GB968862A - Production of polyethylene with caprylyl peroxide catalyst - Google Patents

Production of polyethylene with caprylyl peroxide catalyst

Info

Publication number
GB968862A
GB968862A GB4432660A GB4432660A GB968862A GB 968862 A GB968862 A GB 968862A GB 4432660 A GB4432660 A GB 4432660A GB 4432660 A GB4432660 A GB 4432660A GB 968862 A GB968862 A GB 968862A
Authority
GB
United Kingdom
Prior art keywords
polyethylene
peroxide
production
polymerizing
caprylyl peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4432660A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB968862A publication Critical patent/GB968862A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

A process for polymerizing ethylene comprises continuously passing ethylene into a first reaction zone at 130 DEG to 190 DEG C. and a pressure of at least 500 atmospheres and partially polymerizing in the presence of caprylyl peroxide as catalyst, passing the resulting mixture into a second reaction zone at 190 DEG to 270 DEG C. and a pressure of at least 500 atmospheres and polymerizing residual ethylene, optionally in the presence of an organic peroxide other than caprylyl peroxide (in particular di-t-butyl peroxide). The polymerization may be in the presence of a chain transfer agent, many of which are specified. The polyethylene obtained may be drawn into film of high transparency.
GB4432660A 1959-12-23 1960-12-23 Production of polyethylene with caprylyl peroxide catalyst Expired GB968862A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US86145359A 1959-12-23 1959-12-23

Publications (1)

Publication Number Publication Date
GB968862A true GB968862A (en) 1964-09-02

Family

ID=25335832

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4432660A Expired GB968862A (en) 1959-12-23 1960-12-23 Production of polyethylene with caprylyl peroxide catalyst

Country Status (2)

Country Link
DE (1) DE1233141B (en)
GB (1) GB968862A (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1207723A (en) * 1957-07-08 1960-02-18 Improvements to ship propulsion systems

Also Published As

Publication number Publication date
DE1233141B (en) 1967-01-26

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