GB933059A - Barium titanate dielectric - Google Patents

Barium titanate dielectric

Info

Publication number
GB933059A
GB933059A GB3170160A GB3170160A GB933059A GB 933059 A GB933059 A GB 933059A GB 3170160 A GB3170160 A GB 3170160A GB 3170160 A GB3170160 A GB 3170160A GB 933059 A GB933059 A GB 933059A
Authority
GB
United Kingdom
Prior art keywords
ceramic
temperature
titanate
fired
minutes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3170160A
Inventor
George Girdley Blowers
Frank Ernest Welsby
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Erie Resistor Ltd
Original Assignee
Erie Resistor Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Erie Resistor Ltd filed Critical Erie Resistor Ltd
Priority to GB3170160A priority Critical patent/GB933059A/en
Priority to FR872612A priority patent/FR1299490A/en
Publication of GB933059A publication Critical patent/GB933059A/en
Priority to FR957035A priority patent/FR84980E/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/46Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
    • C04B35/462Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
    • C04B35/465Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
    • C04B35/468Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates
    • C04B35/4682Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates based on barium titanates based on BaTiO3 perovskite phase
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/08Inorganic dielectrics
    • H01G4/12Ceramic dielectrics
    • H01G4/1209Ceramic dielectrics characterised by the ceramic dielectric material
    • H01G4/1218Ceramic dielectrics characterised by the ceramic dielectric material based on titanium oxides or titanates
    • H01G4/1227Ceramic dielectrics characterised by the ceramic dielectric material based on titanium oxides or titanates based on alkaline earth titanates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/002Details
    • H01G4/018Dielectrics
    • H01G4/06Solid dielectrics
    • H01G4/08Inorganic dielectrics
    • H01G4/12Ceramic dielectrics
    • H01G4/1272Semiconductive ceramic capacitors

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Insulating Materials (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Alkaline earth, especially barium, titanate ceramic dielectrics are produced by firing the green ceramic body in an oxidizing atmosphere, e.g. air at 2300 DEG -2800 DEG F. until the dielectric constant is in the range 8000-10000 and then heating to 2300-2800 DEG F. for 10-80 minutes in a reducing atmosphere, e.g. hydrogen. Ceramic bodies thus produced have dielectric constants in excess of 25000. For the production of a capacitor circuit element, electrodes are formed on the reduced ceramic body by the application of metallic electrode compositions, e.g. a silver glaze. The heated dielectric bodies are then fired in an oxidative atmosphere at 1400 DEG -1500 DEG F. for 1/2 -10 minutes when a controlled degree of reoxidation takes place. According to an example, a ceramic composition containing at least 50% by weight of barium titanate and the rest made up of strontium titanate and calcium zirconate was fired in a ceramic kiln on a 20 hour cycle with a maximum temperature of 2500 DEG F. maintained for 2 hours, then reduced for 1/2 hour at a temperature of 2400 DEG F. and reoxidized for one minute at a temperature of 1450 DEG F. Specification 664,370 is referred to.ALSO:Alkaline earth, especially barium, titanate ceramic dielectrics are produced by firing the green ceramic body in an oxidising atmosphere e.g. air at 2300-2800 DEG F until the dielectric constant is in the range 8000-10000 and then heating to 2300-2800 DEG F for 10-80 minutes in a reducing atmosphere e.g. hydrogen. Ceramic bodies thus produced have dielectric constants in excess of 25000. For the production of a capacitor circuit element, electrodes are formed on a reduced ceramic disc by the application of metallic electrode compositions e.g. a silver glaze. The heated dielectric discs are then fired in an oxidative atmosphere at 1400-1500 DEG F for 1/2 -10 minutes when a controlled degree of reoxidation takes place. According to an example, a ceramic composition containing p at least 50% by weight of barium titanate and the rest made up of strontium titanate and calcium zirconate was fired in a ceramic kiln on a 20 hour cycle with a maximum temperature of 2500 DEG F maintained for 2 hours, then reduced for 1/2 hour at a temperature of 2400 DEG F and reoxidized for one minute at a temperature of 1450 DEG F. An epoxy resin may be applied after cooling. Specification 664,370 is referred to.
GB3170160A 1960-09-14 1960-09-14 Barium titanate dielectric Expired GB933059A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB3170160A GB933059A (en) 1960-09-14 1960-09-14 Barium titanate dielectric
FR872612A FR1299490A (en) 1960-09-14 1961-09-07 Ceramic capacitor
FR957035A FR84980E (en) 1960-09-14 1963-12-12 Ceramic capacitor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3170160A GB933059A (en) 1960-09-14 1960-09-14 Barium titanate dielectric

Publications (1)

Publication Number Publication Date
GB933059A true GB933059A (en) 1963-07-31

Family

ID=10327112

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3170160A Expired GB933059A (en) 1960-09-14 1960-09-14 Barium titanate dielectric

Country Status (1)

Country Link
GB (1) GB933059A (en)

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