GB929241A - Nitro-substituted diisocyanate compounds - Google Patents
Nitro-substituted diisocyanate compoundsInfo
- Publication number
- GB929241A GB929241A GB3868760A GB3868760A GB929241A GB 929241 A GB929241 A GB 929241A GB 3868760 A GB3868760 A GB 3868760A GB 3868760 A GB3868760 A GB 3868760A GB 929241 A GB929241 A GB 929241A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- nitro
- diacid
- hexanitro
- diisocyanates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/12—Preparation of derivatives of isocyanic acid from or via nitrogen analogues of carboxylic acids, e.g. from hydroxamic acids, involving a Hofmann, Curtius or Lossen-type rearrangement
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C265/00—Derivatives of isocyanic acid
- C07C265/14—Derivatives of isocyanic acid containing at least two isocyanate groups bound to the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7868—Nitrogen containing nitro groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Nitrated polyurethanes suitable as propellants are prepared by reacting hexanitro diisocyanates of the formula:- <FORM:0929241/IV(a)/1> wherein A and A1 are C1-3 alkylene radicals, with glycols such as 2,2-dinitro-1,3-propanediol, 2,2,4,4-tetranitro-1,5-pentanediol, or 2-nitro-2-methyl-1,3-propanediol.ALSO:The invention comprises hexanitro diisocyanates of the formula:- <FORM:0929241/IV(a)/1> wherein A and A1 are C1-3 alkylene radicals. Th compounds are prepared by heating a diacid halide of the formula:- <FORM:0929241/IV(a)/2> (where X represents halogen, e.g. chlorine or bromine) with an alkali or alkaline earth metal halide to form a diacid azide of the formula:- <FORM:0929241/IV(a)/3> which is then heated to effect rearrangement to the required diisocyanate. Diacid halides of the above formula are obtained by treating the corresponding dicarboxylic acids with PCl3, PCl5 or PBr5.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3868760A GB929241A (en) | 1960-11-10 | 1960-11-10 | Nitro-substituted diisocyanate compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3868760A GB929241A (en) | 1960-11-10 | 1960-11-10 | Nitro-substituted diisocyanate compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB929241A true GB929241A (en) | 1963-06-19 |
Family
ID=10405061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3868760A Expired GB929241A (en) | 1960-11-10 | 1960-11-10 | Nitro-substituted diisocyanate compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB929241A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2175912A (en) * | 1985-05-31 | 1986-12-10 | Ashland Oil Inc | Vapor permeation curable coatings comprising poly (nitro alcohol)compounds and multi-isocyanate curing agents |
-
1960
- 1960-11-10 GB GB3868760A patent/GB929241A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2175912A (en) * | 1985-05-31 | 1986-12-10 | Ashland Oil Inc | Vapor permeation curable coatings comprising poly (nitro alcohol)compounds and multi-isocyanate curing agents |
GB2175912B (en) * | 1985-05-31 | 1989-07-12 | Ashland Oil Inc | Vapor permeation curable coatings comprising nitro alcohol compounds and polyisocyanate curing agents |
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