GB929210A - Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof - Google Patents

Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof

Info

Publication number
GB929210A
GB929210A GB28195/59A GB2819559A GB929210A GB 929210 A GB929210 A GB 929210A GB 28195/59 A GB28195/59 A GB 28195/59A GB 2819559 A GB2819559 A GB 2819559A GB 929210 A GB929210 A GB 929210A
Authority
GB
United Kingdom
Prior art keywords
manganese
dithiocarbamate
manganese salt
hexamethylene tetramine
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28195/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Publication of GB929210A publication Critical patent/GB929210A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14Di-thio analogues thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention comprises a manganese alkylene bis-dithiocarbamate, preferably manganese ethylene bis-dithiocarbamate, stabilized by having intimately admixed therewith hexamethylene tetramine in an amount sufficient to retard decomposition of the manganese salt on ageing. The hexamethylene content is preferably from 0.2 to 5.0% based on the weight of the manganese salt and may be incorporated into the manganese salt by dry mixing or by addition to the aqueous slurry of manganese salt prior to its isolation as a solid product.ALSO:A fungicidal composition comprises a manganese alkylene bis-dithiocarbamate, preferably manganese ethylene bis-dithiocarbamate, stabilized with sufficient hexamethylene tetramine to retard decomposition of the manganese salt on ageing, together with an inert adjuvant. The composition may be in the form of an aqueous slurry of manganese ethylene bisdithiocarbonate formed during the manufacture of the manganese salt and to which the hexamethylene tetramine is added. Alternatively, it may consist of a dry mixture of manganese ethylene bis-dithiocarbamate and hexamethylene tetramine to which has been added other fungicidal ingredients or inert liquid or solid diluents and carriers.
GB28195/59A 1958-08-29 1959-08-18 Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof Expired GB929210A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US757939A US2974156A (en) 1958-08-29 1958-08-29 Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof

Publications (1)

Publication Number Publication Date
GB929210A true GB929210A (en) 1963-06-19

Family

ID=25049816

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28195/59A Expired GB929210A (en) 1958-08-29 1959-08-18 Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof

Country Status (7)

Country Link
US (1) US2974156A (en)
CH (1) CH387014A (en)
DE (1) DE1113607B (en)
ES (1) ES251662A1 (en)
FR (1) FR1234005A (en)
GB (1) GB929210A (en)
OA (1) OA00105A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007053760A2 (en) * 2005-11-01 2007-05-10 Dow Agrosciences Llc Pesticidally active compositions having enhanced activity
US8765697B2 (en) 2009-04-30 2014-07-01 Dow Agrosciences, Llc. Pesticide compositions exhibiting enhanced activity
US8785379B2 (en) 2009-04-30 2014-07-22 Dow Agrosciences, Llc. Pesticide compositions exhibiting enhanced activity
US8796476B2 (en) 2009-04-30 2014-08-05 Dow Agrosciences, Llc Pesticide compositions exhibiting enhanced activity and methods for preparing same

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3036104A (en) * 1959-07-29 1962-05-22 Mountain Copper Company Ltd Stabilization of copper chelate
US3167471A (en) * 1960-07-19 1965-01-26 Siapa Spa Synergistic fungicidal compositions
US3085042A (en) * 1961-06-09 1963-04-09 Du Pont Phytotoxicity of manganese ethylene-bisdithiocarbamate reduced by the addition of zinc and cadmium ions
BE621575A (en) * 1961-08-26
DE1250187B (en) * 1962-10-30 1967-09-14 MONTECATINI Societä Generale per rindustria Mineraria e Chimica, Mailand (Italien) Fungicidal agent containing the manganese salt of ethylene bisdithiocarbamic acid
DE1542768C2 (en) * 1964-05-16 1970-12-17 Farbwerke Hoechst AG, vorm. Meister Lucius & Brüning, 6000 Frankfurt Fungicides
FR1476610A (en) * 1965-12-01 1967-04-14 Soc D Etudes Prod Chimique Process for stabilizing dithiocarbamates and products resulting from this process
NL6606629A (en) * 1966-05-13 1967-11-14
NL7209913A (en) * 1972-07-18 1974-01-22
US4344890A (en) * 1981-05-04 1982-08-17 Adams Jr John B Aqueous fungicidal formulations and their preparation
AT386194B (en) * 1982-04-20 1988-07-11 Borsodi Vegyi Komb Process for the preparation of novel substituted alkoxycarbonyl dithiocarbamates and thiolcarbamates
HU187452B (en) * 1982-04-20 1986-01-28 Borsodi Vegyi Kombinat,Hu Fungicides containing - as reagent - alkoxicarbonile ditiocarbamata and process for production of the reagent
MA19798A1 (en) * 1982-06-08 1983-12-31 Novartis Ag PLANT DISEASE CONTROL AGENT; ITS PREPARATION AND ITS APPLICATION TO THE PROTECTION OF PLANTS.
CN1909787A (en) * 2004-01-14 2007-02-07 美国陶氏益农公司 Method of stabilizing alkylenebisdithiocarbamates

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2665285A (en) * 1951-07-06 1954-01-05 Du Pont Stabilization of derivatives of dithiocarbamic acids
US2860870A (en) * 1954-01-28 1958-11-18 Monroe Auto Equipment Co Stabilizer and spring device
NL254917A (en) * 1954-07-28
US2806870A (en) * 1956-01-09 1957-09-17 Tennessee Corp Methods for stabilization of the manganous salt of dimethyl dithiocarbamic acid and the products thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007053760A2 (en) * 2005-11-01 2007-05-10 Dow Agrosciences Llc Pesticidally active compositions having enhanced activity
WO2007053760A3 (en) * 2005-11-01 2008-01-10 Dow Agrosciences Llc Pesticidally active compositions having enhanced activity
US8765697B2 (en) 2009-04-30 2014-07-01 Dow Agrosciences, Llc. Pesticide compositions exhibiting enhanced activity
US8785379B2 (en) 2009-04-30 2014-07-22 Dow Agrosciences, Llc. Pesticide compositions exhibiting enhanced activity
US8796476B2 (en) 2009-04-30 2014-08-05 Dow Agrosciences, Llc Pesticide compositions exhibiting enhanced activity and methods for preparing same
US9247730B2 (en) 2009-04-30 2016-02-02 Dow Agrosciences Llc Pesticide compositions exhibiting enhanced activity and methods for preparing same
US9374997B2 (en) 2009-04-30 2016-06-28 Dow Agrosciences Llc Pesticide compositions exhibiting enhanced activity
US9480256B2 (en) 2009-04-30 2016-11-01 Dow Agrosciences Llc Pesticide compositions exhibiting enhanced activity

Also Published As

Publication number Publication date
FR1234005A (en) 1960-10-14
CH387014A (en) 1965-01-31
OA00105A (en) 1966-01-15
US2974156A (en) 1961-03-07
ES251662A1 (en) 1960-04-16
DE1113607B (en) 1961-09-07

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