GB978954A - Improvements in or relating to electrolytic recording media - Google Patents
Improvements in or relating to electrolytic recording mediaInfo
- Publication number
- GB978954A GB978954A GB18274/61A GB1827461A GB978954A GB 978954 A GB978954 A GB 978954A GB 18274/61 A GB18274/61 A GB 18274/61A GB 1827461 A GB1827461 A GB 1827461A GB 978954 A GB978954 A GB 978954A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nitrate
- solution
- chloride
- compound
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/20—Duplicating or marking methods; Sheet materials for use therein using electric current
Abstract
An electrolytic recording medium comprises a sheet of paper impregnated with an electrolytically conducting, e.g. aqueous, solution containing a compound of a metal, capable of being oxidized in the presence of electrolytically produced alkalinity, and a polyhydroxyphenolic compound or an aromatic polyamine which, on passage of an electric current between electrodes contacting the paper, reacts with the oxidized metal compound produced to form a distinctive colour. Suitable metal compounds are: manganous, cobaltous or nickelous chloride, chromic or silver nitrate, stannous sulphate, plumbous nitrate, thallous nitrate or sulphate, vanadium tribromide or trichloride. The pH of the solution may range between 2.5 and 8.5. Suitable polyhydroxyphenolic compounds are: gallic acid, catechol, gentisic acid, hydroquinone and pyrogallol. Suitable aromatic polyamines are: o- and p-phenylene diamine, benzidene and their salts, diphenylamine hydrochloride and tolidine hydrochloride. A stabilizer, such as hydrazine, hydroxylamine or a salt thereof, thiourea, an alkyl thiorea and dithiobiuret, may be included in the solution, which may also contain sodium chloride, sodium or potassium nitrate and sodium hydroxide. The electrodes need not be consumed during recording. A preferred solution contains the following substances in parts by weight: manganous chloride 1.3, gallic acid 1.0 and sodium chloride 5.0.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3123260A | 1960-05-23 | 1960-05-23 | |
US50886A US3122488A (en) | 1960-05-23 | 1960-08-22 | Electrical recording medium |
Publications (1)
Publication Number | Publication Date |
---|---|
GB978954A true GB978954A (en) | 1965-01-01 |
Family
ID=26706986
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB18274/61A Expired GB978954A (en) | 1960-05-23 | 1961-05-19 | Improvements in or relating to electrolytic recording media |
Country Status (2)
Country | Link |
---|---|
US (1) | US3122488A (en) |
GB (1) | GB978954A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2341884A1 (en) * | 1976-02-19 | 1977-09-16 | Mita Industrial Co Ltd | ELECTRICAL RECORDING ELEMENT AND PROCEDURE |
FR2484082A1 (en) * | 1980-06-05 | 1981-12-11 | Electricite De France | Permanent recording of remote information on paper - using facing electrodes, one carrying developer-contg. paper |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3399121A (en) * | 1964-11-18 | 1968-08-27 | Mallory & Co Inc P R | Anodic printing by means of a hydrogen ion sensitive precipitation reaction |
JPS53100509A (en) * | 1977-02-16 | 1978-09-02 | Kobe Steel Ltd | Alarm controlling method |
EP1057653A1 (en) * | 1999-06-04 | 2000-12-06 | I.P.T. - Impression Printing Technologies B.V. | Method of producing color changes |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2082735A (en) * | 1937-06-01 | Finger printing method | ||
US168466A (en) * | 1875-10-05 | Improvement in solutions for chemical telegraphs | ||
US1343978A (en) * | 1916-06-03 | 1920-06-22 | Charles H Little | Method of and material for making drawings and other records |
US2358839A (en) * | 1940-10-25 | 1944-09-26 | Faximile Inc | Electrolytic recording |
US2430254A (en) * | 1942-12-23 | 1947-11-04 | Rca Corp | Fibrous sheet material for producing dyes thereon by electrolytic oxidation |
US2570096A (en) * | 1947-01-09 | 1951-10-02 | Pierce Company | Facsimile wet electrolytic recording |
US2663656A (en) * | 1952-05-15 | 1953-12-22 | Minnesota Mining & Mfg | Heat-sensitive copying paper |
US2776252A (en) * | 1953-04-23 | 1957-01-01 | Faximile Inc | Dry electrical recording medium |
GB786496A (en) * | 1956-12-20 | 1957-11-20 | Muirhead & Co Ltd | Improvements in or relating to electrolytic recording media |
-
1960
- 1960-08-22 US US50886A patent/US3122488A/en not_active Expired - Lifetime
-
1961
- 1961-05-19 GB GB18274/61A patent/GB978954A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2341884A1 (en) * | 1976-02-19 | 1977-09-16 | Mita Industrial Co Ltd | ELECTRICAL RECORDING ELEMENT AND PROCEDURE |
FR2484082A1 (en) * | 1980-06-05 | 1981-12-11 | Electricite De France | Permanent recording of remote information on paper - using facing electrodes, one carrying developer-contg. paper |
Also Published As
Publication number | Publication date |
---|---|
US3122488A (en) | 1964-02-25 |
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