GB976919A - Process for the production of alkali salts of cyclohexane carboxylic acid - Google Patents
Process for the production of alkali salts of cyclohexane carboxylic acidInfo
- Publication number
- GB976919A GB976919A GB2563163A GB2563163A GB976919A GB 976919 A GB976919 A GB 976919A GB 2563163 A GB2563163 A GB 2563163A GB 2563163 A GB2563163 A GB 2563163A GB 976919 A GB976919 A GB 976919A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali
- production
- hydrogenation
- cyclohexane carboxylic
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
In a process for the production of alkali salts of cyclohexane carboxylic acids by the catalytic hydrogenation of alkali benzoates in aqueous solution, the hydrogenation is carried out in the presence of catalysts containing metallic nickel and/or cobalt and at a temperature of 120-220 DEG C. preferably 140-180 DEG C. and at a pressure of above 20 atmospheres. The material used for the hydrogenation may consist of the alkali benzoate solutions obtained by direct extraction with aqueous alkali hydroxide from the crude oxidation products of toluol. The catalytic hydrogenation may be carried out continuously by conveying the aqueous alkali benzoate solutions through stationary catalysts or by causing them to flow together with suspended catalysts. Several examples are given.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2563163A GB976919A (en) | 1963-06-27 | 1963-06-27 | Process for the production of alkali salts of cyclohexane carboxylic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2563163A GB976919A (en) | 1963-06-27 | 1963-06-27 | Process for the production of alkali salts of cyclohexane carboxylic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB976919A true GB976919A (en) | 1964-12-02 |
Family
ID=10230796
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2563163A Expired GB976919A (en) | 1963-06-27 | 1963-06-27 | Process for the production of alkali salts of cyclohexane carboxylic acid |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB976919A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3459512A (en) * | 1965-01-20 | 1969-08-05 | Ici Ltd | Centrifugal recovery of copper-vanadium catalyst from adipic acid reaction mixture |
-
1963
- 1963-06-27 GB GB2563163A patent/GB976919A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3459512A (en) * | 1965-01-20 | 1969-08-05 | Ici Ltd | Centrifugal recovery of copper-vanadium catalyst from adipic acid reaction mixture |
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