HUP0103585A2 - Electrical wire or cable having insulation and process making thereof - Google Patents
Electrical wire or cable having insulation and process making thereofInfo
- Publication number
- HUP0103585A2 HUP0103585A2 HU0103585A HUP0103585A HUP0103585A2 HU P0103585 A2 HUP0103585 A2 HU P0103585A2 HU 0103585 A HU0103585 A HU 0103585A HU P0103585 A HUP0103585 A HU P0103585A HU P0103585 A2 HUP0103585 A2 HU P0103585A2
- Authority
- HU
- Hungary
- Prior art keywords
- weight
- polymer
- acrylate
- monomer
- terpolymer
- Prior art date
Links
- 238000009413 insulation Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 11
- 229920001577 copolymer Polymers 0.000 abstract 7
- 239000000178 monomer Substances 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- 229920001897 terpolymer Polymers 0.000 abstract 4
- 239000002033 PVDF binder Substances 0.000 abstract 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- 150000001733 carboxylic acid esters Chemical group 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 abstract 2
- 238000004132 cross linking Methods 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
- H01B3/445—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
Abstract
A találmány tárgya szigeteléssel ellátott villamos vezeték vagy kábel,továbbá eljárás ilyenek előállítására. A találmány szerinti vezetékvagy kábel egyik változata tartalmaz legalább egy, (a teljesanyagösszetételre számítva) legalább 20 tömeg%- ban karboniltartalmúpolimert (amely homo- vagy ko- vagy terpolimer) tartalmazó poliolefinalapú anyag képezte első (i) réteget, ahol a polimernek az egyetlenvagy legalább egyik monomerje karbonsav-észter, előnyösen akrilát vagyacetát, különösen előnyösen alkil-akrilát (például MA, EA, propil-akrilát vagy butil-akrilát), továbbá ha a polimer ko- vagy terpolimer,akkor a polimer legalább 5 tömeg%-át az említett monomer képezi, míg apolimer fennmaradó része olefin monomerből, előnyösen etilénből vanszármaztatva, érintkezésben legalább egy, a teljes anyagösszetételreszámítva legalább 10 tömeg%-ban PVDF-et, vagy részlegesen vagy teljesegészében fluorozott komonomer és VDF kopolimerjét tartalmazó anyagképezte második (ii) réteggel, ahol az egymással érintkezésben lévő(i) és (ii) rétegek a közöttük fennálló lefejtési szilárdságotlegalább 5 N nagyságúra növelőn végrehajtott térhálósítási reakciónakvannak alávetve. A találmány szerinti vezeték vagy kábel egy újabbváltozata tartalmaz legalább egy, a teljes keverék-összetétel polimerrészének legalább 20 tömeg%-ában, előnyösen legalább 40 tömeg%-ában,előnyösebben legalább 60 tömeg%-ában vagy legelőnyösebben legalább 80tömeg%-ában valamilyen karboniltartalmú polimert (amely homo- vagy ko-vagy terpolimer) tartalmazó poliolefin alapú keverékösszetétel képezteelső (i) réteget, ahol a polimernek az egyetlen vagy legalább egyikmonomerje karbonsav-észter, előnyösen akrilát vagy acetát, különösenelőnyösen alkil-akrilát (előnyösen MA, EA, propil-akrilát vagy butil-akrilát), továbbá ha a polimer ko- vagy terpolimer, akkor a polimerlegalább 5 tömeg%-át, előnyösen legalább 9 tömeg%-át, még előnyösebbenlegalább 15 tömeg%-át az említett monomer képezi, míg a polimerfennmaradó része vagy fennmaradó részének nagyobb hányada olefinmonomerből, előnyösen etilénből van származtatva, érintkezésbenlegalább egy, a keverék-összetételre számítva legalább 10 tömeg%-ban,előnyösebben legalább 50 tömeg%-ban, még előnyösebben legalább 90tömeg%-ban, különösen előnyösen 100 tömeg%-ban polivinilidén-fluoridot, PVDF-et, vagy különösen előnyösen részlegesen vagy teljesenfluorozott komonomer és VDF kopolimerjét, előnyösen VDF és HFPkopolimerjét tartalmazó keverék-összetétel képezte második (ii)réteggel, ahol az egymással érintkezésben lévő (i) és (ii) rétegek23°C hőmérsékleten végzett 1 óra időtartamú acetonba merítési tesztsorán bekövetkező szétválást megakadályozó vagy a rétegek közöttfennálló lefejtési szilárdságot az ASTM B1876-95 sz. szabványbanfoglaltak szerint legalább 5 N nagyságúra, a nem térhálósodott rétegeklefejtési szilárdságához képest legalább 50%-kal,The subject of the invention is an electric wire or cable with insulation, as well as a method for producing such. One version of the wire or cable according to the invention contains at least one polyolefin-based material containing at least 20% by weight of a carbonyl-containing polymer (which is a homo- or co- or terpolymer) (calculated from the total material composition) forming the first layer (i), where the polymer has the only or at least one its monomer is a carboxylic acid ester, preferably acrylate or acetate, particularly preferably alkyl acrylate (for example MA, EA, propyl acrylate or butyl acrylate), and if the polymer is a co- or terpolymer, then at least 5% by weight of the polymer is the mentioned monomer forms, while the remainder of the polymer is derived from an olefin monomer, preferably ethylene, in contact with at least one second (ii) layer containing at least 10% by weight of PVDF, or a partially or fully fluorinated comonomer and VDF copolymer, where the layers (i) and (ii) in contact are subjected to a cross-linking reaction that increases the peel strength between them to at least 5 N. Another version of the wire or cable according to the invention contains at least one carbonyl-containing polymer in at least 20% by weight, preferably at least 40% by weight, more preferably at least 60% by weight or most preferably at least 80% by weight of the polymer part of the entire mixture composition (which is a homo- or co- or terpolymer) formed a first (i) layer, where the only or at least one monomer of the polymer is a carboxylic acid ester, preferably acrylate or acetate, particularly preferably alkyl acrylate (preferably MA, EA, propyl acrylate or butyl acrylate), and if the polymer is a co- or terpolymer, then at least 5% by weight, preferably at least 9% by weight, even more preferably at least 15% by weight of the polymer is made up of the mentioned monomer, while the remaining part of the polymer or a greater proportion of its part is derived from an olefin monomer, preferably from ethylene, in contact with at least one, at least 10% by weight, more preferably at least 50% by weight, more preferably at least 90% by weight, particularly preferably 100% by weight of polyvinylidene- fluoride, PVDF, or particularly preferably a partially or fully fluorinated comonomer and a copolymer of VDF, preferably a copolymer of VDF and HFP, formed a mixture composition with a second layer (ii), where the layers (i) and (ii) in contact with each other at a temperature of 23°C 1 The peeling strength that prevents separation occurring during an hour-long immersion in acetone or between the layers is determined by ASTM B1876-95 no. according to the standard, to a value of at least 5 N, at least 50% compared to the peel strength of non-cured layers,
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9820214.6A GB9820214D0 (en) | 1998-09-17 | 1998-09-17 | Bonding polymer interface |
| PCT/GB1999/003116 WO2000017889A1 (en) | 1998-09-17 | 1999-09-17 | Electrical wire insulation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HUP0103585A2 true HUP0103585A2 (en) | 2002-01-28 |
| HUP0103585A3 HUP0103585A3 (en) | 2002-04-29 |
| HU226699B1 HU226699B1 (en) | 2009-07-28 |
Family
ID=10838985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU0103585A HU226699B1 (en) | 1998-09-17 | 1999-09-17 | Electrical wire or cable having insulation and process making thereof |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP1116243B1 (en) |
| JP (1) | JP2002525819A (en) |
| KR (1) | KR100638181B1 (en) |
| CN (1) | CN1331160C (en) |
| AT (1) | ATE321345T1 (en) |
| AU (1) | AU766430B2 (en) |
| BR (1) | BR9913843A (en) |
| CA (1) | CA2340386C (en) |
| CZ (1) | CZ299046B6 (en) |
| DE (1) | DE69930532T2 (en) |
| ES (1) | ES2260937T3 (en) |
| GB (1) | GB9820214D0 (en) |
| HU (1) | HU226699B1 (en) |
| ID (1) | ID29877A (en) |
| IL (2) | IL141338A0 (en) |
| NO (1) | NO324458B1 (en) |
| PL (1) | PL192515B1 (en) |
| RO (1) | RO121928B1 (en) |
| RU (1) | RU2231147C2 (en) |
| TR (1) | TR200100761T2 (en) |
| WO (1) | WO2000017889A1 (en) |
| ZA (1) | ZA200101181B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0006333D0 (en) * | 2000-03-16 | 2000-05-03 | Raychem Ltd | Electrical wire insulation |
| JP2002225204A (en) * | 2001-01-30 | 2002-08-14 | Reitekku:Kk | Modified fluororesin coated material and method for producing the same |
| FR2856404B1 (en) | 2003-06-06 | 2008-08-08 | Atofina | METHOD OF GRAFTING FLUORINATED POLYMER AND MULTILAYER STRUCTURES COMPRISING THE GRAFT POLYMER |
| US7241817B2 (en) | 2003-06-06 | 2007-07-10 | Arkema France | Process for grafting a fluoropolymer and multilayer structures comprising this grafted polymer |
| WO2007006897A2 (en) * | 2005-07-05 | 2007-01-18 | Arkema France | Multilayer insulation structure |
| FR2888389B1 (en) * | 2005-07-05 | 2007-08-31 | Arkema Sa | INSULATING MULTILAYER STRUCTURE |
| CN100370556C (en) * | 2005-12-01 | 2008-02-20 | 上海交通大学 | Unsaturated carboxylic acid salt modified WTR insulation material and preparing method |
| KR100716381B1 (en) * | 2006-02-15 | 2007-05-11 | 엘에스전선 주식회사 | Composition for manufacturing insulation materials of electrical wire and manufactured electrical wire using the same |
| CN101117393B (en) * | 2006-08-04 | 2011-03-16 | 上海尚聚化工科技有限公司 | Multi-layer nuclear shell structural fluorin-containing polymer particle and thermoplastic polyolefin product having the same |
| US8007857B1 (en) * | 2006-09-08 | 2011-08-30 | Abbott Cardiovascular Systems Inc. | Methods for controlling the release rate and improving the mechanical properties of a stent coating |
| CN102667967B (en) * | 2009-11-10 | 2014-04-16 | 大金工业株式会社 | Cable, cable duct and methods for manufacturing cable and cable duct |
| GB2479371B (en) * | 2010-04-07 | 2014-05-21 | Tyco Electronics Ltd Uk | Primary wire for marine and sub-sea cable |
| US9536635B2 (en) * | 2013-08-29 | 2017-01-03 | Wire Holdings Llc | Insulated wire construction for fire safety cable |
| CN106298037A (en) * | 2015-07-26 | 2017-01-04 | 常熟市谷雷特机械产品设计有限公司 | A kind of high pressure resistant layer material of high tension cable |
| RU2606500C1 (en) * | 2015-09-17 | 2017-01-10 | Акционерное общество "Лидер-Компаунд" | Peroxide-crosslinked composition for insulation of power cables |
| FR3081602B1 (en) * | 2018-05-22 | 2020-05-01 | Arkema France | MULTILAYER CABLES FOR OFFSHORE ENVIRONMENT |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3269862A (en) * | 1964-10-22 | 1966-08-30 | Raychem Corp | Crosslinked polyvinylidene fluoride over a crosslinked polyolefin |
| US3650827A (en) * | 1969-11-17 | 1972-03-21 | Electronized Chem Corp | Fep cables |
| US5206459A (en) * | 1991-08-21 | 1993-04-27 | Champlain Cable Corporation | Conductive polymeric shielding materials and articles fabricated therefrom |
| US5589028A (en) * | 1994-11-03 | 1996-12-31 | Elf Atochem North America, Inc. | Bonding method employing tie layers for adhering polyethylene to fluoropolymers |
-
1998
- 1998-09-17 GB GBGB9820214.6A patent/GB9820214D0/en not_active Ceased
-
1999
- 1999-09-17 WO PCT/GB1999/003116 patent/WO2000017889A1/en active IP Right Grant
- 1999-09-17 DE DE69930532T patent/DE69930532T2/en not_active Expired - Lifetime
- 1999-09-17 AT AT99947633T patent/ATE321345T1/en not_active IP Right Cessation
- 1999-09-17 CN CNB998110302A patent/CN1331160C/en not_active Expired - Lifetime
- 1999-09-17 TR TR2001/00761T patent/TR200100761T2/en unknown
- 1999-09-17 CZ CZ20010482A patent/CZ299046B6/en not_active IP Right Cessation
- 1999-09-17 IL IL14133899A patent/IL141338A0/en active IP Right Grant
- 1999-09-17 ID IDW20010554A patent/ID29877A/en unknown
- 1999-09-17 RU RU2001107973/09A patent/RU2231147C2/en not_active IP Right Cessation
- 1999-09-17 EP EP99947633A patent/EP1116243B1/en not_active Expired - Lifetime
- 1999-09-17 PL PL346214A patent/PL192515B1/en unknown
- 1999-09-17 HU HU0103585A patent/HU226699B1/en unknown
- 1999-09-17 JP JP2000571464A patent/JP2002525819A/en active Pending
- 1999-09-17 RO ROA200100291A patent/RO121928B1/en unknown
- 1999-09-17 BR BR9913843-3A patent/BR9913843A/en not_active IP Right Cessation
- 1999-09-17 AU AU61019/99A patent/AU766430B2/en not_active Expired
- 1999-09-17 CA CA002340386A patent/CA2340386C/en not_active Expired - Fee Related
- 1999-09-17 KR KR1020017002898A patent/KR100638181B1/en active IP Right Grant
- 1999-09-17 ES ES99947633T patent/ES2260937T3/en not_active Expired - Lifetime
-
2001
- 2001-02-08 IL IL141338A patent/IL141338A/en not_active IP Right Cessation
- 2001-02-12 ZA ZA200101181A patent/ZA200101181B/en unknown
- 2001-03-15 NO NO20011307A patent/NO324458B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR100638181B1 (en) | 2006-10-26 |
| PL346214A1 (en) | 2002-01-28 |
| AU6101999A (en) | 2000-04-10 |
| HUP0103585A3 (en) | 2002-04-29 |
| DE69930532D1 (en) | 2006-05-11 |
| JP2002525819A (en) | 2002-08-13 |
| CA2340386A1 (en) | 2000-03-30 |
| RO121928B1 (en) | 2008-07-30 |
| CN1318200A (en) | 2001-10-17 |
| ES2260937T3 (en) | 2006-11-01 |
| IL141338A0 (en) | 2002-03-10 |
| HU226699B1 (en) | 2009-07-28 |
| WO2000017889A1 (en) | 2000-03-30 |
| NO20011307D0 (en) | 2001-03-15 |
| RU2231147C2 (en) | 2004-06-20 |
| NO20011307L (en) | 2001-03-15 |
| EP1116243A1 (en) | 2001-07-18 |
| ATE321345T1 (en) | 2006-04-15 |
| IL141338A (en) | 2006-12-31 |
| CN1331160C (en) | 2007-08-08 |
| NO324458B1 (en) | 2007-10-22 |
| ZA200101181B (en) | 2002-05-13 |
| KR20010079751A (en) | 2001-08-22 |
| GB9820214D0 (en) | 1998-11-11 |
| ID29877A (en) | 2001-10-18 |
| BR9913843A (en) | 2001-08-14 |
| CA2340386C (en) | 2009-04-14 |
| CZ2001482A3 (en) | 2001-07-11 |
| AU766430B2 (en) | 2003-10-16 |
| EP1116243B1 (en) | 2006-03-22 |
| DE69930532T2 (en) | 2007-03-08 |
| TR200100761T2 (en) | 2001-09-21 |
| PL192515B1 (en) | 2006-10-31 |
| CZ299046B6 (en) | 2008-04-09 |
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