GB986198A - Manufacture of ª‰-methylmercaptopropionic aldehyde - Google Patents
Manufacture of ª‰-methylmercaptopropionic aldehydeInfo
- Publication number
- GB986198A GB986198A GB3824161A GB3824161A GB986198A GB 986198 A GB986198 A GB 986198A GB 3824161 A GB3824161 A GB 3824161A GB 3824161 A GB3824161 A GB 3824161A GB 986198 A GB986198 A GB 986198A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction
- weight
- acrolein
- less
- cobalt salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
b -Methylmercaptopropionic aldehyde is produced by reacting acrolein with an excess of methylmercaptan at -30 DEG to +50 DEG C. in the presence of a cobalt salt of an organic acid. The reaction, which may be performed at atmospheric pressure, is preferably performed employing an acrolein to methymercaptan molar ratio of less than 1 : 1.6, but above 1 : 1, and in the presence of less than 5% by weight of water or under anhydrous conditions. The cobalt salt may be used alone or on an inert carrier and, preferably, is employed as 0.1 to 0.5% by weight of the weight of acrolein. In a continuous process the first runnings from the distillation of the reaction product may be returned to the reaction vessel to act as a moderator in the reaction of the invention. The examples relate to the use of cobalt acetate, naphthenate and methylmercaptide as catalyst. Specification 687,483 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1306460A CH385183A (en) | 1960-11-22 | 1960-11-22 | Production of B-methyl mercaptopropionaldehyde |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB986198A true GB986198A (en) | 1965-03-17 |
Family
ID=4388953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3824161A Expired GB986198A (en) | 1960-11-22 | 1961-10-25 | Manufacture of ª‰-methylmercaptopropionic aldehyde |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE609967A (en) |
| CH (1) | CH385183A (en) |
| ES (1) | ES271521A1 (en) |
| GB (1) | GB986198A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4048232A (en) * | 1973-04-21 | 1977-09-13 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process for the production of 3-methylmercaptopropionaldehyde |
| US5663409A (en) * | 1995-06-07 | 1997-09-02 | Novus International, Inc. | Process for the preparation of 3-(methylthio) propanal and 2-hydroxy-4-(methylthio) butanenitrile |
-
1960
- 1960-11-22 CH CH1306460A patent/CH385183A/en unknown
-
1961
- 1961-10-25 GB GB3824161A patent/GB986198A/en not_active Expired
- 1961-10-26 ES ES0271521A patent/ES271521A1/en not_active Expired
- 1961-11-06 BE BE609967A patent/BE609967A/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4048232A (en) * | 1973-04-21 | 1977-09-13 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process for the production of 3-methylmercaptopropionaldehyde |
| US5663409A (en) * | 1995-06-07 | 1997-09-02 | Novus International, Inc. | Process for the preparation of 3-(methylthio) propanal and 2-hydroxy-4-(methylthio) butanenitrile |
| US5705675A (en) * | 1995-06-07 | 1998-01-06 | Novus International, Inc. | Processes for the preparation of 3-(methylthio)propanal and 2-hydroxy-4-(methylthio)butanenitrile |
Also Published As
| Publication number | Publication date |
|---|---|
| CH385183A (en) | 1964-12-15 |
| ES271521A1 (en) | 1962-10-01 |
| BE609967A (en) | 1962-03-01 |
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