HRP20220785T1 - Postupak pretvorbe ugljičnog materijala u sintezni plin s niskim sadržajem katrana - Google Patents

Postupak pretvorbe ugljičnog materijala u sintezni plin s niskim sadržajem katrana Download PDF

Info

Publication number
HRP20220785T1
HRP20220785T1 HRP20220785TT HRP20220785T HRP20220785T1 HR P20220785 T1 HRP20220785 T1 HR P20220785T1 HR P20220785T T HRP20220785T T HR P20220785TT HR P20220785 T HRP20220785 T HR P20220785T HR P20220785 T1 HRP20220785 T1 HR P20220785T1
Authority
HR
Croatia
Prior art keywords
zone
pyrolytic
residue
partial oxidation
raw
Prior art date
Application number
HRP20220785TT
Other languages
English (en)
Inventor
Steve Kresnyak
Pavel ZÁHORÍK
Original Assignee
Expander Energy Inc.
Air Technic S.R.O.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Expander Energy Inc., Air Technic S.R.O. filed Critical Expander Energy Inc.
Publication of HRP20220785T1 publication Critical patent/HRP20220785T1/hr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B3/00—Coke ovens with vertical chambers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/16—Features of high-temperature carbonising processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/14—Continuous processes using gaseous heat-carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/16—Continuous processes simultaneously reacting oxygen and water with the carbonaceous material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/22—Arrangements or dispositions of valves or flues
    • C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/22—Arrangements or dispositions of valves or flues
    • C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
    • C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/34—Grates; Mechanical ash-removing devices
    • C10J3/36—Fixed grates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/34—Grates; Mechanical ash-removing devices
    • C10J3/40—Movable grates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/74—Construction of shells or jackets
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/026—Increasing the carbon monoxide content, e.g. reverse water-gas shift [RWGS]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/0923—Sludge, e.g. from water treatment plant
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/093—Coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/1246—Heating the gasifier by external or indirect heating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Industrial Gases (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Carbon And Carbon Compounds (AREA)

Claims (26)

1. Kontinuirani višestupanjski okomito sekvencirani postupak rasplinjavanja namijenjen pretvorbi čvrstog ugljičnog gorivnog materijala u sintezni plin s niskim sadržajem katrana u rasplinjaču koji sadrži: i) zonu pirolize (20); ii) zonu djelomične oksidacije (30), koja se nalazi okomito nizvodno od zone pirolize (20), te odvojenu od zone pirolize elementom za razdvajanje (32), koji sadrži više odušaka (34) nagnutih prema gore; iii) zonu redukcije (40), koja se nalazi okomito nizvodno od zone djelomične oksidacije i sadrži nagnutu perforiranu podnicu (42), jedan ili više otvora (46), smještenih centralno u odnosu na perforiranu podnicu, te centralno smješteni deflektor (48); naznačen time što je podnica nagnuta prema dolje i prema unutra prema jednom ili više otvora, pri čemu je perforirana podnica konfigurirana, dimenzioniranjem njenih perforacija (44), kako bi se prije svega omogućilo prolaženje siteznog plina (49) kroz nju, a spriječilo prolaženje pirolitičkog ostatka (24) koji može nastati u zoni pirolize, pri čemu je nagib perforirane podnice veći od nula stupnjeva, a manji od 60 stupnjeva; gdje se navedeni postupak sastoji u koracima: a) dodavanja ugljičnog gorivnog materijala (16) kroz gornji dio zone pirolize okomito prema dolje, prema donjem dijelu zone pirolize, tijekom pirolize goriva u pirolitičke pare (26), koje sadrži ugljkovodični materijal, i sirovi pirolitički ostatak (24), koji sadrži karbonizirani materijal i pepeo; b) izbornog dodavanja prvog oksidansa (22) u donji dio zone pirolize kako bi se postiglo temperaturu višu od 200 °C; c) usmjeravanja pirolitičkih para (26) u zonu djelomične oksidacije (POX), te usmjeravanja pirolitičkog ostatka prema dolje u zonu redukcije uz pomoć elementa za razdvajanje, pri čemu su odušci elementa za razdvajanje nagnuti prema gore kako bi se omogućilo odlazak pirolitičkih para u zonu djelomične oksidacije, a spriječilo prolaženje sirovog pirolitičkog ostatka u zonu djelomične oksidacije; d) dodavanja drugog oksidansa (36) u zonu djelomične oksidacije kako bi se postiglo temperaturu dovoljnu za reformiranje pirolitičkih para u sirovi sitezni plin koji sadrži značajno smanjene razine katrana; e) stvaranja sloja pirolitičkog ostatka (28) jednolične dubine iz sirovog pirolitičkog ostatka nastalog u koraku c) na podnici zone redukcije; f) propuštanja sirovog siteznog plina (38) iz koraka d) prema dolje kroz sirovi sloj pirolitičkog ostatka nastalog u koraku e), te provođenje endotermne reakcije između CO2 i/ili H2O u sirovom siteznom plinu i ugljika u karboniziranom materijalu u sloju pirolitičkog ostatka, uz istodobno kontroliranje pada tlaka u zoni redukcije, vremena zadržavajna i prostorne brzine protoka sirovog siteznog plina tijekom endotermne reakcije kako bi se dobilo sitezni plin koji uglavnom ne sadrži katran (49) i dekarbonizirani pirolitički ostatak (52); g) propuštanja siteznog plina koji uglavnom ne sadrži katran iz koraka f), u protustrujnom protoku prema gore, kako bi se grijalo zonu pirolize, te tako ohladilo sitezni plin koji uglavnom ne sadrži katran; h) prikupljanja siteznog plina koji uglavnom ne sadrži katran; i i) prikupljanja dekarboniziranog pirolitičkog ostatka s dna rasplinjača.
2. Postupak u skladu s patentnim zahtjevom 1, pri čemu se postupak provodi pod tlakom, nižim od Z 42,4 bar (600 psig), po mogućnosti između atmosferskog tlaka i 7,9 bar (100 psig).
3. Postupak u skladu s patentnim zahtjevom 1 ili 2 pri čemu ugljični gorivni materijal sadrži gorivo iz biomase kojeg se bira između drvne sječke, sječke od željezničkih pragova, otpadnog drva, šumarskog otpada, kanalizacijskog mulja, naftnog koksa, ugljena, krutog komunalnog otpada (MSW), goriva dobivenog iz otpada (RDF), ili bilo koje njihove kombinacije.
4. Postupak u skladu s patentnim zahtjevom 3, pri čemu se gorivo iz biomase dobiva postupkom cjepkanja, sjeckanja, ekstrudiranja, mehaničke obrade, sabijanja, peletiranja, granuliranja ili drobljenja.
5. Postupak u skladu s patentnim zahtjevom 3 ili 4, gdje se biogorivo poprska, obloži ili impregnira tekućim ili čvrstim ugljičnim materijalima.
6. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 do 5, pri čemu je temperatura stadija POX viša od 1250 °C, ili viša od temperature taljenje pepela kako bi se dobilo tekuću trosku.
7. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 do 6, pri čemu prvi i drugi oksidans sadrži zrak, obogaćeni zrak, kisik čistoće veće od 85%, težinski, kisik čistoće veće od 95%, težinski, ili njihovu kombinaciju.
8. Postupak u skladu s patentnim zahtjevom 7, pri čemu su prvi oksidans i drugi oksidans isti.
9. Postupak u skladu s patentnim zahtjevom 7, pri čemu su prvi oksidans i drugi oksidans različiti.
10. Postupak u skladu s patentnim zahtjevom 8, pri čemu prvi oksidans i/ili drugi oksidans dodatno sadrži H2O i/ili CO2.
11. Postupak u skladu s patentnim zahtjevom 10, pri čemu prvi oksidans sadrži zrak, obogaćeni zrak, kisik čistoće veće od 85%, težinski, kisik čistoće veće od 95%, težinski, ili njihovu kombinaciju, i drugi oksidans sadrži najmanje jedno od zraka, obogaćenog zraka, kisika čistoće veće od 85%, težinski, kisika čistoće veće od 95%, težinski, prethodno pomiješanih s H2O i/ili CO2.
12. Postupak u skladu s bilo kojim od patentnih zahtjeva 1 do 11, koji se dodatno sastoji u tresenju i/ili vrtnji sloja pirolitičkog ostatka.
13. Uređaj za kontinuirani višestupanjski okomito sekvencirani postupak rasplinjavanja namijenjen pretvorbi čvrstog ugljičnog gorivnog materijala u sitezni plin s niskim sadržajem katrana, gdje uređaj sadrži: i) zonu pirolize (20), u kojoj se gorivo pretvara u pirolitičke pare koje sadrže ugljkovodični materijal i sirovi pirolitički ostatak bogat ugljikom koji sadrži karbonizirani materijal i pepeo; ii) zonu djelomične oksidacije (30), koja se nalazi okomito nizvodno od zone pirolize, u kojoj se ugljkovodični materijal u pirolitičkim parama pretvara u sirovi sitezni plin koji sadrži H2, CO i CO2, te koja ima najmanje jedan ulaz za dodavanje jednog ili više oksidansa; iii) zonu endotermne redukcije (40), koja se nalazi okomito nizvodno od zone djelomične oksidacije, u kojoj se sirovi sitezni plin (38) pretvara u sitezni plin koji uglavnom ne sadrži katran (49), te u kojoj se smanjuje sadržaj ugljika u sirovom pirolitičkom ostatku kako bi se dobilo dekarbonizirani pirolitički ostatak (52); iv) element za razdvajanje (32), koji se nalazi između zone pirolize i zone djelomične oksidacije, gdje element za razdvajanje sadrži više odušaka (34) nagnutih prema gore kako bi se omogućilo odlazak pirolitičkih para (26) u zonu djelomične oksidacije i spriječilo prolaženje sirovog pirolitičkog ostatka (24) u zonu djelomične oksidacije, gdje je element za razdvajanje konfiguriran za usmjeravanje pirolitičkog ostatka u zonu redukcije; v) izlazni otvor (56) za dekarbonizirani pirolitički ostatak (52), koji se nalazi nizvodno od zone redukcije; vi) izlaz (50) za sitezni plin koji uglavnom ne sadrži katran, koji se nalazi nizvodno od zone redukcije; vii) zonu redukcije koja sadrži nagnutu perforiranu podnicu (42), jedan ili više otvora (46), smještenih centralno u odnosu na perforiranu podnicu, te centralno smješteni deflektor (48), naznačen time što: podnica je nagnuta prema dolje i prema unutra prema jednom ili više otvora, perforacije (44) su tako dimenzionirane da omoguće primarno prolaženje siteznog plina kroz nju prema izlazu za sitezni plin koji uglavnom ne sadrži katran i spriječe prolaženje sirovog pirolitičkog ostatka, a jedan ili više otvora su u fluidnoj komunikaciji s izlaznim otvorom (56), te konfigurirani za prolaženje dekarboniziranog pirolitičkog ostatka (52) kroz nju; pri čemu je nagib perforirane podnice veći od nula stupnjeva, a manji od 60 stupnjeva.
14. Uređaj u skladu s patentnim zahtjevom 13, koji dodatno sadrži prvi mehanizam u komunikaciji sa zonom redukcije, konfiguriran za povremeno ili kontinuirano pomicanje pirolitičkog ostatka s perforirane podnice prema jednom ili više otvora.
15. Uređaj u skladu s patentnim zahtjevom 14, pri čemu mehanizam sadrži tijelo za izguravanje konfigurirano za pomicanje po putu oko deflektora, gdje se tijelo za izguravanje nalazi u blizini perforirane podnice i prema van u odnosu na jedan ili više otvora.
16. Uređaj u skladu s patentnim zahtjevom 15, pri čemu tijelo za izguravanje sadrži jedan ili više krakova koji se pružaju radijalno prema van u odnosu na jedan ili više otvora.
17. Uređaj u skladu s patentnim zahtjevom 16, pri čemu krakovi imaju nagnutu površinu konfigurirana za stupanje u kontakt i izguravanje dijela pirolitičkog ostatka prema jednom ili više otvora tijekom pomicanja tijela za izguravanje.
18. Uređaj u skladu s bilo kojim od patentnih zahtjeva 15 to 17, koji dodatno sadrži upravljač konfiguriran za rad s mehanizmom koji ovisi o razlici tlaka izmjerenoj na lokaciji ispred sloja pirolitičkog ostatka i lokaciji iza perforirane podnice.
19. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 18, koji dodatno sadrži drugi mehanizam za izguravanje dekarboniziranog pirolitičkog ostatka iz donjeg sloja prema izlaznim otvorima.
20. Uređaj u skladu s patentnim zahtjevom 19, pri čemu prvi i drugi mehanizam djeluju međusobno neovisno.
21. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 20, pri čemu se zona pirolize, zona djelomične oksidacije i zona redukcije nalaze u jednom spremniku/komori.
22. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 21, koji dodatno sadrži vanjsku ljusku koja ima ulaz u ljusku u komunikaciji s izlazom za sitezni plin, te izlaz iz ljuske, pri čemu vanjska ljuska okružuje/opkoljava zonu pirolize, zonu djelomične oksidacije i zonu redukcije tvoreći kanal za protok siteznog plina prema izlazu iz ljuske.
23. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 22, pri čemu se na gornjem dijelu ljuske nalazi izlaz iz ljuske kako bi se omogućilo kretanje siteznog plina prema gore u kanalu radi omogućavanja posrednog toplinskog kontakta između siteznog plina i zone pirolize.
24. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 23, pri čemu se zona pirolize, zona djelomične oksidacije i zona redukcije nalaze u odvojenim spremnicima/komorama.
25. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 24, pri čemu je opseg donjeg dijela zone pirolize veći od opsega gornjeg dijela.
26. Uređaj u skladu s bilo kojim od patentnih zahtjeva 13 do 25, pri čemu je podnica zone redukcije konfigurirana za tresenje.
HRP20220785TT 2016-09-29 2017-09-29 Postupak pretvorbe ugljičnog materijala u sintezni plin s niskim sadržajem katrana HRP20220785T1 (hr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201662401711P 2016-09-29 2016-09-29
US15/419,722 US20180086994A1 (en) 2016-09-29 2017-01-30 Process For Converting Carbonaceous Material Into Low Tar Synthetic Gas
PCT/CA2017/051161 WO2018058252A1 (en) 2016-09-29 2017-09-29 Process for converting carbonaceous material into low tar synthesis gas
EP17854301.3A EP3519537B1 (en) 2016-09-29 2017-09-29 Process for converting carbonaceous material into low tar synthesis gas

Publications (1)

Publication Number Publication Date
HRP20220785T1 true HRP20220785T1 (hr) 2022-10-14

Family

ID=61687679

Family Applications (1)

Application Number Title Priority Date Filing Date
HRP20220785TT HRP20220785T1 (hr) 2016-09-29 2017-09-29 Postupak pretvorbe ugljičnog materijala u sintezni plin s niskim sadržajem katrana

Country Status (15)

Country Link
US (1) US20180086994A1 (hr)
EP (1) EP3519537B1 (hr)
CN (1) CN109906264A (hr)
AU (1) AU2017333732B2 (hr)
BR (1) BR112019006163B1 (hr)
CA (1) CA2989862C (hr)
CL (1) CL2019000833A1 (hr)
CZ (1) CZ308375B6 (hr)
DK (1) DK3519537T3 (hr)
HR (1) HRP20220785T1 (hr)
MX (1) MX2019003588A (hr)
PH (1) PH12019500607A1 (hr)
RU (1) RU2714816C1 (hr)
SI (1) SI3519537T1 (hr)
WO (1) WO2018058252A1 (hr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101617392B1 (ko) * 2015-11-13 2016-05-09 김현영 산업용 고온 개질기 및 개질 방법
FR3067038B1 (fr) * 2017-05-31 2020-02-14 Raymond Guyomarc'h Dispositif et installation de conversion de matieres premieres carbonees et/ou hydrocarbonees seches en gaz de synthese
MX2021006085A (es) * 2018-11-28 2021-07-06 African Rainbow Minerals Ltd Reactor y proceso de gasificacion y/o fusion de materiales de alimentos.
CN110699120A (zh) * 2019-09-29 2020-01-17 安徽香杨新能源科技发展股份有限公司 生物质气化炉除焦油装置
CN112725038B (zh) * 2019-10-29 2021-12-17 中国石油化工股份有限公司 一种煤与石油焦共气化系统及方法
US20230093433A1 (en) * 2020-02-10 2023-03-23 Eastman Chemical Company Treatment of light pyrolysis products by partial oxidation gasification
WO2021211514A1 (en) * 2020-04-13 2021-10-21 Eastman Chemical Company Vitrification materials to partial oxidation gasifier
CN111718737B (zh) * 2020-06-29 2021-07-09 中国科学院过程工程研究所 一种低粘结煤热解制备高品质油气的工艺方法及系统装置
CN112552933B (zh) * 2020-11-17 2021-12-10 玉环市维道科技有限公司 一种避免粘煤的炼焦炉用传输设备
GB2621637A (en) * 2022-08-19 2024-02-21 Getgo Recycling Ltd Method and system for processing waste material
GB2622377A (en) * 2022-09-13 2024-03-20 Gasification Consultancy Ltd Gasification

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2569715B1 (fr) * 1984-08-29 1986-09-05 Hissung Wolfgang Gazogene a sciure resineuse avec bruleur
DE102007005799B4 (de) * 2006-10-18 2018-01-25 Heinz-Jürgen Mühlen Verfahren zur Erzeugung eines wasserstoffreichen Produktgases
AU2008300900B2 (en) * 2007-09-18 2013-03-21 Thyssenkrupp Uhde Gmbh Gasification reactor and method for entrained-flow gasification
RU2495076C1 (ru) * 2012-07-25 2013-10-10 Закрытое Акционерное Общество Научно-Производственная Компания "Интергаз" Способ переработки горючих углерод- и/или углеводородсодержащих продуктов, реактор для его осуществления (варианты) и установка для переработки горючих углерод- и/или углеводородсодержащих продуктов
DE202012008777U1 (de) * 2012-09-13 2015-10-06 Big Dutchman International Gmbh Vorrichtung zur Erzeugung von Brenngas aus einem festen Brennstoff
CZ26592U1 (cs) * 2013-12-18 2014-03-10 Tarpo Spol.S R.O. Zařízení pro vícestupňové zplyňování uhlíkatých paliv
CZ28354U1 (cs) * 2015-03-31 2015-06-23 Pavel Záhořík Generátor plynu na zplyňování biopaliva, zejména dřevní štěpky

Also Published As

Publication number Publication date
CL2019000833A1 (es) 2019-08-16
CN109906264A (zh) 2019-06-18
EP3519537B1 (en) 2022-03-23
AU2017333732A1 (en) 2019-04-18
PH12019500607A1 (en) 2019-06-03
US20180086994A1 (en) 2018-03-29
CA2989862A1 (en) 2018-03-29
EP3519537A1 (en) 2019-08-07
BR112019006163A2 (pt) 2019-06-18
DK3519537T3 (da) 2022-06-27
EP3519537A4 (en) 2020-06-10
BR112019006163B1 (pt) 2022-08-09
RU2714816C1 (ru) 2020-02-19
CA2989862C (en) 2022-01-11
CZ308375B6 (cs) 2020-07-08
SI3519537T1 (sl) 2022-09-30
AU2017333732B2 (en) 2023-01-05
WO2018058252A1 (en) 2018-04-05
MX2019003588A (es) 2019-08-16
CZ2017802A3 (cs) 2018-04-11

Similar Documents

Publication Publication Date Title
HRP20220785T1 (hr) Postupak pretvorbe ugljičnog materijala u sintezni plin s niskim sadržajem katrana
US6941879B2 (en) Process and gas generator for generating fuel gas
Zhu et al. Co-gasification of beech-wood and polyethylene in a fluidized-bed reactor
JP5756231B2 (ja) バイオマスのガス化装置
Bridgwater et al. A review of biomass pyrolysis and pyrolysis technologies
US9051522B2 (en) Gasification reactor
AU2002220288A1 (en) Process and gas generator for generating fuel gas
PL195893B1 (pl) Sposób wytwarzania czystej energii z węgla kamiennego
FI126357B (en) Process and apparatus for gasification of raw material and gaseous product
WO2019065851A1 (ja) バイオマスのガス化装置
de Caprariis et al. Olive oil residue gasification and syngas integrated clean up system
CA2749822A1 (en) Reactor for generating a product gas by allothermic gasification of carbonaceous raw materials
JP2014125577A (ja) 生成ガスの製造方法、製造装置及びタール除去装置
US10982151B2 (en) Process for converting carbonaceous material into low tar synthesis gas
EP4185658A1 (en) Reactor and method for the pyrolysis of industrial or municipal waste and for the reduction and purification of pyrolysis gas from heavy hydrocarbons and carbon particles
WO2023164079A1 (en) Fixed bed gasifier
CN116376602A (zh) 一种热解气化炉
CZ306239B6 (cs) Zařízení pro vícestupňové zplyňování uhlíkatých paliv
WO2012011799A2 (en) System and method for thermal cracking of a hydrocarbons comprising mass
CZ29748U1 (cs) Zařízení pro vícestupňové zplyňování uhlíkatých paliv