GB928326A - Agents for increasing the wet shape retention of fibrous materials containing or consisting of cellulose and a process using the same - Google Patents

Agents for increasing the wet shape retention of fibrous materials containing or consisting of cellulose and a process using the same

Info

Publication number
GB928326A
GB928326A GB45579/61A GB4557961A GB928326A GB 928326 A GB928326 A GB 928326A GB 45579/61 A GB45579/61 A GB 45579/61A GB 4557961 A GB4557961 A GB 4557961A GB 928326 A GB928326 A GB 928326A
Authority
GB
United Kingdom
Prior art keywords
vinyl
polymers
urea
polymer
ether units
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB45579/61A
Inventor
Heinz Graefje
Ernst Ploetz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB928326A publication Critical patent/GB928326A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/28—Condensation with aldehydes or ketones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45—Shrinking resistance, anti-felting properties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Vinyl polymers containing vinyl acyloxymethyl ether units may be prepared by acylating vinyl hydroxymethyl ether polymers which may be obtained by reacting formaldehyde with hydrolysed vinyl ester polymers as described in Specification 924,036. The acylating agent may be the anhydride or acid halides of acetic, propionic, butyric, caproic, lauric, palmitic or stearic acid. Acylation may be complete, or sufficient hydroxymethyl groups may be retained to render the polymers water-soluble. In examples a saponified vinyl acetate polymer which has been reacted with formaldehyde is acylated with (1) acetic anhydride and (3) propionic anhydride in dimethyl formamide. Aqueous or organic solvent solutions or dispersions of the polymers may be used for treating fibrous materials comprising cellulose, e.g. cotton and rayon fabrics to improve the wet shape retention thereof. Such compositions may also comprise acid reacting catalysts, e.g. magnesium chloride, zinc chloride and zinc nitrate; softeners such as N-alkyl ethylene ureas; methylol compounds of urea or cyclic urea derivatives such as ethylene urea, glyoxal monoureine and glyoxal diureine; and emulsifiers such as ethylene oxide adducts of sperm oil alcohols.ALSO:The wet shape retention, particularly crease resistance, of fabrics containing or consisting of cellulose is increased by impregnating with vinyl polymers containing vinyl acyloxymethyl ether units, and heating in the presence of acid reacting substances. The acyl group may be derived from acetic, propionic, butyric, caproic, lauric, palmitic or stearic acid, and the polymer may contain other units, e.g. sufficient vinyl hydroxymethyl ether units to render it watersoluble. The acid reacting substance may be magnesium chloride, zinc chloride or zinc nitrate. Impregnation may be effected with aqueous or organic solvent solutions or dispersions of the polymer which may also contain softeners such as N-alkyl ethylene ureas, and methylol compounds of urea or cyclic urea derivatives such as p ethylene urea, glyoxalmonoureine and glyoxaldiureine. Examples describe the impregnation of (1) cotton fabric and (2) rayon fabric with an aqueous solution of a polymer containing vinyl acetyloxymethyl ether units, sodium carbonate and magnesium chloride; and (3) the impregnation of cotton fabric with an aqueous dispersion of a polymer containing vinyl propionoxymethyl ether units emulsified with an ethylene oxide adduct of sperm oil alcohol, and zinc chloride. Specification 924,036 is referred to.
GB45579/61A 1960-12-23 1961-12-20 Agents for increasing the wet shape retention of fibrous materials containing or consisting of cellulose and a process using the same Expired GB928326A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB60616A DE1141252B (en) 1960-12-23 1960-12-23 Process for increasing the wet form stability of cellulose-containing or cellulose-based fiber material

Publications (1)

Publication Number Publication Date
GB928326A true GB928326A (en) 1963-06-12

Family

ID=6972898

Family Applications (1)

Application Number Title Priority Date Filing Date
GB45579/61A Expired GB928326A (en) 1960-12-23 1961-12-20 Agents for increasing the wet shape retention of fibrous materials containing or consisting of cellulose and a process using the same

Country Status (4)

Country Link
BE (1) BE611912A (en)
DE (1) DE1141252B (en)
GB (1) GB928326A (en)
NL (1) NL272833A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4846933A (en) * 1986-06-03 1989-07-11 Betz Laboratories, Inc. Process for controlling pitch deposition from pulp in papermaking systems
EP1505085A1 (en) * 2003-08-04 2005-02-09 Celanese Emulsions GmbH Water resistant adhesives, process for their manufacture and use thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE415454A (en) * 1935-05-08
DE732172C (en) * 1940-02-24 1943-02-23 Ig Farbenindustrie Ag Softening of cellulose hydrate fabrics
US2806838A (en) * 1955-07-15 1957-09-17 Rohm & Haas Unsaturated carbamato ethers and thioethers, polymers thereof, and methods of making them

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4846933A (en) * 1986-06-03 1989-07-11 Betz Laboratories, Inc. Process for controlling pitch deposition from pulp in papermaking systems
EP1505085A1 (en) * 2003-08-04 2005-02-09 Celanese Emulsions GmbH Water resistant adhesives, process for their manufacture and use thereof
US7585915B2 (en) 2003-08-04 2009-09-08 Celanese Emulsions Gmbh Water-resistant adhesives, their preparation and use

Also Published As

Publication number Publication date
NL272833A (en)
DE1141252B (en) 1962-12-20
BE611912A (en)

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