GB931571A - New disubstituted tetrahydro-oxazinones and a process for the production thereof - Google Patents
New disubstituted tetrahydro-oxazinones and a process for the production thereofInfo
- Publication number
- GB931571A GB931571A GB28314/61A GB2831461A GB931571A GB 931571 A GB931571 A GB 931571A GB 28314/61 A GB28314/61 A GB 28314/61A GB 2831461 A GB2831461 A GB 2831461A GB 931571 A GB931571 A GB 931571A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethyl
- hydrogen
- oxazinones
- production
- aralkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- SXCHDDWMFBETRA-UHFFFAOYSA-N oxazinan-3-one Chemical class O=C1CCCON1 SXCHDDWMFBETRA-UHFFFAOYSA-N 0.000 title 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 10
- 229910052739 hydrogen Inorganic materials 0.000 abstract 7
- 239000001257 hydrogen Substances 0.000 abstract 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 abstract 1
- 150000001414 amino alcohols Chemical class 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 238000005292 vacuum distillation Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
- C07D265/28—1,4-Oxazines; Hydrogenated 1,4-oxazines
- C07D265/34—1,4-Oxazines; Hydrogenated 1,4-oxazines condensed with carbocyclic rings
- C07D265/36—1,4-Oxazines; Hydrogenated 1,4-oxazines condensed with carbocyclic rings condensed with one six-membered ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
- C07D265/04—1,3-Oxazines; Hydrogenated 1,3-oxazines
- C07D265/06—1,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings
- C07D265/08—1,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D265/10—1,3-Oxazines; Hydrogenated 1,3-oxazines not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with oxygen atoms directly attached to ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention comprises 5,51-disubstituted tetrahydro-1,3-oxazin-(2)-ones of the general formula <FORM:0931571/IV(a)/1> where R1 and R2 are alkyl, aralkyl or aryl and R3 is hydrogen, alkyl, aralkyl or aryl, and the preparation thereof by condensing amino-alcohols of the general formula <FORM:0931571/IV(a)/2> with diethyl carbonate in the presence of an alkaline catalyst and distilling off the ethyl alcohol formed; the products are recovered by vacuum distillation. Examples describe the preparation of the compounds wherein R1, R2 and R3 have the values:-(1) ethyl; ethyl; hydrogen: (2) ethyl; propyl; hydrogen: (3) ethyl; allyl; hydrogen: (4) ethyl; butyl; hydrogen: (5) ethyl; benzyl; hydrogen: (6) ethyl; phenyl; hydrogen: (7) ethyl; ethyl; ethyl. The catalyst used is sodium methoxide; sodium carbonate can also be used.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK0041367 | 1960-08-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB931571A true GB931571A (en) | 1963-07-17 |
Family
ID=7222387
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28314/61A Expired GB931571A (en) | 1960-08-03 | 1961-08-03 | New disubstituted tetrahydro-oxazinones and a process for the production thereof |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE606879A (en) |
CH (1) | CH401975A (en) |
FR (1) | FR1626M (en) |
GB (1) | GB931571A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2545488B1 (en) * | 1983-05-02 | 1985-12-20 | Delalande Sa | NOVEL LATERAL CHAIN CARBAMATES OF THE ARYLMETHYL OR ARYLOXYMETHYL TYPE, PREPARATION METHODS THEREOF AND THERAPEUTIC APPLICATION THEREOF |
-
1961
- 1961-08-03 BE BE606879A patent/BE606879A/en unknown
- 1961-08-03 CH CH908761A patent/CH401975A/en unknown
- 1961-08-03 GB GB28314/61A patent/GB931571A/en not_active Expired
- 1961-11-02 FR FR870009A patent/FR1626M/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE606879A (en) | 1961-12-01 |
CH401975A (en) | 1965-11-15 |
FR1626M (en) | 1962-12-26 |
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