HUP0100703A2 - Gázfázisú katalitikus eljárás telítetlen szénhidrogének direkt oxidálására és aranybevonatú hordozós katalizátorok - Google Patents

Gázfázisú katalitikus eljárás telítetlen szénhidrogének direkt oxidálására és aranybevonatú hordozós katalizátorok

Info

Publication number
HUP0100703A2
HUP0100703A2 HU0100703A HUP0100703A HUP0100703A2 HU P0100703 A2 HUP0100703 A2 HU P0100703A2 HU 0100703 A HU0100703 A HU 0100703A HU P0100703 A HUP0100703 A HU P0100703A HU P0100703 A2 HUP0100703 A2 HU P0100703A2
Authority
HU
Hungary
Prior art keywords
unsaturated hydrocarbons
gaseous phase
catalytic oxidation
gold coated
gold particles
Prior art date
Application number
HU0100703A
Other languages
English (en)
Inventor
Herbert Dilcher
Ernst-Ulrich Dorf
Bernhard Lücke
Christoph Schild
Ulrich Schülke
Gerhard Wegener
Markus Weisbeck
Original Assignee
Bayer Ag.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Ag. filed Critical Bayer Ag.
Publication of HUP0100703A2 publication Critical patent/HUP0100703A2/hu
Publication of HUP0100703A3 publication Critical patent/HUP0100703A3/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/773—Nanoparticle, i.e. structure having three dimensions of 100 nm or less
    • Y10S977/775—Nanosized powder or flake, e.g. nanosized catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/89—Deposition of materials, e.g. coating, cvd, or ald
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/895—Manufacture, treatment, or detection of nanostructure having step or means utilizing chemical property
    • Y10S977/896—Chemical synthesis, e.g. chemical bonding or breaking
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/902—Specified use of nanostructure
    • Y10S977/904—Specified use of nanostructure for medical, immunological, body treatment, or diagnosis
    • Y10S977/931—Medical device coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A találmány epoxidok előállítására alkalmas katalitikus eljárásravonatkozik, amely szerint telítetlen szénhidrogéneket molekulárishidrogén jelenlétében molekuláris oxigénnel gázfázisban oxidálunk. Atalálmány tárgyát képezik továbbá az eljárás megvalósításáhozszükséges, nanométeres nagyságrendű aranyrészecskékkel bevontkatalizátorok is. A találmány szerinti eljárás megvalósításáhoznanométeres nagyságrendű aranyrészecskékkel bevont, adott esetbendotált titánoxid--hidrátból előállított és kalcinált katalizátortalkalmaznak. A találmány szerinti, aranyrészecskékkel bevont hordozóskatalizátorokat úgy állítják elő, hogy - adott esetben szulfátottartalmazó - titán-oxid-hidrátot a <leválasztásos/lecsapásos< módszerszerint bevonnak a hordozóanyag mennyiségére számítva 0,05-10 tömeg%,nanométeres nagyságrendű aranyrészecskékkel, majd az így kapottterméket mossák, szárítják és kalcinálják. Ó
HU0100703A 1998-02-06 1999-01-27 Method for the direct catalytic oxidation of unsaturated hydrocarbons in gaseous phase and gold coated supporting catalyst HUP0100703A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19804709A DE19804709A1 (de) 1998-02-06 1998-02-06 Verfahren zur katalytischen Direktoxidation ungesättigter Kohlenwasserstoffe in der Gasphase
PCT/EP1999/000530 WO1999040077A2 (de) 1998-02-06 1999-01-27 Verfahren zur katalytischen direktoxidation ungesättigter kohlenwasserstoffe in der gasphase

Publications (2)

Publication Number Publication Date
HUP0100703A2 true HUP0100703A2 (hu) 2001-06-28
HUP0100703A3 HUP0100703A3 (en) 2002-06-28

Family

ID=7856832

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0100703A HUP0100703A3 (en) 1998-02-06 1999-01-27 Method for the direct catalytic oxidation of unsaturated hydrocarbons in gaseous phase and gold coated supporting catalyst

Country Status (15)

Country Link
US (2) US6548682B1 (hu)
EP (1) EP1054879B1 (hu)
JP (1) JP2002502847A (hu)
KR (1) KR20010040710A (hu)
CN (1) CN1290259A (hu)
AU (1) AU2719999A (hu)
BR (1) BR9907695A (hu)
CA (1) CA2319613A1 (hu)
DE (2) DE19804709A1 (hu)
ES (1) ES2168851T3 (hu)
HU (1) HUP0100703A3 (hu)
ID (1) ID25501A (hu)
PT (1) PT1054879E (hu)
TW (1) TW458953B (hu)
WO (1) WO1999040077A2 (hu)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1125933A1 (en) * 2000-02-07 2001-08-22 Bayer Aktiengesellschaft Epoxidation catalyst containing metals of the lanthanoide series
US7118498B2 (en) 2000-06-16 2006-10-10 Skyhawke Technologies, Llc Personal golfing assistant and method and system for graphically displaying golf related information and for collection, processing and distribution of golf related data
US8172702B2 (en) 2000-06-16 2012-05-08 Skyhawke Technologies, Llc. Personal golfing assistant and method and system for graphically displaying golf related information and for collection, processing and distribution of golf related data
DE10049625A1 (de) * 2000-10-05 2002-04-11 Bayer Ag Verfahren zur katalytischen Direktoxidation ungesättigter Kohlenwasserstoffe in der Gasphase
US7121962B2 (en) 2000-12-19 2006-10-17 Reeves G George Golf round data system with cellular telephone and player help features
DE10362249B4 (de) * 2003-05-05 2014-05-15 Südzucker AG Mannheim/Ochsenfurt C1-selektive Oxidation von Oligosacchariden und die Verwendung eines Kohlenstoff geträgerten Gold-Katalysators für diese Oxidation
PL1663481T3 (pl) * 2003-09-26 2009-07-31 3M Innovative Properties Co Nanoskalowe katalizatory ze złota, środki aktywujące, nośniki oraz powiązane metodologie użyteczne do wytwarzania takich układów katalitycznych, zwłaszcza gdy złoto jest osadzane na nośniku z zastosowaniem fizycznego osadzania z fazy gazowej
WO2015073249A1 (en) * 2013-11-15 2015-05-21 Corning Incorporated Alkylene oxide synthesis
WO2015162562A1 (en) * 2014-04-22 2015-10-29 Sabic Global Technologies B.V. Method for the synthesis of supported gold (au) nanoparticles for epoxidation reactions

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63252908A (ja) 1987-04-08 1988-10-20 Agency Of Ind Science & Technol 金超微粒子固定化酸化物、その製造法、酸化触媒、還元触媒、可燃性ガスセンサ素子、及び電極用触媒
JPS6483513A (en) 1987-09-24 1989-03-29 Agency Ind Science Techn Ultrafine gold particle immobilized alkaline earth metallic compound, production thereof, oxidation catalyst, reduction catalyst and combustible gas sensor element
JPH02252610A (ja) 1989-03-24 1990-10-11 Agency Of Ind Science & Technol 金超微粒子固定化酸化物の製造法
JP2615432B2 (ja) 1994-10-28 1997-05-28 工業技術院長 金−酸化チタン含有触媒による炭化水素の部分酸化方法
WO1997034692A1 (fr) 1996-03-21 1997-09-25 Japan As Represented By Director General Of Agency Of Industrial Science And Technology Catalyseurs et procede pour l'oxydation partielle des hydrocarbures
DE19623609A1 (de) * 1996-06-13 1997-12-18 Basf Ag Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators
DE69704869T2 (de) 1996-07-01 2001-08-30 Dow Chemical Co Verfahren zur direkten oxidation von olefinen zu olefinoxiden
DE69731363T2 (de) * 1996-12-25 2005-12-22 Agency Of Industrial Science And Technology Verfahren zur Epoxid-Herstellung und Katalysator für die Verwendung darin
FR2771310B1 (fr) * 1997-11-24 2000-02-18 Rhone Poulenc Chimie Composition a base d'or et d'au moins un autre metal sur un support d'oxyde de cerium, d'oxyde de zirconium ou d'un melange de ces oxydes, procede de preparation et utilisation comme catalyseur
WO1999043431A1 (fr) 1998-02-24 1999-09-02 Japan As Represented By Director-General Of Agency Of Industrial Science And Technology Catalyseur d'oxydation partielle d'hydrocarbure insature
US5939569A (en) 1998-03-10 1999-08-17 Jones; C. Andrew Epoxidation process

Also Published As

Publication number Publication date
DE19804709A1 (de) 1999-08-12
BR9907695A (pt) 2000-11-14
WO1999040077A2 (de) 1999-08-12
AU2719999A (en) 1999-08-23
CA2319613A1 (en) 1999-08-12
EP1054879B1 (de) 2001-11-21
HUP0100703A3 (en) 2002-06-28
WO1999040077A3 (de) 1999-10-28
PT1054879E (pt) 2002-04-29
US20020165404A1 (en) 2002-11-07
ES2168851T3 (es) 2002-06-16
KR20010040710A (ko) 2001-05-15
TW458953B (en) 2001-10-11
US6548682B1 (en) 2003-04-15
US6504039B2 (en) 2003-01-07
EP1054879A2 (de) 2000-11-29
ID25501A (id) 2000-10-05
JP2002502847A (ja) 2002-01-29
DE59900678D1 (de) 2002-02-21
CN1290259A (zh) 2001-04-04

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