HUP0200112A2 - Eljárás ciklohexánkarbonsav előállítására [2+4] Diels-Alder reakció alkalmazásával - Google Patents
Eljárás ciklohexánkarbonsav előállítására [2+4] Diels-Alder reakció alkalmazásávalInfo
- Publication number
- HUP0200112A2 HUP0200112A2 HU0200112A HUP0200112A HUP0200112A2 HU P0200112 A2 HUP0200112 A2 HU P0200112A2 HU 0200112 A HU0200112 A HU 0200112A HU P0200112 A HUP0200112 A HU P0200112A HU P0200112 A2 HUP0200112 A2 HU P0200112A2
- Authority
- HU
- Hungary
- Prior art keywords
- diels
- alder reaction
- cyclohexanecarboxylic acid
- preparing
- solvent
- Prior art date
Links
- 238000005698 Diels-Alder reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 title 2
- VZFUCHSFHOYXIS-UHFFFAOYSA-N cycloheptane carboxylic acid Natural products OC(=O)C1CCCCCC1 VZFUCHSFHOYXIS-UHFFFAOYSA-N 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- FPIQZBQZKBKLEI-UHFFFAOYSA-N ethyl 1-[[2-chloroethyl(nitroso)carbamoyl]amino]cyclohexane-1-carboxylate Chemical compound ClCCN(N=O)C(=O)NC1(C(=O)OCC)CCCCC1 FPIQZBQZKBKLEI-UHFFFAOYSA-N 0.000 abstract 1
- 239000012847 fine chemical Substances 0.000 abstract 1
- JSSXHAMIXJGYCS-UHFFFAOYSA-N piperazin-4-ium-2-carboxylate Chemical compound OC(=O)C1CNCCN1 JSSXHAMIXJGYCS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A találmány szerinti eljárás során 1,3-butadiént és akrilsavat[2+4]Diels-Alder reakció körülményei között reagáltatnak, így 3-ciklohexén-l-karbonsavat kapnak, amelyet azután hidrogénező katalizátor éshidrogénező oldószer jelenlétében vagy oldószer alkalmazása nélkülhidrogéneznek. Az eljárással nagy hozammal és tisztán előállítottciklohexánkarbonsav finomvegyszerek gyártására is alkalmas. Ó
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR19990004025 | 1999-02-05 | ||
KR1019990037508A KR20000056975A (ko) | 1999-02-05 | 1999-09-03 | [2+4] 딜즈-알더 반응을 이용하는 시클로헥산카르복실산의 제조방법 |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP0200112A2 true HUP0200112A2 (hu) | 2002-05-29 |
HUP0200112A3 HUP0200112A3 (en) | 2003-02-28 |
Family
ID=26634676
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU0200112A HUP0200112A3 (en) | 1999-02-05 | 1999-12-04 | A method of preparing cyclohexanecarboxylic acid by [2+4] diels-alder reaction |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP1187801A4 (hu) |
JP (1) | JP2002539083A (hu) |
KR (1) | KR20000056975A (hu) |
CN (1) | CN1348437A (hu) |
AU (1) | AU1513800A (hu) |
BR (1) | BR9917235A (hu) |
CA (1) | CA2361682A1 (hu) |
HU (1) | HUP0200112A3 (hu) |
PL (1) | PL350029A1 (hu) |
WO (1) | WO2000046174A1 (hu) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100496763B1 (ko) * | 2002-04-23 | 2005-06-22 | 한국과학기술연구원 | 벤조산의 수용액상 수소화 반응에 의한 사이클로헥산카르복실산의 제조방법 |
KR20040026964A (ko) * | 2002-09-27 | 2004-04-01 | 금호석유화학 주식회사 | 1,3-부타디엔과 아크릴산으로부터 시클로헥실 페닐 케톤의제조방법 |
CN101768074B (zh) * | 2009-12-29 | 2017-09-26 | 大连九信精细化工有限公司 | 一种合成4‑羧甲基环己烷羧酸的新方法 |
DE102010040282A1 (de) * | 2010-09-06 | 2012-03-08 | Evonik Röhm Gmbh | Funktionsmaterialien mit steuerbarer Viskosität bzw. reversibler Vernetzung über Aza-Diels-Alder-Reaktionen mit Bishydrazonen oder konjugierten Bis-Schiff'schen Basen |
US9115155B1 (en) * | 2014-03-20 | 2015-08-25 | Eastman Chemical Company | Low-pressure synthesis of cyclohexanedimethanol and derivatives |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54157546A (en) * | 1978-05-30 | 1979-12-12 | Mitsui Toatsu Chem Inc | Preparation of 3-cyclohexenecarboxylic acid |
-
1999
- 1999-09-03 KR KR1019990037508A patent/KR20000056975A/ko not_active Application Discontinuation
- 1999-12-04 EP EP99957434A patent/EP1187801A4/en not_active Withdrawn
- 1999-12-04 PL PL99350029A patent/PL350029A1/xx unknown
- 1999-12-04 CN CN99816019A patent/CN1348437A/zh active Pending
- 1999-12-04 BR BR9917235-6A patent/BR9917235A/pt not_active Application Discontinuation
- 1999-12-04 JP JP2000597247A patent/JP2002539083A/ja active Pending
- 1999-12-04 WO PCT/KR1999/000739 patent/WO2000046174A1/en not_active Application Discontinuation
- 1999-12-04 HU HU0200112A patent/HUP0200112A3/hu unknown
- 1999-12-04 AU AU15138/00A patent/AU1513800A/en not_active Abandoned
- 1999-12-04 CA CA002361682A patent/CA2361682A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
JP2002539083A (ja) | 2002-11-19 |
EP1187801A4 (en) | 2002-09-18 |
BR9917235A (pt) | 2001-11-27 |
PL350029A1 (en) | 2002-10-21 |
KR20000056975A (ko) | 2000-09-15 |
WO2000046174A1 (en) | 2000-08-10 |
HUP0200112A3 (en) | 2003-02-28 |
CA2361682A1 (en) | 2000-08-10 |
CN1348437A (zh) | 2002-05-08 |
AU1513800A (en) | 2000-08-25 |
EP1187801A1 (en) | 2002-03-20 |
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