Geigy Ag | |
US3959398A (en) * | 1974-06-03 | 1976-05-25 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
US4028486A (en) * | 1974-06-03 | 1977-06-07 | The Goodyear Tire & Rubber Company | Alpha-methyl-p-bromo-styrene and method of preparation |
US3932542A (en) * | 1974-08-26 | 1976-01-13 | Great Lakes Chemical Corporation | Process for preparation of 2,5-dibromo-p-xylene |
US4178327A (en) * | 1974-12-19 | 1979-12-11 | The Dow Chemical Company | Ar-halo-ar(t-alkyl)styrenes and polymers thereof |
CA1054161A (fr) * | 1975-08-22 | 1979-05-08 | Herbert Naarmann | Fabrication d'oligomeres bromes resistant a la chaleur a base de composes aromatiques monovynyliques |
DE2645711C3 (de) * | 1976-10-09 | 1979-06-07 | Basf Ag, 6700 Ludwigshafen | Halogenhaltige Flammschutzmittel enthaltende Fasern und Fäden aus linearen, thermoplastischen Polyestern |
DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
CA1050754A (fr) * | 1977-01-02 | 1979-03-20 | Louis Scodeller | Niveleuse |
DE2703419B1 (de) * | 1977-01-28 | 1978-02-02 | Basf Ag | Flammwidrig ausgeruestete polyamid- formmassen |
FR2413409A1 (fr) * | 1978-01-02 | 1979-07-27 | Huels Chemische Werke Ag | Procede pour preparer des polystyrenes resistant a la chaleur, bromes sur le noyau |
DE3006448A1 (de) * | 1980-02-21 | 1981-08-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen aus bromierten polystyrolen und bromierten aromatischen verbindungen |
US4352909A (en) * | 1980-08-20 | 1982-10-05 | Ferro Corporation | Process for the bromination of polystyrenes |
US4389517A (en) * | 1982-04-02 | 1983-06-21 | The Dow Chemical Company | Hydrogenation of phenylacetylene prior to styrene polymerization |
US4554326A (en) * | 1983-04-01 | 1985-11-19 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
US4501859A (en) * | 1983-04-01 | 1985-02-26 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
US4513116A (en) * | 1983-04-01 | 1985-04-23 | Exxon Research And Engineering Co. | Process for the manufacture of halogenated polymers |
US4548995A (en) * | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
EP0150332A3 (fr) * | 1983-12-26 | 1987-08-19 | Mitsubishi Kasei Corporation | Procédé de fabrication de polymères chlorométhylés |
JPS6134723A (ja) * | 1984-07-26 | 1986-02-19 | Teijin Ltd | 磁気記録媒体及びその製造法 |
US4650832A (en) * | 1984-09-17 | 1987-03-17 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
EP0201411A3 (fr) * | 1985-05-03 | 1989-02-08 | The Dow Chemical Company | Polymères bromés de composés alcénylaromatiques |
US4879353A (en) * | 1987-01-28 | 1989-11-07 | Great Lakes Chemical Corporation | Bromination of polystyrene using bromine as the reaction solvent |
US4835222A (en) * | 1987-02-19 | 1989-05-30 | The Dow Chemical Company | Alkylation of vinyl aromatic polymer |
US4832873A (en) * | 1987-10-09 | 1989-05-23 | Great Lakes Chemical Corporation | Process for producing polybrominated higher alkylbenzenes |
JPH0760235B2 (ja) * | 1988-09-29 | 1995-06-28 | 株式会社三協精機製作所 | エレクトロクロミック表示装置 |
JPH02215807A (ja) * | 1989-02-17 | 1990-08-28 | Nippon Kayaku Co Ltd | 臭素化ポリスチレンの製造方法 |
US5112896A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High-impact polystyrene containing low molecular weight brominated polystyrene |
US5112897A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
US5112898A (en) * | 1989-06-06 | 1992-05-12 | Ferro Corporation | High impact polystyrene containing low molecular weight brominated polystyrene |
US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
WO1991013915A1 (fr) * | 1990-03-16 | 1991-09-19 | Great Lakes Chemical Corporation | Procede de purification de polystyrene brome |
US5194482A (en) * | 1990-08-23 | 1993-03-16 | Ferro Corporation | Flame retardant resin composition containing styrenic polymers |
US5235000A (en) * | 1990-12-10 | 1993-08-10 | Ethyl Corporation | Preparation, storage, and usage of bromine chloride |
US5326837A (en) * | 1992-11-20 | 1994-07-05 | Mobil Oil Corporation | Catalyst systems for syndiospecific polymerization of styrenes |
US5304618A (en) * | 1993-07-22 | 1994-04-19 | Great Lakes Chemical Corporation | Polymers of brominated styrene |
US5532322B1 (en) * | 1995-09-26 | 1999-12-07 | Manac Inc | Process for preparing brominated polystyrene |
-
1996
- 1996-09-26 US US08/727,341 patent/US5677390A/en not_active Expired - Lifetime
-
1997
- 1997-06-11 US US08/872,985 patent/US5852132A/en not_active Expired - Lifetime
- 1997-09-05 CA CA002265785A patent/CA2265785C/fr not_active Expired - Lifetime
- 1997-09-05 WO PCT/US1997/015624 patent/WO1998013397A1/fr active IP Right Grant
- 1997-09-05 EP EP97939809A patent/EP0928299B1/fr not_active Expired - Lifetime
- 1997-09-05 DE DE69701996T patent/DE69701996T2/de not_active Expired - Lifetime
- 1997-09-05 IL IL12911597A patent/IL129115A/en not_active IP Right Cessation
- 1997-09-05 JP JP51565998A patent/JP3806942B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69701996D1 (de) | 2000-06-15 |
WO1998013397A1 (fr) | 1998-04-02 |
JP2002512641A (ja) | 2002-04-23 |
CA2265785C (fr) | 2005-04-19 |
EP0928299A1 (fr) | 1999-07-14 |
DE69701996T2 (de) | 2000-11-09 |
US5677390A (en) | 1997-10-14 |
IL129115A0 (en) | 2000-02-17 |
CA2265785A1 (fr) | 1998-04-02 |
JP3806942B2 (ja) | 2006-08-09 |
US5852132A (en) | 1998-12-22 |
EP0928299B1 (fr) | 2000-05-10 |
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EP0928298B1 (fr) | Procede de bromation de resines de polystyrene | |
EP0277429B1 (fr) | Bromuration aromatique de polystyrène en utilisant un composé de brome comme solvant de réaction | |
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Legal Events
Date | Code | Title | Description |
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FF | Patent granted | ||
KB | Patent renewed | ||
KB | Patent renewed | ||
KB | Patent renewed | ||
KB | Patent renewed | ||
KB | Patent renewed | ||
EXP | Patent expired |