HRP20161698T1 - Trajni super hidrofobni premazi - Google Patents

Trajni super hidrofobni premazi Download PDF

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Publication number
HRP20161698T1
HRP20161698T1 HRP20161698TT HRP20161698T HRP20161698T1 HR P20161698 T1 HRP20161698 T1 HR P20161698T1 HR P20161698T T HRP20161698T T HR P20161698TT HR P20161698 T HRP20161698 T HR P20161698T HR P20161698 T1 HRP20161698 T1 HR P20161698T1
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Croatia
Prior art keywords
super hydrophobic
particles
hydrophobic coating
coating according
resin
Prior art date
Application number
HRP20161698TT
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English (en)
Inventor
John T. Simpson
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Ut-Battelle, Llc
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Priority claimed from US13/631,212 external-priority patent/US10150875B2/en
Application filed by Ut-Battelle, Llc filed Critical Ut-Battelle, Llc
Publication of HRP20161698T1 publication Critical patent/HRP20161698T1/hr

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/26Silicon- containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/22Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/031Powdery paints characterised by particle size or shape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1681Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Materials For Medical Uses (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Claims (23)

1. Super hidrofobni premaz, naznačen time, da obuhvaća: smolu; i mnoštvo čestica od kojih svaka sadržava: najmanje jedno super hidrofobno područje i barem jedno hidrofilno područje, pri čemu svaka čestica ima trodimenzionalnu, nanostrukturiranu površinsku topologiju, s većim brojem pora, pri čemu su čestice kovalentno vezane na smolu pomoću najmanje jedne hidrofilne regije, pri čemu smola ne ispunjava pore čestica tako da se trodimenzionalna površinska topologija čestica održava, i pri čemu mnoštvo čestica čini najmanje jednu površinu smole super hidrofobnom, pri čemu barem jedno hidrofilno područje sadržava kemijsku skupinu odabranu iz skupine koju čine silan koji sadržava najmanje jednu funkcionalnu skupinu odabranu iz skupine koja se sastoji od (3-glicidoksipropil) trimetoksisilana, (3-metoksisililpropil)dietilen-triamina i njihove kombinacije.
2. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je barem dio super hidrofobnih čestica ugrađen unutar smole, tako da se okružene smolom.
3. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je smola hidrofobna.
4. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da svaka čestica sadržava hidrofobni premaz, hidrofobni premaz sukladan je površini super hidrofobnih čestica tako da se očuva nanostrukturirana površinska topologija.
5. Super hidrofobni premaz u skladu s patentnim zahtjevom 4, naznačen time, da super hidrofobna čestica sadržava čestice dijatomejske zemlje.
6. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je porozna jezgra hidrofilna.
7. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je porozna jezgra silikat.
8. Super hidrofobni premaz u skladu s patentnim zahtjevom 7, naznačen time, da je silikat obrađen jetkanjem kako bi se dobila nanostrukturirana površinska topologija.
9. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je volumen pora svake čestice ispunjen smolom manje od 50 %.
10. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je promjer svake čestice između 1-20 mm.
11. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je promjer svake čestice je između 10 - 20 mm.
12. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da je omjer volumena čestica i smole 1: 1 i 1: 10.
13. Super hidrofobni premaz u skladu s patentnim zahtjevom 1, naznačen time, da barem jedno super hidrofobno područje sadržava kemijska skupinu odabranu iz skupine koju čine fluoromonomer, monomer parafinskog ugljikovodika i njihove kombinacije.
14. Super hidrofobni premaz u skladu s patentnim zahtjevom 14, naznačen time, da je fluoromonomer heptadekafluoro-l,l,2,2-tetrahidrodecil)triklorosilan.
15. Super hidrofobni premaz u skladu s patentnim zahtjevom 14, naznačen time, da je monomer parafinskog ugljikovodika silan na bazi alkila.
16. Postupak za proizvodnju amfoternih čestica, naznačen time, da postupak podrazumijeva reakciju mnoštva čestica koje sadrže silicijev dioksid s najmanje jednim superhidrofobnim silanom i najmanje jednim sredstvom za spajanje, čime se dobiva mnoštvo amfoternih čestica, pri čemu svaka amfoterna čestica sadržava barem jedno superhidrofobno područje i barem jedno hidrofilno područje, barem jedno hidrofilno područje sadržava kemijsku skupinu odabranu iz skupine koja se sastoji od silana koji sadržava najmanje jednu funkcionalnu skupinu odabranu iz skupine koju čine (3-glicidoksipropil)trimetoksisilan, (3-trimetoksisililpropil)dietilen-triamin, i njihove kombinacije.
17. Postupak u skladu s patentnim zahtjevom 16, naznačen time, da se reakcija odvija u jednom koraku.
18. Postupak u skladu s patentnim zahtjevom 16, naznačen time, da se reakcija odvija u prvom koraku i u drugom koraku, pri čemu u prvom koraku mnoštvo reagira s barem jedan superhidrofobnim silanom, i pri čemu u drugom koraku više čestica reagira s najmanje jednim sredstvom za spajanje.
19. Postupak u skladu s patentnim zahtjevom 16, naznačen time, da barem jedno super hidrofobno područje sadržava kemijsku skupinu odabranu iz skupine koja se sastoji od fluormonomera, monomera parafinskog ugljikovodika i njihovih kombinacija.
20. Postupak u skladu s patentnim zahtjevom 19, naznačen time, da je fluormonomer (heptadekafluoro -1,1,2,2- tetrahidrodecil)triklorsilan.
21. Postupak u skladu s patentnim zahtjevom 16, naznačen time, da je sredstvo za spajanje monomer parafinskog ugljikovodika.
22. Postupak u skladu s patentnim zahtjevom 21, naznačen time, da je monomer parafinskog ugljikovodika silan na bazi alkila.
23. Postupak za proizvodnju superhidrofobnog premaza, naznačen time, da postupak obuhvaća raspršivanje mnoštva amfoternih čestica u otopini koja sadržava polimerno vezivno sredstvo, pri čemu svaka amfoterna čestica sadržava barem jedno superhidrofobno područje i najmanje jedno hidrofilno područje, barem jedno hidrofilno područje sadržava kemijsku skupinu odabranu iz skupine koju čini silan sa najmanje jednom funkcionalnom skupinom odabranom iz skupine koju čine (3-glicidoksipropil) trimetoksisilan, (3-metoksisililpropil)dietilentriamin i njihove kombinacije, i pri čemu polimerno vezivo sadržava veći broj funkcionalnih skupina koje su se sposobne kovalentno vezati na najmanje jedno hidrofilno područje svake amfoterne čestice.
HRP20161698TT 2012-09-28 2016-12-13 Trajni super hidrofobni premazi HRP20161698T1 (hr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/631,212 US10150875B2 (en) 2012-09-28 2012-09-28 Superhydrophobic powder coatings
US13/793,394 US9828521B2 (en) 2012-09-28 2013-03-11 Durable superhydrophobic coatings
PCT/US2013/052662 WO2014051852A2 (en) 2012-09-28 2013-07-30 Durable superhydrophobic coatings
EP13747923.4A EP2900768B1 (en) 2012-09-28 2013-07-30 Durable superhydrophobic coatings

Publications (1)

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HRP20161698T1 true HRP20161698T1 (hr) 2017-02-24

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Country Status (20)

Country Link
US (1) US9828521B2 (hr)
EP (1) EP2900768B1 (hr)
JP (1) JP6298061B2 (hr)
KR (1) KR20150065790A (hr)
CN (1) CN104822777B (hr)
AU (1) AU2013324205B2 (hr)
CA (1) CA2886232C (hr)
CY (1) CY1118355T1 (hr)
DK (1) DK2900768T3 (hr)
ES (1) ES2606677T3 (hr)
HK (1) HK1210491A1 (hr)
HR (1) HRP20161698T1 (hr)
HU (1) HUE032456T2 (hr)
LT (1) LT2900768T (hr)
PL (1) PL2900768T3 (hr)
PT (1) PT2900768T (hr)
RS (1) RS55549B1 (hr)
SI (1) SI2900768T1 (hr)
SM (1) SMT201600451B (hr)
WO (1) WO2014051852A2 (hr)

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