GB969764A - Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins - Google Patents
Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefinsInfo
- Publication number
- GB969764A GB969764A GB355762A GB355762A GB969764A GB 969764 A GB969764 A GB 969764A GB 355762 A GB355762 A GB 355762A GB 355762 A GB355762 A GB 355762A GB 969764 A GB969764 A GB 969764A
- Authority
- GB
- United Kingdom
- Prior art keywords
- metal
- alumina
- silica
- olefins
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
A polymerization catalyst (see Division C3) component is made by reacting a dry, inorganic metal or metaloid oxide, of particle size less than 1 micron, other than silica, alumina, or alumina-silica, e.g. titania zirconia, thoria and magnesia having surface hydroxyl groups, with a Group IVA, VA, VIA metal halide or oxyhalide at 0-300 DEG C. in an inert liquid hydrocarbon whilst removing gaseous hydrogen halide by product. Metal and halogen components are thus incorporated on the surface of the particles. Numerous examples are given. Specifications 967,762, 967,763, 967,765, 967,766 and 967,767 also are referred to.ALSO:A polymerization catalyst suitable for up to C8 mono- or di-olefins or mixtures thereof is obtained by the reaction of a product consisting (see Division C1) of a metal or metaloid oxide of less than 1 micron, other than silica, alumina or alumina-silica, e.g. titania, zirconia, thoria and magnesia, and a Group IVa, Va, VIa metal halide or oxyhalide, together with a Group I, II, III metal hydride or organometallic compound, which may contain more than one metal and/or halogen. Numerous examples of reactants are specified and polymerization using the catalysts obtained are described. Hydrogen may be present as a chain-terminator. Specifications 967,762, 967,763, 967,765, 967,766 and 967,767 also are referred to.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US286160A | 1960-01-18 | 1960-01-18 | |
US11961A US3166541A (en) | 1960-03-01 | 1960-03-01 | Surface treated carbon black as polymerization catalyst and method of polymerizationtherewith |
US1581560A | 1960-03-18 | 1960-03-18 | |
US2111060A | 1960-04-11 | 1960-04-11 | |
US19530962A | 1962-05-16 | 1962-05-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB969764A true GB969764A (en) | 1964-09-16 |
Family
ID=27532984
Family Applications (7)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4454360A Expired GB969761A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB356062A Expired GB969767A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355562A Expired GB969762A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355762A Expired GB969764A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355962A Expired GB969766A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355862A Expired GB969765A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355662A Expired GB969763A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4454360A Expired GB969761A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB356062A Expired GB969767A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355562A Expired GB969762A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB355962A Expired GB969766A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355862A Expired GB969765A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
GB355662A Expired GB969763A (en) | 1960-01-18 | 1960-12-29 | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPS4425353B1 (en) |
CH (1) | CH423262A (en) |
DE (1) | DE1214653B (en) |
GB (7) | GB969761A (en) |
LU (1) | LU39635A1 (en) |
NL (1) | NL259961A (en) |
SE (1) | SE309964B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1745415B1 (en) * | 1966-10-21 | 1972-06-29 | Solvay | PROCESS FOR THE POLYMERIZATION AND MIXED POLYMERIZATION OF OLEFINS |
US4087380A (en) | 1975-07-30 | 1978-05-02 | Bp Chemicals Limited | Polymerization catalyst |
WO2018123070A1 (en) * | 2016-12-28 | 2018-07-05 | Irpc Public Company, Limited | A method to produce a well-dispersed mgo nanoparticle-based ziegler-natta catalyst, and usage in producing ultra high molecular weight polyethylene |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6335405B1 (en) * | 1998-03-03 | 2002-01-01 | Idemitsu Petrochemical Co., Ltd. | Catalysts for olefin polymer production and process for producing olefin polymer |
SG83223A1 (en) * | 1999-12-27 | 2001-09-18 | Sumitomo Chemical Co | Modified particles, catalyst for olefin polymerization using the same, and process of producing olefin polymer |
JP2006176601A (en) * | 2004-12-21 | 2006-07-06 | Bussan Nanotech Research Institute Inc | Polymerization catalyst, polymer obtained by using the same, and its polymer complex |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB838028A (en) * | 1955-12-01 | 1960-06-22 | Exxon Research Engineering Co | Polymerization catalyst |
US2938000A (en) * | 1956-10-29 | 1960-05-24 | Exxon Research Engineering Co | Olefin polymerization catalysts |
GB823024A (en) * | 1957-06-07 | 1959-11-04 | Bataafsche Petroleum | Improvements in or relating to the catalytic polymerization of alpha-olefins and to the preparation of catalysts therefor |
-
0
- NL NL259961D patent/NL259961A/xx unknown
- LU LU39635D patent/LU39635A1/xx unknown
-
1960
- 1960-12-29 GB GB4454360A patent/GB969761A/en not_active Expired
- 1960-12-29 GB GB356062A patent/GB969767A/en not_active Expired
- 1960-12-29 GB GB355562A patent/GB969762A/en not_active Expired
- 1960-12-29 GB GB355762A patent/GB969764A/en not_active Expired
- 1960-12-29 GB GB355962A patent/GB969766A/en not_active Expired
- 1960-12-29 GB GB355862A patent/GB969765A/en not_active Expired
- 1960-12-29 GB GB355662A patent/GB969763A/en not_active Expired
-
1961
- 1961-01-11 CH CH33961A patent/CH423262A/en unknown
- 1961-01-17 SE SE43061A patent/SE309964B/xx unknown
- 1961-01-17 DE DEC23174A patent/DE1214653B/en active Pending
- 1961-01-18 JP JP174261A patent/JPS4425353B1/ja active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1745415B1 (en) * | 1966-10-21 | 1972-06-29 | Solvay | PROCESS FOR THE POLYMERIZATION AND MIXED POLYMERIZATION OF OLEFINS |
DE1745415C2 (en) * | 1966-10-21 | 1982-11-18 | Solvay & Cie., 1050 Bruxelles | Process for the polymerization and copolymerization of ethylene |
US4087380A (en) | 1975-07-30 | 1978-05-02 | Bp Chemicals Limited | Polymerization catalyst |
USRE30970E (en) | 1975-07-30 | 1982-06-15 | Bp Chemicals Limited | Polymerization catalyst |
WO2018123070A1 (en) * | 2016-12-28 | 2018-07-05 | Irpc Public Company, Limited | A method to produce a well-dispersed mgo nanoparticle-based ziegler-natta catalyst, and usage in producing ultra high molecular weight polyethylene |
Also Published As
Publication number | Publication date |
---|---|
GB969763A (en) | 1964-09-16 |
GB969767A (en) | 1964-09-16 |
JPS4425353B1 (en) | 1969-10-25 |
DE1214653B (en) | 1966-04-21 |
SE309964B (en) | 1969-04-14 |
GB969766A (en) | 1964-09-16 |
GB969762A (en) | 1964-09-16 |
CH423262A (en) | 1966-10-31 |
LU39635A1 (en) | |
GB969761A (en) | 1964-09-16 |
NL259961A (en) | |
GB969765A (en) | 1964-09-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1513673A (en) | Organozirconium compound and its use in the polymerisation of olefins | |
ES395397A1 (en) | Polymerization of ethylene and catalyst therefor | |
GB969764A (en) | Improved catalysts for the polymerization and copolymerization of mono-olefins and di-olefins | |
GB1218716A (en) | Process for the polymerisation of olefins | |
ES225560A1 (en) | Stabilized catalyst and improved polymerization process | |
GB840327A (en) | Polymerisation catalysts | |
GB827464A (en) | Polymerisation process | |
ES287879A1 (en) | A procedure that comprises the polymerization of ethylene and its conversion in a normally solid polymer (Machine-translation by Google Translate, not legally binding) | |
GB905187A (en) | Catalysts and their use in ª--olefinic polymerisation | |
ES296800A1 (en) | Polymerization procedure (Machine-translation by Google Translate, not legally binding) | |
ES303258A1 (en) | Procedure to polymerize alpha-olefins. (Machine-translation by Google Translate, not legally binding) | |
GB957461A (en) | Polymerisation catalyist and process of polymerisation using said catalyst | |
US2891937A (en) | Polymerisation of unsaturated hydrocarbons | |
NL6410124A (en) | ||
ES259687A1 (en) | Polymerization catalysts containing group ivb metal dioxides having halogen chemically bound thereto | |
ES281221A1 (en) | Procedure for obtaining ethylene oxide (Machine-translation by Google Translate, not legally binding) | |
GB975969A (en) | Polymerisation of olefines and catalyst therefor | |
GB616793A (en) | Improvements in or relating to catalyst regeneration | |
ES239424A1 (en) | Procedure for the polymerization of olefins (Machine-translation by Google Translate, not legally binding) | |
GB813793A (en) | Improvements in and relating to the polymerisation of unsaturated hydrocarbons | |
ES321591A1 (en) | An ethylene polymerization procedure. (Machine-translation by Google Translate, not legally binding) | |
GB933364A (en) | Process for the production of 3,3-dialkylpentylene-1,5 aluminum compounds | |
ES232002A1 (en) | Procedure for ethyl polymerization (Machine-translation by Google Translate, not legally binding) | |
ES374286A3 (en) | Process of polymerization of olefines with oxide of group 6a. (Machine-translation by Google Translate, not legally binding) | |
ES374288A3 (en) | Process of conversion of ethylene and propylene in solid polymers with metal oxides of group 6a and complex catalysts of metallic aluminum hydride. (Machine-translation by Google Translate, not legally binding) |