GB994373A - Foaming agent, highly resistant to breakdown in particular suitable as a fire extinguisher - Google Patents

Foaming agent, highly resistant to breakdown in particular suitable as a fire extinguisher

Info

Publication number
GB994373A
GB994373A GB113262A GB113262A GB994373A GB 994373 A GB994373 A GB 994373A GB 113262 A GB113262 A GB 113262A GB 113262 A GB113262 A GB 113262A GB 994373 A GB994373 A GB 994373A
Authority
GB
United Kingdom
Prior art keywords
mol
neutralized
product
sulphated
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB113262A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
B O S A Prodotti Chimici Botta
Original Assignee
B O S A Prodotti Chimici Botta
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by B O S A Prodotti Chimici Botta filed Critical B O S A Prodotti Chimici Botta
Publication of GB994373A publication Critical patent/GB994373A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0094High foaming compositions
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Anionic surface-active foaming agents are prepared as follows: (a) lauryl alcohol (1 mol.) is condensed with ethylene oxide (2 mols.), the condensate is sulphated with chlorosulphonic acid (0.95 mol.) and the product is neutralized with caustic soda; (b) lauryl alcohol is esterified with excess of phosphoric acid and phosphoric anhydride and the product is neutralized with monoethanolamine; (c) tridecyl alcohol (0.5 mol.) is condensed with ethylene oxide (1.5 mols.), the condensate is sulphated with chlorosulphonic acid (0.48 mol.) and the product is neutralized with monoethanolamine; (d) decyl alcohol (0.5 mol.) is condensed with a -propylene oxide (1.5 mols.), the condensate is sulphated as in (c) and the product is neutralized with caustic soda; (e) lauryl alcohol (0.5 mol.) is condensed with ethylene oxide (0.75 mol.), the condensate is sulphated with sulphuric acid (0.9 mol.) and the product is neutralized with sodium carbonate; (f) lauric acid monopropanolamide is sulphated with sulphuric acid or oleum of low SO3 content and the product is neutralized with sodium carbonate. Foam stabilizers are prepared by condensing aliphatic alcohols, containing at least 8 carbon atoms in the molecule, with up to 3 molecular proportions of an alkylene oxide.ALSO:A highly breakdown-resistant foaming composition is constituted by an anionic surface-active foaming ester of the general formula R1-F-(OA)n-X-C and a foam stabilizer of the general formula R2-F-(OA)mH, in which formulae R1 and R2 represent aliphatic, aromatic or alkylaromatic hydrocarbon radicals of at least 8 carbon atoms, with at least 40% by weight of the anionic surface active agent being made of up a compound in which R1 is aliphatic, F represents the residue of an active hydrogen end function (i.e. an alcoholic, phenolic, carboxyl, amino or amido group, the stabilizing agent containing at least 40% by weight of a compound in which F is the residue of an alcohol), (OA) represents an oxyalkylene radical, n is 1-10, m is 0-3, x represents an inorganic (e.g. sulphuric or phosphoric) acid residue, and C represents a cation (preferably potassium or ammonium) neutralizing said residue, the foaming composition containing not more than 10% of free alkylolamide in cases where the anionic surface active agent is formed from an alkylolamide.
GB113262A 1961-01-11 1962-01-11 Foaming agent, highly resistant to breakdown in particular suitable as a fire extinguisher Expired GB994373A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT45961 1961-01-11

Publications (1)

Publication Number Publication Date
GB994373A true GB994373A (en) 1965-06-10

Family

ID=11098733

Family Applications (1)

Application Number Title Priority Date Filing Date
GB113262A Expired GB994373A (en) 1961-01-11 1962-01-11 Foaming agent, highly resistant to breakdown in particular suitable as a fire extinguisher

Country Status (4)

Country Link
BE (1) BE612534A (en)
CH (1) CH453087A (en)
DE (1) DE1232029B (en)
GB (1) GB994373A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4578208A (en) * 1983-05-07 1986-03-25 Henkel Kommanditgesellschaft Auf Aktien Compositions and processes for cleaning and passivating metals

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2506062A (en) * 1946-01-12 1950-05-02 Gen Aniline & Film Corp Fire extinguishing composition and method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4578208A (en) * 1983-05-07 1986-03-25 Henkel Kommanditgesellschaft Auf Aktien Compositions and processes for cleaning and passivating metals

Also Published As

Publication number Publication date
BE612534A (en)
DE1232029B (en) 1967-01-05
CH453087A (en) 1968-05-31

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