GB929241A - Nitro-substituted diisocyanate compounds - Google Patents

Nitro-substituted diisocyanate compounds

Info

Publication number
GB929241A
GB929241A GB3868760A GB3868760A GB929241A GB 929241 A GB929241 A GB 929241A GB 3868760 A GB3868760 A GB 3868760A GB 3868760 A GB3868760 A GB 3868760A GB 929241 A GB929241 A GB 929241A
Authority
GB
United Kingdom
Prior art keywords
formula
nitro
diacid
hexanitro
diisocyanates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3868760A
Inventor
Karl Klager
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aerojet Rocketdyne Inc
Original Assignee
Aerojet General Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aerojet General Corp filed Critical Aerojet General Corp
Priority to GB3868760A priority Critical patent/GB929241A/en
Publication of GB929241A publication Critical patent/GB929241A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B25/00Compositions containing a nitrated organic compound
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C263/00Preparation of derivatives of isocyanic acid
    • C07C263/12Preparation of derivatives of isocyanic acid from or via nitrogen analogues of carboxylic acids, e.g. from hydroxamic acids, involving a Hofmann, Curtius or Lossen-type rearrangement
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C265/00Derivatives of isocyanic acid
    • C07C265/14Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7868Nitrogen containing nitro groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Nitrated polyurethanes suitable as propellants are prepared by reacting hexanitro diisocyanates of the formula:- <FORM:0929241/IV(a)/1> wherein A and A1 are C1-3 alkylene radicals, with glycols such as 2,2-dinitro-1,3-propanediol, 2,2,4,4-tetranitro-1,5-pentanediol, or 2-nitro-2-methyl-1,3-propanediol.ALSO:The invention comprises hexanitro diisocyanates of the formula:- <FORM:0929241/IV(a)/1> wherein A and A1 are C1-3 alkylene radicals. Th compounds are prepared by heating a diacid halide of the formula:- <FORM:0929241/IV(a)/2> (where X represents halogen, e.g. chlorine or bromine) with an alkali or alkaline earth metal halide to form a diacid azide of the formula:- <FORM:0929241/IV(a)/3> which is then heated to effect rearrangement to the required diisocyanate. Diacid halides of the above formula are obtained by treating the corresponding dicarboxylic acids with PCl3, PCl5 or PBr5.
GB3868760A 1960-11-10 1960-11-10 Nitro-substituted diisocyanate compounds Expired GB929241A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3868760A GB929241A (en) 1960-11-10 1960-11-10 Nitro-substituted diisocyanate compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3868760A GB929241A (en) 1960-11-10 1960-11-10 Nitro-substituted diisocyanate compounds

Publications (1)

Publication Number Publication Date
GB929241A true GB929241A (en) 1963-06-19

Family

ID=10405061

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3868760A Expired GB929241A (en) 1960-11-10 1960-11-10 Nitro-substituted diisocyanate compounds

Country Status (1)

Country Link
GB (1) GB929241A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2175912A (en) * 1985-05-31 1986-12-10 Ashland Oil Inc Vapor permeation curable coatings comprising poly (nitro alcohol)compounds and multi-isocyanate curing agents

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2175912A (en) * 1985-05-31 1986-12-10 Ashland Oil Inc Vapor permeation curable coatings comprising poly (nitro alcohol)compounds and multi-isocyanate curing agents
GB2175912B (en) * 1985-05-31 1989-07-12 Ashland Oil Inc Vapor permeation curable coatings comprising nitro alcohol compounds and polyisocyanate curing agents

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