GB975922A - Polymethine dyes,processes of making them and photographic elements containing them - Google Patents
Polymethine dyes,processes of making them and photographic elements containing themInfo
- Publication number
- GB975922A GB975922A GB8638/61A GB863861A GB975922A GB 975922 A GB975922 A GB 975922A GB 8638/61 A GB8638/61 A GB 8638/61A GB 863861 A GB863861 A GB 863861A GB 975922 A GB975922 A GB 975922A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- dyes
- formula
- pyridinium
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0091—Methine or polymethine dyes, e.g. cyanine dyes having only one heterocyclic ring at one end of the methine chain, e.g. hemicyamines, hemioxonol
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
- G03C1/83—Organic dyestuffs therefor
- G03C1/832—Methine or polymethine dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
9-Formylvinyl-julolidine is prepared by adding paraldehyde to 9-formyl-julolidine in concentrated sulphuric acid at 0 DEG C., pouring the product on ice and treating with sodium carbonate.ALSO:The Specification relates to methine dyes of the general Formula I <FORM:0975922/C4-C5/1> wherein Q is a pyridinium or quinolinium group, substituted or not, and joined to the carbon atom through its nitrogen atom, W is a benzoyl, cyano or 2-benzothiazolyl group, P is a dialkylamino-aryl or 9-julolidinyl group or the group <FORM:0975922/C4-C5/2> (to give a symmetrical dye), m is 0 or 1 or, when the dyes are symmetrical, m may be 2, and X is an anion. The unsymmetrical dyes are prepared by condensing a compound of the formula P1-CH(=CH-CH)m=O (where P1 is dialkylamino-aryl or 9-julolidinyl) with a pyridinium or quinolinium salt of Formula V [Q-CH2-W]\sJx\sK. The symmetrical dyes are prepared by condensing a salt of Formula V with a trialkoxypropene, a dialkoxymethyl acetate, a trialkyl orthoformate or glutaconic aldehyde dianil hydrochloride. The pyridinium group Q may carry a bromine atom or methyl group in the 3-position or a phenyl substituent.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14139A US3094418A (en) | 1960-03-10 | 1960-03-10 | Silver halide meulsions containing cationic oxonol and benzylidene dyes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB975922A true GB975922A (en) | 1964-11-25 |
Family
ID=21763776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8638/61A Expired GB975922A (en) | 1960-03-10 | 1961-03-09 | Polymethine dyes,processes of making them and photographic elements containing them |
Country Status (2)
Country | Link |
---|---|
US (1) | US3094418A (en) |
GB (1) | GB975922A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3352680A (en) * | 1964-05-04 | 1967-11-14 | Eastman Kodak Co | Sensitizing and filter dyes for photographic elements |
US3314794A (en) * | 1964-05-13 | 1967-04-18 | Eastman Kodak Co | Ultraviolet absorbers |
US3637395A (en) * | 1970-04-09 | 1972-01-25 | Eastman Kodak Co | Silver halide emulsions containing cyclic enamine cyanine dyes |
US4017484A (en) * | 1971-07-14 | 1977-04-12 | Bayer Aktiengesellschaft | Cationic dyestuffs |
US5451494A (en) * | 1994-04-28 | 1995-09-19 | Eastman Kodak Company | Photographic elements containing acyl substituted oxonol dyes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2395879A (en) * | 1946-03-05 | Cyanine dyestuffs | ||
BE462493A (en) * | 1945-01-19 | |||
BE509612A (en) * | 1951-03-02 | |||
US2882160A (en) * | 1955-05-10 | 1959-04-14 | Sperry Rand Corp | Sensitizing dyes from 2-methyl-5, 6-dihydro-4-cyclopentathiazoles |
-
1960
- 1960-03-10 US US14139A patent/US3094418A/en not_active Expired - Lifetime
-
1961
- 1961-03-09 GB GB8638/61A patent/GB975922A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
US3094418A (en) | 1963-06-18 |
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