GB977263A - Stabilisation of trimethylolpropane polyester lubricating oil - Google Patents

Stabilisation of trimethylolpropane polyester lubricating oil

Info

Publication number
GB977263A
GB977263A GB32622/61A GB3262261A GB977263A GB 977263 A GB977263 A GB 977263A GB 32622/61 A GB32622/61 A GB 32622/61A GB 3262261 A GB3262261 A GB 3262261A GB 977263 A GB977263 A GB 977263A
Authority
GB
United Kingdom
Prior art keywords
alkoxy
particularly preferred
dialkoxydiphenylamines
acyloxydiphenylamines
acyloxydiphenylamine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB32622/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB977263A publication Critical patent/GB977263A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M3/00Liquid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single liquid substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/286Esters of polymerised unsaturated acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/062Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08Resistance to extreme temperature
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/12Gas-turbines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/12Gas-turbines
    • C10N2040/13Aircraft turbines

Abstract

Trimethylol propane polyester lubricating oils are stabilized against deterioration by incorporating 0.1% to 5% by weight of either p-alkoxy-diphenylanimes, p-p1-dialkoxydiphenylamines or p-acyloxydiphenylamines in which the alkoxy and acyloxy groups contain 1-8 carbon atoms, and the acyloxy group is the residue of a carboxylic acid. Particularly preferred p-alkoxy- and p,p1-dialkoxyphenylamines are p-methoxy-, p,p1 -dimethoxy-, p-isopropoxy-, and p,p1-diiso-propoxydiphenylamine. The p-alkoxy- or p,p1-dialkoxy compounds may have an aryl substituent attached to the alkyl portion, thus p-benzyloxydiphenylamine is a preferred compound. A particularly preferred p-acyloxydiphenylamine is p-acetoxydiphenylamine. The inhibitor is mixed with the oil preferably to form a homogeneous mixture and may be used with other additives e.g. a metal deactivator, dye, viscosity index improver, pour point depressant, anti-foaming additive, detergent, and lubricity or extreme pressure additive.ALSO:Trimethylolpropane polyester lubricating oils are stabilized against deterioration by incorporating 0.1-5% by weight of either p-alkoxydiphenylamines, p,p1 - dialkoxydiphenylamines or p-acyloxydiphenylamines in which the alkoxy and acyloxy groups contain 1-8 carbon atoms, and the acyloxy group is the residue of a carboxylic acid. Particularly preferred p-alkoxy and p,p1-dialkoxydiphenylamines are p-methoxy-, p,p1-dimethoxy-, p-isopropoxy -, and p,p1 - diisopropxydiphenylamine. The p-alkoxy or p,p1-dialkoxy compounds may have an aryl substituent attached to the alkyl portion, thus p-benzyl-oxydiphenylamine is a preferred compound. A particularly preferred p-acyloxydiphenylamine is p-acetoxydiphenylamine.
GB32622/61A 1960-09-16 1961-09-12 Stabilisation of trimethylolpropane polyester lubricating oil Expired GB977263A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US5636060A 1960-09-16 1960-09-16

Publications (1)

Publication Number Publication Date
GB977263A true GB977263A (en) 1964-12-02

Family

ID=22003879

Family Applications (1)

Application Number Title Priority Date Filing Date
GB32622/61A Expired GB977263A (en) 1960-09-16 1961-09-12 Stabilisation of trimethylolpropane polyester lubricating oil

Country Status (2)

Country Link
DE (1) DE1158653B (en)
GB (1) GB977263A (en)

Also Published As

Publication number Publication date
DE1158653B (en) 1963-12-05

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