GB968334A - Process for the extraction of gallium and indium from anode slime - Google Patents
Process for the extraction of gallium and indium from anode slimeInfo
- Publication number
- GB968334A GB968334A GB8576/61A GB857661A GB968334A GB 968334 A GB968334 A GB 968334A GB 8576/61 A GB8576/61 A GB 8576/61A GB 857661 A GB857661 A GB 857661A GB 968334 A GB968334 A GB 968334A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gallium
- methods
- halides
- separation
- indium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/22—Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B58/00—Obtaining gallium or indium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Gallium and indium are recovered by working up the anode slime which is formed in an electrolytic process employing aluminium or an aluminium alloy as anode, and an organometallic complex salt melt or solution as electrolyte. Methods of working up which may be used include physical methods of separation, e.g. evaporation, distillation, sublimation, flotation, centrifugal separation and methods which make use of differences in magnetic properties, for example fluidized bed methods of separation, and chemical methods of separation, e.g. selective oxidation, amalgamation, electrochemical methods and methods which make use of differences in the solubility of the various elements in different solvents. A preferred and novel method for separating the gallium, however, comprises drying the anode slime, reacting the dried slime with a halogen or hydrohalide to form a mixture of halides, separating the volatile halides including gallium halide from the non-volatile halides, treating the volatile halides with a non-aromatic hydrocarbon solvent to selectively dissolve the gallium halide, recovering the gallium halide from the resulting solution and working up the gallium halide into gallium, e.g. by electrolysis in an alkaline medium. In the example the mixture of indium and aluminium chlorides remaining after the removal of gallium trichloride by the above method is separated by making use of the great difference in the rate of solution of the two halides in ethers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DES67488A DE1164101B (en) | 1960-03-09 | 1960-03-09 | Process for the extraction of gallium or indium from the anode sludge of the electrorefining of aluminum in organometallic complex salts |
Publications (1)
Publication Number | Publication Date |
---|---|
GB968334A true GB968334A (en) | 1964-09-02 |
Family
ID=7499594
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB8576/61A Expired GB968334A (en) | 1960-03-09 | 1961-03-08 | Process for the extraction of gallium and indium from anode slime |
Country Status (4)
Country | Link |
---|---|
US (1) | US3325383A (en) |
CH (1) | CH438750A (en) |
DE (1) | DE1164101B (en) |
GB (1) | GB968334A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2150549A (en) * | 1983-12-01 | 1985-07-03 | Pavel Hurt | Process for the separate recovery of metal chlorides from complex ores etc |
CN109609779A (en) * | 2019-02-19 | 2019-04-12 | 东北大学 | A method of primary aluminum, which is carried out, using vacuum distillation removes gallium |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3897317A (en) * | 1974-06-24 | 1975-07-29 | Texas Instruments Inc | Process for making hyperpure gallium |
US3904497A (en) * | 1974-10-16 | 1975-09-09 | Aluminum Co Of America | Process for electrolytic recovery of metallic gallium |
FR2330773A1 (en) * | 1975-11-05 | 1977-06-03 | Inst Metallurg Obogascheni | Gallium extn foom sodium aluminate liquors - using liquid gallium and aluminium alloy to effect cementation |
US4728505A (en) * | 1985-12-23 | 1988-03-01 | Mitsui Aluminium Co., Ltd. | Process for producing gallium-containing solution from the aluminum smelting dust |
US4812167A (en) * | 1987-04-24 | 1989-03-14 | Chiyoda Corporation | Process for recovering metallic gallium from gallium compound-containing waste |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2598777A (en) * | 1948-01-23 | 1952-06-03 | Aluminum Co Of America | Recovering gallium from metallic aluminum |
US2848398A (en) * | 1955-05-11 | 1958-08-19 | Zh Sekitan Sogo Kenkyujo | Recovery of gallium compounds from the combustion gases of coal |
BE540052A (en) * | 1955-06-13 | |||
US2823096A (en) * | 1956-03-15 | 1958-02-11 | Dow Chemical Co | Process for recovering gallium from its ores |
US3075901A (en) * | 1958-06-04 | 1963-01-29 | Pechiney Prod Chimiques Sa | Purification of gallium by halogenation and electrolysis |
US3167422A (en) * | 1960-04-16 | 1965-01-26 | Siemens Ag | Method of producing gallium from the residues from chemical production of aluminum alkyls and aluminum-alkyl derivatives |
-
1960
- 1960-03-09 DE DES67488A patent/DE1164101B/en active Pending
-
1961
- 1961-02-15 CH CH178761A patent/CH438750A/en unknown
- 1961-03-08 GB GB8576/61A patent/GB968334A/en not_active Expired
-
1964
- 1964-05-05 US US365155A patent/US3325383A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2150549A (en) * | 1983-12-01 | 1985-07-03 | Pavel Hurt | Process for the separate recovery of metal chlorides from complex ores etc |
CN109609779A (en) * | 2019-02-19 | 2019-04-12 | 东北大学 | A method of primary aluminum, which is carried out, using vacuum distillation removes gallium |
Also Published As
Publication number | Publication date |
---|---|
US3325383A (en) | 1967-06-13 |
DE1164101B (en) | 1964-02-27 |
CH438750A (en) | 1967-06-30 |
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