GB976707A - Improvements in or relating to the desulphurisation of hydrocarbon oils - Google Patents

Improvements in or relating to the desulphurisation of hydrocarbon oils

Info

Publication number
GB976707A
GB976707A GB12373/61A GB1237361A GB976707A GB 976707 A GB976707 A GB 976707A GB 12373/61 A GB12373/61 A GB 12373/61A GB 1237361 A GB1237361 A GB 1237361A GB 976707 A GB976707 A GB 976707A
Authority
GB
United Kingdom
Prior art keywords
oil
sulphur
hydrocarbon oils
hydrogen peroxide
peracid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB12373/61A
Inventor
Alfred Bentley Webster
Norman James Herbert Small
Richard Rigby
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Research Ltd
Original Assignee
Shell Research Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL276740D priority Critical patent/NL276740A/xx
Application filed by Shell Research Ltd filed Critical Shell Research Ltd
Priority to GB12373/61A priority patent/GB976707A/en
Priority to US183714A priority patent/US3163593A/en
Priority to FR893310A priority patent/FR1325139A/en
Priority to DE19621470636 priority patent/DE1470636A1/en
Publication of GB976707A publication Critical patent/GB976707A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/06—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates

Abstract

The sulphur content of hydrocarbon oils, at least 50 vol. % boiling above 250 DEG C., is reduced by treating the oil with an organic peracid, or a mixture of organic acids and hydrogen peroxide such as to give rise to the formation of a peracid, to yield products containing both oxygen and sulphur, and subjecting the thus treated oil to a thermal after-treatment, preferably above 350 DEG C., which decomposes at least a proportion of said products to give hydrocarbons and volatile sulphur compounds. The hydrocarbon oil may be treated dissolved in a low-boiling organic solvent, for example benzene or carbon tetrachloride. Preferred oxidants are mixtures of hydrogen peroxide with formic or acetic acid. The thermal treatment may be effected in the presence of an alkaline material such as dolomite or lime.
GB12373/61A 1961-04-06 1961-04-06 Improvements in or relating to the desulphurisation of hydrocarbon oils Expired GB976707A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NL276740D NL276740A (en) 1961-04-06
GB12373/61A GB976707A (en) 1961-04-06 1961-04-06 Improvements in or relating to the desulphurisation of hydrocarbon oils
US183714A US3163593A (en) 1961-04-06 1962-03-30 Desulfurization of heavy oils
FR893310A FR1325139A (en) 1961-04-06 1962-04-04 Process for reducing the sulfur content of a heavy hydrocarbon oil
DE19621470636 DE1470636A1 (en) 1961-04-06 1962-04-04 Process for reducing the sulfur content of a sulfur-containing heavy hydrocarbon oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB12373/61A GB976707A (en) 1961-04-06 1961-04-06 Improvements in or relating to the desulphurisation of hydrocarbon oils

Publications (1)

Publication Number Publication Date
GB976707A true GB976707A (en) 1964-12-02

Family

ID=10003352

Family Applications (1)

Application Number Title Priority Date Filing Date
GB12373/61A Expired GB976707A (en) 1961-04-06 1961-04-06 Improvements in or relating to the desulphurisation of hydrocarbon oils

Country Status (5)

Country Link
US (1) US3163593A (en)
DE (1) DE1470636A1 (en)
FR (1) FR1325139A (en)
GB (1) GB976707A (en)
NL (1) NL276740A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004099346A1 (en) * 2003-05-06 2004-11-18 Petroleo Brasiliero S.A. Process for the extractive oxidation of contaminants from raw hydrocarbon streams

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE625074A (en) * 1961-11-24
NL6602260A (en) * 1965-02-23 1966-08-24
US3413307A (en) * 1965-05-10 1968-11-26 Exxon Research Engineering Co Desulfurization process
US4485007A (en) * 1982-06-15 1984-11-27 Environmental Research And Technology Inc. Process for purifying hydrocarbonaceous oils
US5284635A (en) * 1989-09-05 1994-02-08 Societe Francaise Hoechst Process for the elimination of hydrogen sulfide by using water-in-oil emulsions
US5310479A (en) * 1991-12-04 1994-05-10 Mobil Oil Corporation Process for reducing the sulfur content of a crude
US6827845B2 (en) * 2001-02-08 2004-12-07 Bp Corporation North America Inc. Preparation of components for refinery blending of transportation fuels
US20030094400A1 (en) * 2001-08-10 2003-05-22 Levy Robert Edward Hydrodesulfurization of oxidized sulfur compounds in liquid hydrocarbons
DE10223805A1 (en) * 2002-05-28 2003-12-11 Gummi Jaeger Gmbh Device for aerating water
US7128829B1 (en) 2003-05-29 2006-10-31 Uop Llc Removal of impurities from liquid hydrocarbon streams
US20050218038A1 (en) * 2004-03-31 2005-10-06 Nero Vincent P Pre-treatment of hydrocarbon feed prior to oxidative desulfurization
US20090242459A1 (en) * 2008-03-26 2009-10-01 General Electric Company Oxidative desulfurization of fuel oil
MX358123B (en) 2011-10-24 2018-08-06 Aditya Birla Nuvo Ltd An improved process for the production of carbon black.
US9410042B2 (en) 2012-03-30 2016-08-09 Aditya Birla Science And Technology Company Ltd. Process for obtaining carbon black powder with reduced sulfur content
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US20180230389A1 (en) 2017-02-12 2018-08-16 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US11198824B2 (en) * 2019-05-16 2021-12-14 Alternative Petroleum Technologies Holdings Corp. System and method for liquid hydrocarbon desulfurization

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1972102A (en) * 1930-12-12 1934-09-04 Atlantic Refining Co Hydrocarbon oil treatment
US2414963A (en) * 1944-03-10 1947-01-28 Standard Oil Co Process of removing sulphur from mineral oil
US2749284A (en) * 1950-11-15 1956-06-05 British Petroleum Co Treatment of sulphur-containing mineral oils with kerosene peroxides

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004099346A1 (en) * 2003-05-06 2004-11-18 Petroleo Brasiliero S.A. Process for the extractive oxidation of contaminants from raw hydrocarbon streams

Also Published As

Publication number Publication date
US3163593A (en) 1964-12-29
NL276740A (en)
DE1470636A1 (en) 1968-12-05
FR1325139A (en) 1963-04-26

Similar Documents

Publication Publication Date Title
GB976707A (en) Improvements in or relating to the desulphurisation of hydrocarbon oils
GB1425850A (en) Process for producing hydrocarbon material of reduced sulphur content
GB972803A (en) Desulphurisation of hydrocarbon materials
FR1334749A (en) Process for preparing carbon tetrachloride addition compounds with organic hydrocarbon compounds
KR930021598A (en) Method for Purifying Fluorinated Carboxylic Acid
ES408055A1 (en) Catalyst recycle
KR840003707A (en) Pitch for carbon fiber
GB910735A (en) Production of hydroquinone
US1459084A (en) Process of treating acid sludge
US2302825A (en) Fortification and decarbonizing of sulphuric acid
GB1089136A (en) Improvements relating to the production of sulphonic acids
US2409614A (en) Refining sulfate turpentine
US2473930A (en) Process for bleaching glyceridic esters
GB927809A (en) Improvements in and relating to glycols
GB914416A (en) Process for the stabilization of polymers of ethylenically unsaturated hydrocarbons
GB974143A (en) Improvements relating to the production of alcohols
ES303816A1 (en) A combined procedure to treat a distilled agriculture of hydrocarbon. (Machine-translation by Google Translate, not legally binding)
GB879653A (en) Improvements in or relating to the hypochlorite treatment of light hydrocarbon oils
GB1015254A (en) Process for removing nitric oxide from gases containing the same
GB700463A (en) Improvements in or relating to the treatment of rubber
GB634935A (en) Process for the reconcentration of spent mineral acids
GB1007703A (en) Process and apparatus for the continuous manufacture of low molecular weight fatty acids containing mainly acetic acid by paraffin oxidation
GB951822A (en) Improvements in heating oils
GB1032633A (en) An improved process for the elimination of peroxide from ethers
GB1048800A (en) Process for the separation of p-cresol from cresol mixtures