HUE035591T2 - Anionic surfactant-based ball-shaped toilet block - Google Patents
Anionic surfactant-based ball-shaped toilet block Download PDFInfo
- Publication number
- HUE035591T2 HUE035591T2 HUE11787809A HUE11787809A HUE035591T2 HU E035591 T2 HUE035591 T2 HU E035591T2 HU E11787809 A HUE11787809 A HU E11787809A HU E11787809 A HUE11787809 A HU E11787809A HU E035591 T2 HUE035591 T2 HU E035591T2
- Authority
- HU
- Hungary
- Prior art keywords
- oil
- toilet
- cleaning block
- weight
- acid
- Prior art date
Links
- 239000003945 anionic surfactant Substances 0.000 title description 6
- 238000004140 cleaning Methods 0.000 claims description 67
- -1 fatty alcohol salt Chemical class 0.000 claims description 55
- 239000002253 acid Substances 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 31
- 239000004480 active ingredient Substances 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 150000007513 acids Chemical class 0.000 claims description 14
- 239000003205 fragrance Substances 0.000 claims description 14
- 102000004190 Enzymes Human genes 0.000 claims description 13
- 108090000790 Enzymes Proteins 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000002736 nonionic surfactant Substances 0.000 claims description 11
- 239000000975 dye Substances 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 6
- 238000005260 corrosion Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 claims description 5
- 230000000536 complexating effect Effects 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 244000005700 microbiome Species 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims 1
- 241001553014 Myrsine salicina Species 0.000 claims 1
- 241001122767 Theaceae Species 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 claims 1
- 235000019634 flavors Nutrition 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 1
- 229910000679 solder Inorganic materials 0.000 claims 1
- 239000003921 oil Substances 0.000 description 45
- 235000019198 oils Nutrition 0.000 description 45
- 235000002639 sodium chloride Nutrition 0.000 description 20
- 230000000845 anti-microbial effect Effects 0.000 description 18
- 239000004615 ingredient Substances 0.000 description 18
- 235000019441 ethanol Nutrition 0.000 description 15
- 239000002304 perfume Substances 0.000 description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- 229910052708 sodium Inorganic materials 0.000 description 14
- 125000004432 carbon atom Chemical group C* 0.000 description 13
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 229940088598 enzyme Drugs 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 11
- 150000001298 alcohols Chemical class 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- 238000009472 formulation Methods 0.000 description 9
- 239000000314 lubricant Substances 0.000 description 8
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 230000000249 desinfective effect Effects 0.000 description 7
- 150000002170 ethers Chemical class 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 7
- 238000007493 shaping process Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 5
- 239000008139 complexing agent Substances 0.000 description 5
- 238000011010 flushing procedure Methods 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 229960004889 salicylic acid Drugs 0.000 description 4
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 235000010338 boric acid Nutrition 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 2
- OHBQPCCCRFSCAX-UHFFFAOYSA-N 1,4-Dimethoxybenzene Chemical compound COC1=CC=C(OC)C=C1 OHBQPCCCRFSCAX-UHFFFAOYSA-N 0.000 description 2
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 2
- FKUPPRZPSYCDRS-UHFFFAOYSA-N Cyclopentadecanolide Chemical compound O=C1CCCCCCCCCCCCCCO1 FKUPPRZPSYCDRS-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- 229940120146 EDTMP Drugs 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- ZFMSMUAANRJZFM-UHFFFAOYSA-N Estragole Chemical compound COC1=CC=C(CC=C)C=C1 ZFMSMUAANRJZFM-UHFFFAOYSA-N 0.000 description 2
- JUWUWIGZUVEFQB-UHFFFAOYSA-N Fenchyl acetate Chemical compound C1CC2C(C)(C)C(OC(=O)C)C1(C)C2 JUWUWIGZUVEFQB-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZYEMGPIYFIJGTP-UHFFFAOYSA-N O-methyleugenol Chemical compound COC1=CC=C(CC=C)C=C1OC ZYEMGPIYFIJGTP-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 241000018646 Pinus brutia Species 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000005844 Thymol Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- AKGGYBADQZYZPD-UHFFFAOYSA-N benzylacetone Chemical compound CC(=O)CCC1=CC=CC=C1 AKGGYBADQZYZPD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 235000017803 cinnamon Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 235000019820 disodium diphosphate Nutrition 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 2
- 229940038485 disodium pyrophosphate Drugs 0.000 description 2
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 150000002357 guanidines Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 229940039748 oxalate Drugs 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 229960003975 potassium Drugs 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- ZMQAAUBTXCXRIC-UHFFFAOYSA-N safrole Chemical compound C=CCC1=CC=C2OCOC2=C1 ZMQAAUBTXCXRIC-UHFFFAOYSA-N 0.000 description 2
- 239000010671 sandalwood oil Substances 0.000 description 2
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Chemical compound C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 238000005670 sulfation reaction Methods 0.000 description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 229960000790 thymol Drugs 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- 239000001226 triphosphate Substances 0.000 description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 2
- 239000010679 vetiver oil Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 1
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- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
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- 239000004224 potassium gluconate Substances 0.000 description 1
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- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000002568 propynyl group Chemical group [*]C#CC([H])([H])[H] 0.000 description 1
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- FCOCXFOQAWJIIT-UHFFFAOYSA-M sodium hydroxy(dioxido)phosphanium Chemical compound [Na+].OP([O-])=O FCOCXFOQAWJIIT-UHFFFAOYSA-M 0.000 description 1
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- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229940083982 sodium phytate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- FMYOMWCQJXWGEN-WYRLRVFGSA-M sodium;(2r,3r,4s,5r,6r)-2,3,4,5,6,7-hexahydroxyheptanoate Chemical compound [Na+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O)C([O-])=O FMYOMWCQJXWGEN-WYRLRVFGSA-M 0.000 description 1
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- 239000008117 stearic acid Substances 0.000 description 1
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- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
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- 150000008163 sugars Chemical class 0.000 description 1
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- 239000011975 tartaric acid Substances 0.000 description 1
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- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000010678 thyme oil Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 description 1
- FYZXEMANQYHCFX-UHFFFAOYSA-K tripotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate Chemical compound [K+].[K+].[K+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O FYZXEMANQYHCFX-UHFFFAOYSA-K 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- WJUFSDZVCOTFON-UHFFFAOYSA-N veratraldehyde Chemical compound COC1=CC=C(C=O)C=C1OC WJUFSDZVCOTFON-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/005—Devices adding disinfecting or deodorising agents to the bowl
-
- E—FIXED CONSTRUCTIONS
- E03—WATER SUPPLY; SEWERAGE
- E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
- E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
- E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010043848A DE102010043848A1 (de) | 2010-11-12 | 2010-11-12 | Kugelförmige WC-Steine auf Aniontensidbasis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HUE035591T2 true HUE035591T2 (en) | 2018-05-28 |
Family
ID=45033940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HUE11787809A HUE035591T2 (en) | 2010-11-12 | 2011-11-11 | Anionic surfactant-based ball-shaped toilet block |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US20130239313A1 (enExample) |
| EP (1) | EP2638137B1 (enExample) |
| JP (1) | JP5934715B2 (enExample) |
| KR (1) | KR20130119446A (enExample) |
| CN (1) | CN103210072B (enExample) |
| AU (1) | AU2011327998B2 (enExample) |
| BR (1) | BR112013011456A2 (enExample) |
| CA (1) | CA2817413C (enExample) |
| CR (1) | CR20130215A (enExample) |
| DE (1) | DE102010043848A1 (enExample) |
| GE (1) | GEP20176613B (enExample) |
| GT (1) | GT201300120A (enExample) |
| HU (1) | HUE035591T2 (enExample) |
| IL (1) | IL226254A0 (enExample) |
| MX (1) | MX2013005308A (enExample) |
| MY (1) | MY161254A (enExample) |
| NZ (1) | NZ611639A (enExample) |
| PH (1) | PH12013500926B1 (enExample) |
| PL (1) | PL2638137T3 (enExample) |
| RU (1) | RU2013126792A (enExample) |
| SG (1) | SG190192A1 (enExample) |
| WO (1) | WO2012062914A1 (enExample) |
| ZA (1) | ZA201304285B (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012106742A1 (de) | 2012-07-25 | 2014-01-30 | Geting Solutions Gmbh | Stückförmiges Mittel zur Applikation auf einem Sanitärgegenstand |
| US9234338B2 (en) | 2012-09-14 | 2016-01-12 | Impact Products, Llc | Fragrance control |
| USD720428S1 (en) | 2013-10-02 | 2014-12-30 | S.C. Johnson & Son, Inc. | Toilet rim block |
| USD720830S1 (en) | 2013-10-02 | 2015-01-06 | S.C. Johnson & Son, Inc. | Toilet rim block holder |
| USD720427S1 (en) | 2013-10-02 | 2014-12-30 | S.C. Johnson & Son, Inc. | Toilet rim block holder and toilet rim block |
| WO2016040341A1 (en) | 2014-09-08 | 2016-03-17 | S. C. Johnson & Son, Inc. | Toilet rimblock and method of making such rimblock |
| MX2017011370A (es) | 2015-03-05 | 2018-06-15 | Crossford Int Llc | Sistemas y métodos para limpieza de tubos por medio de tabletas. |
| USD752733S1 (en) | 2015-03-18 | 2016-03-29 | S.C. Johnson & Son, Inc. | Toilet rim block holder |
| USD752198S1 (en) | 2015-03-18 | 2016-03-22 | S.C. Johnson & Son, Inc. | Toilet rim block holder |
| DE102015215135A1 (de) | 2015-08-07 | 2017-02-09 | Henkel Ag & Co. Kgaa | WC-Stein und WC-Körbchen |
| USD791911S1 (en) * | 2015-09-15 | 2017-07-11 | Tomil S.R.O. | Toilet rim blocks |
| EP3168284A1 (en) * | 2015-11-13 | 2017-05-17 | Unilever N.V. | Shaped toilet cleaner block |
| USD784491S1 (en) | 2016-05-17 | 2017-04-18 | S. C. Johnson & Son, Inc. | Toilet rim block |
| USD789485S1 (en) | 2016-05-17 | 2017-06-13 | S. C. Johnson & Son, Inc. | Toilet rim block holder |
| US10669705B2 (en) | 2016-07-05 | 2020-06-02 | Willert Home Products, Inc. | Toilet bowl treatment apparatus and method of making same |
| US10493177B2 (en) | 2017-01-12 | 2019-12-03 | Impact Products, Llc | Solid state fragrancing |
| USD841120S1 (en) | 2017-01-31 | 2019-02-19 | S. C. Johnson & Son, Inc. | Toilet rim-block |
| USD850578S1 (en) | 2017-01-31 | 2019-06-04 | S. C. Johnson & Son, Inc. | Toilet rimblock |
| AU2018218188B2 (en) * | 2017-02-10 | 2018-12-06 | Wayne Desmond Burgis | Lavatory cleansing block |
| CN107503417A (zh) * | 2017-08-17 | 2017-12-22 | 福州大学厦门工艺美术学院 | 一种模块化移动式坐便器 |
| CN109701369B (zh) * | 2018-12-29 | 2021-04-16 | 陈红 | 一种利用柑橘皮渣制备的便池除臭丸 |
| CA3136356A1 (en) | 2019-04-12 | 2020-10-15 | Ecolab Usa Inc. | Antimicrobial multi-purpose cleaner and methods of making and using the same |
| USD912761S1 (en) | 2019-06-07 | 2021-03-09 | S. C. Johnson & Son, Inc. | Toilet rim-block |
| USD923139S1 (en) | 2019-06-07 | 2021-06-22 | S. C. Johnson & Son, Inc. | Set of toilet rim-blocks |
| USD914131S1 (en) | 2019-06-07 | 2021-03-23 | S. C. Johnson & Son, Inc. | Toilet rim-block holder |
| DE102019211571A1 (de) * | 2019-08-01 | 2021-02-04 | Henkel Ag & Co. Kgaa | Mehrphasiger Reinigungsmittelformkörper |
| DE102019211566A1 (de) * | 2019-08-01 | 2021-02-04 | Henkel Ag & Co. Kgaa | Reinigungsmittelformkörper |
| EP4061915A1 (en) * | 2019-11-19 | 2022-09-28 | Symrise AG | Home care product or formulation |
| US11499124B2 (en) | 2020-03-13 | 2022-11-15 | YFY Consumer Products, Co. | Solid granules used for cleaning agents |
| US11767495B2 (en) | 2020-03-13 | 2023-09-26 | YFY Consumer Products, Co. | Systems and methods for manufacturing solid granules |
| EP4011406A1 (de) | 2020-12-09 | 2022-06-15 | Henkel AG & Co. KGaA | Kontinuierlicher formprozess von kugelförmigen wc-steinen |
| KR102240245B1 (ko) * | 2021-01-07 | 2021-04-13 | 김종덕 | 소변 냄새 방지 기능을 강화한 반려동물용 수세식 배변판 |
| BR112023018191A2 (pt) * | 2021-03-08 | 2023-12-12 | Unilever Ip Holdings B V | Bloco formatado para limpeza de vaso sanitário, método de produção de um bloco formatado para limpeza de vaso sanitário e método de limpeza e/ou desinfecção e/ou desodorização do interior de um vaso sanitário |
| EP4496874A1 (en) | 2022-03-22 | 2025-01-29 | Unilever IP Holdings B.V. | A solid hard surface cleaning composition |
| EP4674934A1 (en) | 2024-07-01 | 2026-01-07 | RE.LE.VI. S.p.A. | Sanitary agent for cleaning and perfuming a sanitary apparatus |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE756790A (fr) * | 1969-10-01 | 1971-03-29 | Henkel & Cie Gmbh | Detergent faconne a base de surfactifs synthetiques |
| JPS6369146U (enExample) * | 1986-10-24 | 1988-05-10 | ||
| GB9013539D0 (en) * | 1990-06-18 | 1990-08-08 | Unilever Plc | Lavatory cleansing block |
| DE4439677A1 (de) | 1994-11-07 | 1996-05-09 | Henkel Kgaa | Reinigungsmittelstück für Spültoiletten |
| US6184192B1 (en) * | 1997-04-24 | 2001-02-06 | S. C. Johnson & Son, Inc. | Chlorinated in-tank toilet cleansing block |
| GB2333778B (en) * | 1998-01-29 | 2000-02-09 | Reckitt & Colman France | A lavatory block |
| WO2003042462A2 (en) * | 2001-11-13 | 2003-05-22 | Reckitt Benckiser Inc | Improvements relating to toilet bowl cleaning articles |
| CN1234624C (zh) * | 2002-06-04 | 2006-01-04 | 陈平 | 一种芳香除臭滤洁块及其制造方法 |
| DE102004020400A1 (de) * | 2004-04-23 | 2005-11-17 | Henkel Kgaa | Parfümierte Feststoffe |
| DE102008037723A1 (de) | 2008-08-14 | 2010-02-25 | Henkel Ag & Co. Kgaa | WC-Körbchen mit Spülwasserverteilelement |
| DE102009003088A1 (de) * | 2009-05-13 | 2010-11-18 | Henkel Ag & Co. Kgaa | Kugelförmige WC-Steine, Verfahren zu ihrer Herstellung und WC-Reinigungskörpchen mit kugelförmigen WC-Steinen |
| FR2957085B1 (fr) * | 2010-03-05 | 2012-06-01 | Eurvest | Bloc detergent pour toilettes, dispositif de nettoyage de toilettes comportant un bloc detergent et procede de fabrication d'un bloc detergent |
-
2010
- 2010-11-12 DE DE102010043848A patent/DE102010043848A1/de not_active Ceased
-
2011
- 2011-11-11 PL PL11787809T patent/PL2638137T3/pl unknown
- 2011-11-11 CA CA2817413A patent/CA2817413C/en active Active
- 2011-11-11 CN CN201180054080.3A patent/CN103210072B/zh not_active Expired - Fee Related
- 2011-11-11 KR KR1020137015026A patent/KR20130119446A/ko not_active Abandoned
- 2011-11-11 AU AU2011327998A patent/AU2011327998B2/en active Active
- 2011-11-11 GE GEAP201113113A patent/GEP20176613B/en unknown
- 2011-11-11 EP EP11787809.0A patent/EP2638137B1/de active Active
- 2011-11-11 MX MX2013005308A patent/MX2013005308A/es active IP Right Grant
- 2011-11-11 JP JP2013538212A patent/JP5934715B2/ja not_active Expired - Fee Related
- 2011-11-11 HU HUE11787809A patent/HUE035591T2/en unknown
- 2011-11-11 BR BR112013011456A patent/BR112013011456A2/pt not_active IP Right Cessation
- 2011-11-11 RU RU2013126792/04A patent/RU2013126792A/ru not_active Application Discontinuation
- 2011-11-11 SG SG2013035159A patent/SG190192A1/en unknown
- 2011-11-11 NZ NZ611639A patent/NZ611639A/en not_active IP Right Cessation
- 2011-11-11 MY MYPI2013001632A patent/MY161254A/en unknown
- 2011-11-11 PH PH1/2013/500926A patent/PH12013500926B1/en unknown
- 2011-11-11 WO PCT/EP2011/069965 patent/WO2012062914A1/de not_active Ceased
-
2013
- 2013-05-09 IL IL226254A patent/IL226254A0/en unknown
- 2013-05-09 US US13/890,837 patent/US20130239313A1/en not_active Abandoned
- 2013-05-10 CR CR20130215A patent/CR20130215A/es unknown
- 2013-05-10 GT GT201300120A patent/GT201300120A/es unknown
- 2013-06-11 ZA ZA2013/04285A patent/ZA201304285B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN103210072B (zh) | 2015-11-25 |
| MY161254A (en) | 2017-04-14 |
| AU2011327998A1 (en) | 2013-07-04 |
| EP2638137B1 (de) | 2017-08-23 |
| JP2014501801A (ja) | 2014-01-23 |
| MX2013005308A (es) | 2013-06-03 |
| EP2638137A1 (de) | 2013-09-18 |
| PH12013500926A1 (en) | 2013-07-08 |
| CA2817413A1 (en) | 2012-05-18 |
| HK1187362A1 (zh) | 2014-04-04 |
| ZA201304285B (en) | 2014-03-26 |
| GEP20176613B (en) | 2017-02-10 |
| PL2638137T3 (pl) | 2018-01-31 |
| SG190192A1 (en) | 2013-06-28 |
| US20130239313A1 (en) | 2013-09-19 |
| IL226254A0 (en) | 2013-07-31 |
| NZ611639A (en) | 2015-05-29 |
| PH12013500926B1 (en) | 2018-01-12 |
| JP5934715B2 (ja) | 2016-06-15 |
| KR20130119446A (ko) | 2013-10-31 |
| CA2817413C (en) | 2018-09-25 |
| DE102010043848A1 (de) | 2012-05-16 |
| CR20130215A (es) | 2013-06-28 |
| GT201300120A (es) | 2015-07-06 |
| RU2013126792A (ru) | 2014-12-20 |
| WO2012062914A1 (de) | 2012-05-18 |
| CN103210072A (zh) | 2013-07-17 |
| BR112013011456A2 (pt) | 2016-08-09 |
| AU2011327998B2 (en) | 2014-11-27 |
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