GB968862A - Production of polyethylene with caprylyl peroxide catalyst - Google Patents
Production of polyethylene with caprylyl peroxide catalystInfo
- Publication number
- GB968862A GB968862A GB4432660A GB4432660A GB968862A GB 968862 A GB968862 A GB 968862A GB 4432660 A GB4432660 A GB 4432660A GB 4432660 A GB4432660 A GB 4432660A GB 968862 A GB968862 A GB 968862A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyethylene
- peroxide
- production
- polymerizing
- caprylyl peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
A process for polymerizing ethylene comprises continuously passing ethylene into a first reaction zone at 130 DEG to 190 DEG C. and a pressure of at least 500 atmospheres and partially polymerizing in the presence of caprylyl peroxide as catalyst, passing the resulting mixture into a second reaction zone at 190 DEG to 270 DEG C. and a pressure of at least 500 atmospheres and polymerizing residual ethylene, optionally in the presence of an organic peroxide other than caprylyl peroxide (in particular di-t-butyl peroxide). The polymerization may be in the presence of a chain transfer agent, many of which are specified. The polyethylene obtained may be drawn into film of high transparency.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US86145359A | 1959-12-23 | 1959-12-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB968862A true GB968862A (en) | 1964-09-02 |
Family
ID=25335832
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4432660A Expired GB968862A (en) | 1959-12-23 | 1960-12-23 | Production of polyethylene with caprylyl peroxide catalyst |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1233141B (en) |
GB (1) | GB968862A (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1207723A (en) * | 1957-07-08 | 1960-02-18 | Improvements to ship propulsion systems |
-
1960
- 1960-10-25 DE DE1960E0020091 patent/DE1233141B/en active Pending
- 1960-12-23 GB GB4432660A patent/GB968862A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1233141B (en) | 1967-01-26 |
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