HRP20210111T1 - Postupak nanošenja smjese za razgradnju spoja nox na betonskom elementu - Google Patents
Postupak nanošenja smjese za razgradnju spoja nox na betonskom elementu Download PDFInfo
- Publication number
- HRP20210111T1 HRP20210111T1 HRP20210111TT HRP20210111T HRP20210111T1 HR P20210111 T1 HRP20210111 T1 HR P20210111T1 HR P20210111T T HRP20210111T T HR P20210111TT HR P20210111 T HRP20210111 T HR P20210111T HR P20210111 T1 HRP20210111 T1 HR P20210111T1
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- Croatia
- Prior art keywords
- concrete element
- equal
- less
- mixture
- preferably equal
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 11
- 238000000034 method Methods 0.000 title claims 10
- 230000000593 degrading effect Effects 0.000 title 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 16
- 239000002245 particle Substances 0.000 claims 8
- 239000004408 titanium dioxide Substances 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 6
- 238000000354 decomposition reaction Methods 0.000 claims 6
- 230000001699 photocatalysis Effects 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 235000012239 silicon dioxide Nutrition 0.000 claims 3
- 239000000377 silicon dioxide Substances 0.000 claims 3
- -1 silicon dioxide compound Chemical class 0.000 claims 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 2
- 238000010998 test method Methods 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5041—Titanium oxide or titanates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/88—Handling or mounting catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4578—Coating or impregnating of green ceramics or unset concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/65—Coating or impregnation with inorganic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4591—Construction elements containing cleaning material, e.g. catalysts
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
- C04B2111/00827—Photocatalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Catalysts (AREA)
- Dispersion Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Claims (15)
1. Postupak nanošenja smjese za razgradnju spoja NOx na betonskom elementu (1), koji obuhvaća
– osiguravanje betonskog elementa (1) određene površine (4), i
– nanošenje smjese koja sadrži čestice titanijeva dioksida fotokatalitičkog djelovanja raspršene u kontinuiranoj fazi na površini (4) navedenog betonskog elementa (1);
pri čemu se navedena smjesa nanosi u količini koja je jednaka 100 ml/m2 ili veća, te
naznačena time da se čestice titanijeva dioksida nanose na površini (4) betonskog elementa (1) u količini od 5 g/m2 ili manje, poželjno 3 g/m2 ili manje, poželjnije 2 g/m2 ili manje, a najpoželjnije 1 g/m2 ili manje, i
time da smjesa nadalje sadrži spoj silicijeva dioksida koji sadrži alkalijski silikat, i
time da je kontinuirana faza voda.
2. Postupak prema zahtjevu 1, pri čemu je učinkovitost razgradnje spoja NOx, izmjerena prema ispitnom postupku u skladu s normom ISO 22197-1, jednaka 10 % ili veća, poželjno jednaka 15 % ili veća, poželjnije jednaka 20 % ili veća, a najpoželjnije jednaka 30 % ili veća, na navedenoj površini betonske komponente.
3. Postupak prema zahtjevu 1 ili 2, pri čemu se smjesa nanosi u količini koja je jednaka 150 ml/m2 ili veća, a poželjno jednaka 200 ml/m2 ili veća.
4. Postupak prema bilo kojem prethodnom zahtjevu, pri čemu je koncentracija navedenih čestica titanijeva dioksida u navedenoj smjesi jednaka 2,5 wt% ili manja, poželjno jednaka 1,5 wt% ili manja, a poželjnije jednaka 1,0 wt% ili manja.
5. Postupak prema bilo kojem prethodnom zahtjevu, pri čemu smjesa barem djelomično prodire u poroznu strukturu betonskog elementa (1).
6. Postupak prema bilo kojem prethodnom zahtjevu, pri čemu smjesa ne sadrži nikakvo vezivo.
7. Postupak prema bilo kojem prethodnom zahtjevu, pri čemu gornja površina (4) betonskog elementa poprima hidrofilna svojstva nakon nanošenja smjese.
8. Postupak prema bilo kojem prethodnom zahtjevu, pri čemu je učinkovitost razgradnje spoja NOx jednaka 2,5 % ili veća, poželjno jednaka 5 % ili veća, a poželjnije jednaka 10 % ili veća, na dubini od 0,5 mm ispod navedene površine betonske komponente.
9. Postupak prema bilo kojem prethodnom zahtjevu, pri čemu se omjer količine spoja silicijeva dioksida u odnosu na količinu čestica titanijeva dioksida u smjesi kreće u rasponu od 1 : 1 do 15 : 1.
10. Betonski element (1) koji ima svojstva razgradnje spoja NOx, i koji sadrži čestice titanijeva dioksida fotokatalitičkog djelovanja u količini jednakoj 5 g/m2 ili manje, a poželjno jednakoj 3 g/m2 ili manje, i spoj silicijeva dioksida koji sadrži alkalijski silikat, te pri čemu je učinkovitost razgradnje spoja NOx, izmjerena prema ispitnom postupku u skladu s normom ISO 22197-1, jednaka 5 % ili veća, poželjno jednaka 10 % ili veća, poželjnije jednaka 15 % ili veća, a najpoželjnije jednaka 20 % ili veća, primjerice 30 %, na površini (4) betonskog elementa (1).
11. Betonski element prema zahtjevu 10, pri čemu se čestice titanijeva dioksida fotokatalitičkog djelovanja nalaze u gornjem dijelu (5) navedenog betonskog elementa (1), u sloju koji seže od gornje površine betonskog elementa poželjno do dubine od 1,5 mm, poželjnije do dubine od 2,0 mm, a najpoželjnije do dubine od 2,5 mm.
12. Betonski element prema bilo kojem od zahtjeva 10 – 11, pri čemu su čestice titanijeva dioksida heterogeno raspoređene u betonskom elementu (1).
13. Betonski element prema bilo kojem od zahtjeva 10 – 12, pri čemu je učinkovitost razgradnje spoja NOx jednaka 2,5 % ili veća, poželjno jednaka 5 % ili veća, a poželjnije jednaka 10 % ili veća, na dubini od 0,5 mm ispod gornje površine (4) navedenog betonskog elementa (1).
14. Betonski element prema bilo kojem od zahtjeva 10 – 13, pri čemu je primarna veličina čestica titanijeva dioksida fotokatalitičkog djelovanja manja od 50 nm, poželjno manja od 30 nm, a poželjnije manja od 20 nm.
15. Betonski element prema bilo kojem od zahtjeva 10 – 14, pri čemu je gornja površina (4) betonskog elementa (1) hidrofilna.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE1350470 | 2013-04-12 | ||
| PCT/SE2014/050454 WO2014168576A1 (en) | 2013-04-12 | 2014-04-11 | A method of applying a nox degrading composition on a concrete element |
| EP14783398.2A EP2984059B1 (en) | 2013-04-12 | 2014-04-11 | A method of applying a nox degrading composition on a concrete element |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HRP20210111T1 true HRP20210111T1 (hr) | 2021-03-19 |
Family
ID=51690154
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HRP20210111TT HRP20210111T1 (hr) | 2013-04-12 | 2021-01-21 | Postupak nanošenja smjese za razgradnju spoja nox na betonskom elementu |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US11465944B2 (hr) |
| EP (1) | EP2984059B1 (hr) |
| CN (2) | CN111233511A (hr) |
| CA (1) | CA2908426C (hr) |
| DK (1) | DK2984059T3 (hr) |
| ES (1) | ES2846075T3 (hr) |
| HR (1) | HRP20210111T1 (hr) |
| MX (1) | MX2015014068A (hr) |
| PL (1) | PL2984059T3 (hr) |
| PT (1) | PT2984059T (hr) |
| SI (1) | SI2984059T1 (hr) |
| WO (1) | WO2014168576A1 (hr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK2411141T3 (da) | 2009-03-23 | 2014-03-31 | Vaelinge Photocatalytic Ab | Frembringelse af kolloide titandioxidnanopartikelopslæm-ninger med opretholdt krystallinitet ved anvendelse af en perlemølle med perler i mikrometerstørrelse |
| US11045798B2 (en) | 2011-07-05 | 2021-06-29 | Valinge Photocatalytic Ab | Coated wood products and method of producing coated wood products |
| US9375750B2 (en) | 2012-12-21 | 2016-06-28 | Valinge Photocatalytic Ab | Method for coating a building panel and a building panel |
| US9945075B2 (en) | 2013-09-25 | 2018-04-17 | Valinge Photocatalytic Ab | Method of applying a photocatalytic dispersion |
| WO2015051210A1 (en) * | 2013-10-03 | 2015-04-09 | Oldcastle Architectural, Inc. | Cementitious product |
| US11452988B2 (en) * | 2015-02-27 | 2022-09-27 | Photocat A/S | Photocatalytic concrete product and a method to produce a photocatalytic concrete product |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5560773A (en) * | 1995-06-13 | 1996-10-01 | Fmc Corporation | Penetrating sealant composition |
| IT1286492B1 (it) | 1996-08-07 | 1998-07-15 | Italcementi Spa | Legante idraulico con migliorate proprieta' di costanza di colore |
| JP3428381B2 (ja) | 1996-08-16 | 2003-07-22 | 三菱マテリアル株式会社 | ＮＯｘ浄化舗装構造物 |
| IT1312119B1 (it) * | 1999-06-25 | 2002-04-04 | Italcementi Spa | Uso di preparazioni fotocatalitiche di titanio biossido colloidale per conservare l'aspetto originario di manufatti camentizi,lapidei o |
| JP5025856B2 (ja) * | 2001-05-23 | 2012-09-12 | 東曹産業株式会社 | 表面強化材 |
| JP2005015307A (ja) | 2003-06-27 | 2005-01-20 | Kansai Paint Co Ltd | コンクリートの塗装工法 |
| CN1220732C (zh) * | 2003-07-28 | 2005-09-28 | 东南大学 | 具有降解汽车尾气功能的沥青及其制备工艺 |
| JP5113985B2 (ja) * | 2004-09-30 | 2013-01-09 | 株式会社大林組 | 光触媒の担持方法及び光触媒を担持した多孔質材 |
| CN101384680B (zh) * | 2006-02-20 | 2012-05-30 | 多摩化学工业株式会社 | 均匀分散性光催化涂覆液及其制造方法、以及使用它而得到的光催化活性复合材料 |
| US8465805B2 (en) * | 2007-10-25 | 2013-06-18 | Walter Henry Huber | Glass veneer on ceramics |
| US20100297434A1 (en) | 2007-11-16 | 2010-11-25 | Bildningsagenten 3117 Ab | Photocatalytic boards or panels and a method of manufacturing thereof |
| CN101254406A (zh) * | 2007-12-06 | 2008-09-03 | 哈尔滨工业大学 | 一种汽车尾气降解材料及其应用 |
| CN101224417A (zh) * | 2008-01-23 | 2008-07-23 | 北京大学 | 一种高热稳定性的磷掺杂氧化钛光催化剂及其制备方法 |
| DK2411141T3 (da) | 2009-03-23 | 2014-03-31 | Vaelinge Photocatalytic Ab | Frembringelse af kolloide titandioxidnanopartikelopslæm-ninger med opretholdt krystallinitet ved anvendelse af en perlemølle med perler i mikrometerstørrelse |
| KR101136014B1 (ko) * | 2009-04-14 | 2012-04-18 | 주식회사 해성기업 | 발수성과 대기정화성을 가지는 하이드록시 아파타이트가 피복된 이산화티탄을 포함하는 광촉매 도료 조성물 |
| CN101591195A (zh) * | 2009-06-11 | 2009-12-02 | 浙江工业大学 | 一种纳米光催化透水混凝土制品及其制备方法 |
| CN101747085A (zh) * | 2009-12-22 | 2010-06-23 | 张天宝 | 一种混凝土表面密封剂与施工方法 |
| US20110189471A1 (en) | 2010-01-29 | 2011-08-04 | Valinge Innovation Ab | Method for applying nanoparticles |
| FR2968653B1 (fr) * | 2010-12-08 | 2013-05-03 | Lafarge Sa | Element en beton recouvert d'un revetement photocatalytique |
| CN102561627A (zh) * | 2010-12-30 | 2012-07-11 | 佐贺光触媒环保科技(大连)有限公司 | 具有光触媒抗菌效果的瓷砖 |
| CN102247755A (zh) * | 2011-04-26 | 2011-11-23 | 同济大学 | 一种分解汽车尾气的方法 |
| US11045798B2 (en) | 2011-07-05 | 2021-06-29 | Valinge Photocatalytic Ab | Coated wood products and method of producing coated wood products |
| EP2827987B1 (en) | 2012-03-20 | 2021-05-26 | Välinge Photocatalytic AB | Photocatalytic compositions comprising titanium dioxide and anti-photogreying additives |
| US9375750B2 (en) | 2012-12-21 | 2016-06-28 | Valinge Photocatalytic Ab | Method for coating a building panel and a building panel |
| US9945075B2 (en) | 2013-09-25 | 2018-04-17 | Valinge Photocatalytic Ab | Method of applying a photocatalytic dispersion |
-
2014
- 2014-04-11 EP EP14783398.2A patent/EP2984059B1/en active Active
- 2014-04-11 CN CN202010165705.4A patent/CN111233511A/zh active Pending
- 2014-04-11 CA CA2908426A patent/CA2908426C/en active Active
- 2014-04-11 ES ES14783398T patent/ES2846075T3/es active Active
- 2014-04-11 CN CN201480020340.9A patent/CN105102400A/zh active Pending
- 2014-04-11 DK DK14783398.2T patent/DK2984059T3/da active
- 2014-04-11 WO PCT/SE2014/050454 patent/WO2014168576A1/en active Application Filing
- 2014-04-11 PL PL14783398T patent/PL2984059T3/pl unknown
- 2014-04-11 PT PT147833982T patent/PT2984059T/pt unknown
- 2014-04-11 MX MX2015014068A patent/MX2015014068A/es unknown
- 2014-04-11 US US14/783,493 patent/US11465944B2/en active Active
- 2014-04-11 SI SI201431751T patent/SI2984059T1/sl unknown
-
2021
- 2021-01-21 HR HRP20210111TT patent/HRP20210111T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US11465944B2 (en) | 2022-10-11 |
| CN111233511A (zh) | 2020-06-05 |
| WO2014168576A1 (en) | 2014-10-16 |
| US20160075606A1 (en) | 2016-03-17 |
| CN105102400A (zh) | 2015-11-25 |
| DK2984059T3 (da) | 2021-01-25 |
| EP2984059A1 (en) | 2016-02-17 |
| EP2984059B1 (en) | 2020-11-18 |
| PT2984059T (pt) | 2021-01-28 |
| PL2984059T3 (pl) | 2021-05-04 |
| CA2908426A1 (en) | 2014-10-16 |
| CA2908426C (en) | 2021-10-19 |
| MX2015014068A (es) | 2015-12-11 |
| SI2984059T1 (sl) | 2021-03-31 |
| ES2846075T3 (es) | 2021-07-28 |
| EP2984059A4 (en) | 2016-12-28 |
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