GB929210A - Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof - Google Patents
Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereofInfo
- Publication number
- GB929210A GB929210A GB28195/59A GB2819559A GB929210A GB 929210 A GB929210 A GB 929210A GB 28195/59 A GB28195/59 A GB 28195/59A GB 2819559 A GB2819559 A GB 2819559A GB 929210 A GB929210 A GB 929210A
- Authority
- GB
- United Kingdom
- Prior art keywords
- manganese
- dithiocarbamate
- manganese salt
- hexamethylene tetramine
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises a manganese alkylene bis-dithiocarbamate, preferably manganese ethylene bis-dithiocarbamate, stabilized by having intimately admixed therewith hexamethylene tetramine in an amount sufficient to retard decomposition of the manganese salt on ageing. The hexamethylene content is preferably from 0.2 to 5.0% based on the weight of the manganese salt and may be incorporated into the manganese salt by dry mixing or by addition to the aqueous slurry of manganese salt prior to its isolation as a solid product.ALSO:A fungicidal composition comprises a manganese alkylene bis-dithiocarbamate, preferably manganese ethylene bis-dithiocarbamate, stabilized with sufficient hexamethylene tetramine to retard decomposition of the manganese salt on ageing, together with an inert adjuvant. The composition may be in the form of an aqueous slurry of manganese ethylene bisdithiocarbonate formed during the manufacture of the manganese salt and to which the hexamethylene tetramine is added. Alternatively, it may consist of a dry mixture of manganese ethylene bis-dithiocarbamate and hexamethylene tetramine to which has been added other fungicidal ingredients or inert liquid or solid diluents and carriers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US757939A US2974156A (en) | 1958-08-29 | 1958-08-29 | Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
GB929210A true GB929210A (en) | 1963-06-19 |
Family
ID=25049816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28195/59A Expired GB929210A (en) | 1958-08-29 | 1959-08-18 | Method for stabilization of manganese salts of alkylene bisdithiocarbamic acids and the products thereof |
Country Status (7)
Country | Link |
---|---|
US (1) | US2974156A (en) |
CH (1) | CH387014A (en) |
DE (1) | DE1113607B (en) |
ES (1) | ES251662A1 (en) |
FR (1) | FR1234005A (en) |
GB (1) | GB929210A (en) |
OA (1) | OA00105A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007053760A2 (en) * | 2005-11-01 | 2007-05-10 | Dow Agrosciences Llc | Pesticidally active compositions having enhanced activity |
US8765697B2 (en) | 2009-04-30 | 2014-07-01 | Dow Agrosciences, Llc. | Pesticide compositions exhibiting enhanced activity |
US8785379B2 (en) | 2009-04-30 | 2014-07-22 | Dow Agrosciences, Llc. | Pesticide compositions exhibiting enhanced activity |
US8796476B2 (en) | 2009-04-30 | 2014-08-05 | Dow Agrosciences, Llc | Pesticide compositions exhibiting enhanced activity and methods for preparing same |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3036104A (en) * | 1959-07-29 | 1962-05-22 | Mountain Copper Company Ltd | Stabilization of copper chelate |
US3167471A (en) * | 1960-07-19 | 1965-01-26 | Siapa Spa | Synergistic fungicidal compositions |
US3085042A (en) * | 1961-06-09 | 1963-04-09 | Du Pont | Phytotoxicity of manganese ethylene-bisdithiocarbamate reduced by the addition of zinc and cadmium ions |
BE621575A (en) * | 1961-08-26 | |||
DE1250187B (en) * | 1962-10-30 | 1967-09-14 | MONTECATINI Societä Generale per rindustria Mineraria e Chimica, Mailand (Italien) | Fungicidal agent containing the manganese salt of ethylene bisdithiocarbamic acid |
DE1542768C2 (en) * | 1964-05-16 | 1970-12-17 | Farbwerke Hoechst AG, vorm. Meister Lucius & Brüning, 6000 Frankfurt | Fungicides |
FR1476610A (en) * | 1965-12-01 | 1967-04-14 | Soc D Etudes Prod Chimique | Process for stabilizing dithiocarbamates and products resulting from this process |
NL6606629A (en) * | 1966-05-13 | 1967-11-14 | ||
NL7209913A (en) * | 1972-07-18 | 1974-01-22 | ||
US4344890A (en) * | 1981-05-04 | 1982-08-17 | Adams Jr John B | Aqueous fungicidal formulations and their preparation |
AT386194B (en) * | 1982-04-20 | 1988-07-11 | Borsodi Vegyi Komb | Process for the preparation of novel substituted alkoxycarbonyl dithiocarbamates and thiolcarbamates |
HU187452B (en) * | 1982-04-20 | 1986-01-28 | Borsodi Vegyi Kombinat,Hu | Fungicides containing - as reagent - alkoxicarbonile ditiocarbamata and process for production of the reagent |
MA19798A1 (en) * | 1982-06-08 | 1983-12-31 | Novartis Ag | PLANT DISEASE CONTROL AGENT; ITS PREPARATION AND ITS APPLICATION TO THE PROTECTION OF PLANTS. |
CN1909787A (en) * | 2004-01-14 | 2007-02-07 | 美国陶氏益农公司 | Method of stabilizing alkylenebisdithiocarbamates |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2665285A (en) * | 1951-07-06 | 1954-01-05 | Du Pont | Stabilization of derivatives of dithiocarbamic acids |
US2860870A (en) * | 1954-01-28 | 1958-11-18 | Monroe Auto Equipment Co | Stabilizer and spring device |
NL254917A (en) * | 1954-07-28 | |||
US2806870A (en) * | 1956-01-09 | 1957-09-17 | Tennessee Corp | Methods for stabilization of the manganous salt of dimethyl dithiocarbamic acid and the products thereof |
-
1958
- 1958-08-29 US US757939A patent/US2974156A/en not_active Expired - Lifetime
-
1959
- 1959-08-07 DE DER26117A patent/DE1113607B/en active Pending
- 1959-08-18 GB GB28195/59A patent/GB929210A/en not_active Expired
- 1959-08-21 ES ES0251662A patent/ES251662A1/en not_active Expired
- 1959-08-28 FR FR803830A patent/FR1234005A/en not_active Expired
- 1959-08-28 CH CH7750359A patent/CH387014A/en unknown
-
1964
- 1964-05-27 OA OA50121A patent/OA00105A/en unknown
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007053760A2 (en) * | 2005-11-01 | 2007-05-10 | Dow Agrosciences Llc | Pesticidally active compositions having enhanced activity |
WO2007053760A3 (en) * | 2005-11-01 | 2008-01-10 | Dow Agrosciences Llc | Pesticidally active compositions having enhanced activity |
US8765697B2 (en) | 2009-04-30 | 2014-07-01 | Dow Agrosciences, Llc. | Pesticide compositions exhibiting enhanced activity |
US8785379B2 (en) | 2009-04-30 | 2014-07-22 | Dow Agrosciences, Llc. | Pesticide compositions exhibiting enhanced activity |
US8796476B2 (en) | 2009-04-30 | 2014-08-05 | Dow Agrosciences, Llc | Pesticide compositions exhibiting enhanced activity and methods for preparing same |
US9247730B2 (en) | 2009-04-30 | 2016-02-02 | Dow Agrosciences Llc | Pesticide compositions exhibiting enhanced activity and methods for preparing same |
US9374997B2 (en) | 2009-04-30 | 2016-06-28 | Dow Agrosciences Llc | Pesticide compositions exhibiting enhanced activity |
US9480256B2 (en) | 2009-04-30 | 2016-11-01 | Dow Agrosciences Llc | Pesticide compositions exhibiting enhanced activity |
Also Published As
Publication number | Publication date |
---|---|
FR1234005A (en) | 1960-10-14 |
CH387014A (en) | 1965-01-31 |
OA00105A (en) | 1966-01-15 |
US2974156A (en) | 1961-03-07 |
ES251662A1 (en) | 1960-04-16 |
DE1113607B (en) | 1961-09-07 |
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