GB946728A - New phenylbenzimidazoles - Google Patents

New phenylbenzimidazoles

Info

Publication number
GB946728A
GB946728A GB19727/60A GB1972760A GB946728A GB 946728 A GB946728 A GB 946728A GB 19727/60 A GB19727/60 A GB 19727/60A GB 1972760 A GB1972760 A GB 1972760A GB 946728 A GB946728 A GB 946728A
Authority
GB
United Kingdom
Prior art keywords
materials
sept
alkyl group
phenylbenzimidazoles
new
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19727/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB946728A publication Critical patent/GB946728A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/54Benzoxazoles; Hydrogenated benzoxazoles
    • C07D263/56Benzoxazoles; Hydrogenated benzoxazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
    • C07D263/57Aryl or substituted aryl radicals
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D235/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/18Benzimidazoles; Hydrogenated benzimidazoles with aryl radicals directly attached in position 2
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D277/00Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62Benzothiazoles
    • C07D277/64Benzothiazoles with only hydrocarbon or substituted hydrocarbon radicals attached in position 2
    • C07D277/66Benzothiazoles with only hydrocarbon or substituted hydrocarbon radicals attached in position 2 with aromatic rings or ring systems directly attached in position 2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041Optical brightening agents, organic pigments
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3445Five-membered rings
    • C08K5/3447Five-membered rings condensed with carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/35Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00Preserving by using additives, e.g. anti-oxidants
    • C11B5/0042Preserving by using additives, e.g. anti-oxidants containing nitrogen
    • C11B5/0064Heterocyclic compounds containing nitrogen in the ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35Heterocyclic compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Textile Engineering (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dermatology (AREA)
  • Computer Hardware Design (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Paints Or Removers (AREA)
  • Cosmetics (AREA)

Abstract

946,728. Leather. CIBA Ltd. Sept. 14, 1960 [Sept. 23, 1959 ; Dec. 8, 1959], No. 19727/62. Divided out of 941,990. Heading C6C. [Also in Divisions A2, A5, B5, C2, C3, C4, C5, Dl, D2 and G2] Materials are protected against ultra-violet rays by means of compounds of formula where A1 is a branched alkyl group having at least 4 carbon atoms, A2 is an unbranched alkyl group, and n is I or 2 (see Division C2). Materials specified include fibrous materials such as skins and hides and leathers made from the latter and products made therefrom.
GB19727/60A 1959-09-23 1960-09-14 New phenylbenzimidazoles Expired GB946728A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH317661A CH483276A (en) 1959-09-23 1959-09-23 Use of 2-phenyl-benzazoles as a protective agent against ultraviolet radiation outside the textile industry
CH7855059 1959-09-23
CH8156459 1959-12-08

Publications (1)

Publication Number Publication Date
GB946728A true GB946728A (en) 1964-01-15

Family

ID=31498871

Family Applications (2)

Application Number Title Priority Date Filing Date
GB31716/60A Expired GB941990A (en) 1959-09-23 1960-09-14 New phenylbenzoxazoles and process for their preparation
GB19727/60A Expired GB946728A (en) 1959-09-23 1960-09-14 New phenylbenzimidazoles

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB31716/60A Expired GB941990A (en) 1959-09-23 1960-09-14 New phenylbenzoxazoles and process for their preparation

Country Status (6)

Country Link
US (1) US3095422A (en)
CH (1) CH483276A (en)
DE (1) DE1201953B (en)
FR (1) FR1279273A (en)
GB (2) GB941990A (en)
NL (1) NL256123A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0251760A2 (en) * 1986-07-01 1988-01-07 Bridgestone Corporation Rubber composition

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3205083A (en) * 1961-07-31 1965-09-07 Air Prod & Chem Ultra-violet absorbers
DE1157231B (en) * 1961-12-20 1963-11-14 Bayer Ag Process for the preparation of 3-hydroxy-benzisoxazoles
NL300694A (en) * 1962-11-19
US3183231A (en) * 1963-07-17 1965-05-11 American Cyanamid Co Cyanonaphthoxazole brighteners
CH420044A (en) * 1964-09-01 1967-03-15 Ciba Geigy Use of new azole derivatives as optical brighteners for textile organic materials
CH449843A (en) * 1964-09-15 1968-01-15 Ciba Geigy Process for the production of optically brightened moldings from regenerated cellulose
CH472220A (en) * 1966-04-21 1969-05-15 Ciba Geigy Use of 2-phenylbenzoxazole derivatives as ultraviolet absorbers in cosmetic products
US4011236A (en) * 1968-09-09 1977-03-08 Merck & Co., Inc. N-(benzimidazol-2-yl)arylcarboxamides as ultraviolet (uv) light absorbers
IL37633A (en) * 1970-09-10 1975-08-31 Merck & Co Inc 2-(4-(2-benzoxazolyl)phenyl)alkanoic acid derivatives
US3716489A (en) * 1970-10-02 1973-02-13 American Cyanamid Co Supersaturated solid solutions of photochromic materials in epoxies
US3928617A (en) * 1973-11-30 1975-12-23 Uniroyal Inc Control of acarids using certain benzothiazoles or benzothiazolines
US3876791A (en) * 1973-11-30 1975-04-08 Uniroyal Inc Control of acarids using certain benzothiazoles or benzothiazolines
US4109093A (en) * 1975-01-14 1978-08-22 Produits Chimiques Ugine Kuhlmann Process for making 2-(4'-aminophenyl) 5-amino benzimidazole
US3974287A (en) * 1975-01-24 1976-08-10 Uniroyal Inc. Control of acarids using certain benzothiazoles or benzothiazolines
US4046905A (en) * 1975-02-10 1977-09-06 Merck & Co., Inc. Anti-inflammatory, analgesic and antipyretic phenylacetic acids
US4020165A (en) * 1975-08-20 1977-04-26 Uniroyal Inc. Control of acarids using certain benzothiazoles or benzothiazolines
DE2816819A1 (en) * 1978-04-18 1979-10-31 Bayer Ag LIGHT PROTECTION AGENTS
US4522808A (en) * 1980-08-15 1985-06-11 Societe Anonyme Dite: L'oreal Anti-sunburn compositions containing 2-phenyl-indole derivatives
LU85544A1 (en) * 1984-09-19 1986-04-03 Cird AROMATIC HETEROCYCLIC DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR APPLICATION IN THE THERAPEUTIC AND COSMETIC FIELDS
DE3905884A1 (en) * 1989-02-25 1990-09-20 Huels Chemische Werke Ag METHOD FOR PRODUCING A THERMOPLASTICALLY PROCESSABLE, AROMATIC POLYAMIDE
DE59304173D1 (en) * 1992-02-13 1996-11-21 Merck Patent Gmbh USE OF BENZIMIDAZOLE DERIVATIVES AS A LIGHT PROTECTION FILTER
IT1284526B1 (en) * 1996-09-13 1998-05-21 3V Sigma Spa BENZOSSAZOLE DERIVATIVES THEIR USE AS STABILIZERS AGAINST UV RADIATIONS
PT2280706E (en) 2008-05-14 2013-02-19 Otsuka Pharma Co Ltd Lipoprotein lipase-activating compositions comprising benzene derivatives

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE676103C (en) * 1933-03-31 1939-05-25 I G Farbenindustrie Akt Ges Radiation protection agents
US2746971A (en) * 1954-11-02 1956-05-22 Dow Chemical Co Dinitrobenzoxazoles
NL208080A (en) * 1955-06-17
US2985661A (en) * 1956-02-06 1961-05-23 American Cyanamid Co Preparation of 2(omicron-aminophenyl)-benzimidazole
AT195922B (en) * 1956-06-02 1958-02-25 Ciba Geigy Process for the preparation of α, β-di- [aryloxazolyl- (2)] - ethylene compounds
DE1022360B (en) * 1956-07-28 1958-01-09 Bayer Ag Sunscreens for human skin
BE559680A (en) * 1956-07-31
US2933503A (en) * 1957-01-14 1960-04-19 Merck & Co Inc Benzimidazole derivatives
DE1040753B (en) * 1957-05-02 1958-10-09 Bayer Ag Radiation protection agents
US2932649A (en) * 1958-09-10 1960-04-12 Rhone Poulenc Sa 2-thiocyanomethyl benzothiazole and corresponding 5-chlorobenzothiazole and benzoxazoe

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0251760A2 (en) * 1986-07-01 1988-01-07 Bridgestone Corporation Rubber composition
EP0251760A3 (en) * 1986-07-01 1988-06-01 Bridgestone Corporation Rubber composition

Also Published As

Publication number Publication date
NL256123A (en) 1964-03-25
GB941990A (en) 1963-11-20
FR1279273A (en) 1961-12-22
US3095422A (en) 1963-06-25
DE1201953B (en) 1965-09-30
CH483276A (en) 1969-12-31

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