GB720387A - A process for the production of finishing effects on cellulose textile materials - Google Patents

A process for the production of finishing effects on cellulose textile materials

Info

Publication number
GB720387A
GB720387A GB20538/52A GB2053852A GB720387A GB 720387 A GB720387 A GB 720387A GB 20538/52 A GB20538/52 A GB 20538/52A GB 2053852 A GB2053852 A GB 2053852A GB 720387 A GB720387 A GB 720387A
Authority
GB
United Kingdom
Prior art keywords
glyoxal
monourein
derivatives
compounds
polyacrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20538/52A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB720387A publication Critical patent/GB720387A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Natural or regenerated cellulose textiles are impregnated with an aqueous solution of a methylol compound of a monourein in the presence of an acid-reacting hardening catalyst, dried and if desired heated for a short time. The monoureins are 4 : 5-derivatives of 2-keto-, thion- or imino-imidazolidines, and may be derived from glyoxal, diacetyl, benzil and other a ,b -dicarbonyl compounds. Those derived from glyoxal are of the general formula <FORM:0720387/IV (c)/1> in which X represents O, S or NH. If desired, the methylol compounds of the monoureins may be produced on the fibres. Methylol compounds of urea, urethanes or melamine may be added during the impregnation. There may also be added polyfunctional compounds having reactive hydrogen atoms such as glyoxal, amino-alcohols and diamines, textile finishing agents such as high molecular polyglycol ethers, polyvinyl pyrrolidone, polyacrylic acid and its derivatives, polyvinyl imidazole, saponification products of polyacrylonitrile or polyacrylic acid esters, polyvinyl alcohol, soluble starch, dextrine, cellulose esters or ethers, animal glue and amides obtained by the reaction of long-chain aliphatic carboxylic acids and amino alcohols. After drying, preferably between 40 DEG and 85 DEG C., the treated textile may be calendered or embossed and finally heated preferably at from 110 DEG to 140 DEG C. In an example (all parts by weight) 120 to 140 parts of the dimethylol-monourein of glyoxal are dissolved in 1000 parts of water and 20 to 25 parts of zinc chloride added. A regenerated cellulose staple fibre fabric is impregnated with the solution, dried at 70 DEG C. and heated at 120 DEG C. for 5 minutes. Specification 720,386, [Group IV (a)], is referred to.ALSO:A composition for impregnating natural or regenerated cellulose textiles comprises an aqueous solution of a methylol compound of a monourein and a textile finishing agent such as polyvinyl pyrrolidone, polyacrylic acid and its derivatives, polyvinyl imidazole, polyvinyl alcohol or a saponification product of polyacrylonitrile or a polyacrylic acid ester (see Groups IV (c) and VIII). Monoureins are 4 : 5-derivatives of 2-keto-, thion- or imino-imidazolidines, and may be derived from glyoxal, diacetyl, benzil and other a ,b -dicarbonyl compounds. Those derived from glyoxal are of general formula <FORM:0720387/IV (a)/1> in which X represents O,S or NH. Methylol compounds of urea, urethanes or melamine may also be incorporated. In an example (4) a composition comprising an aqueous solution of the dimethylol monourein of glyoxal and a saponification product of an acrylonitrile/methyl acrylate interpolymer is used to impregnate regenerated cellulose staple fibre fabric. Specification 720,386 is referred to.
GB20538/52A 1951-08-18 1952-08-15 A process for the production of finishing effects on cellulose textile materials Expired GB720387A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE310796X 1951-08-18

Publications (1)

Publication Number Publication Date
GB720387A true GB720387A (en) 1954-12-15

Family

ID=6126186

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20538/52A Expired GB720387A (en) 1951-08-18 1952-08-15 A process for the production of finishing effects on cellulose textile materials

Country Status (5)

Country Link
US (1) US2731364A (en)
BE (1) BE513352A (en)
CH (1) CH310796A (en)
FR (2) FR1061107A (en)
GB (1) GB720387A (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2810624A (en) * 1954-04-08 1957-10-22 Rohm & Haas Cellulose plisse fabric and method of producing by applying 1, 3-bis(hydroxy-methyl)-2-imidazolidone and chemical shrinking agent
US2926062A (en) * 1956-03-05 1960-02-23 Gagliardi Res Corp Water repellent compositions, products and processes for making same
US2898238A (en) * 1956-08-20 1959-08-04 American Cyanamid Co Process for treating textiles with ethylene urea-formaldehyde reaction products
US2887408A (en) * 1957-09-27 1959-05-19 American Cyanamid Co Method of treating textile materials
US3116967A (en) * 1958-01-09 1964-01-07 Sun Chemical Corp Creaseproofing compositions for textiles
US2992138A (en) * 1958-04-17 1961-07-11 Du Pont Cellulosic textile treating composition and process
GB897757A (en) * 1959-03-12 1962-05-30 Sumitomo Chemical Co 1, 3-di-methylol-4, 5-bis(alkoxy)-2-imidazolidinones and use of the same
BE591782A (en) * 1959-06-11 1900-01-01
US3181927A (en) * 1959-11-16 1965-05-04 American Cyanamid Co Process of wet and dry wrinkleproofing cellulose fabric with an aminoplast resin and zinc chloride
US3049446A (en) * 1960-02-05 1962-08-14 Sun Chemical Corp Process for the manufacture of urea, glyoxal and formaldehye reaction product useful for improving cellulosic textile materials
US3355242A (en) * 1960-07-11 1967-11-28 Sun Chemical Corp Reactive dyes and methylolated-4, 5-dihydroxy-imidazolidone-2, in coloring cellulosic textiles
US3112156A (en) * 1960-10-07 1963-11-26 Sidney L Vail Treatment of cellulosic textile material with 1, 3-dimethyl-4, 5-dihydroxy-2-imidazolidinone
US3260565A (en) * 1961-02-03 1966-07-12 American Cyanamid Co Novel imidazolidinones and their use as textile finishing agents
NL130155C (en) * 1962-11-10 1900-01-01
US3376101A (en) * 1963-10-22 1968-04-02 Agriculture Usa Process of modifying cellulosic textiles with glyoxal-biscarbamate reaction products
CH1126565D (en) * 1964-08-11
US3639096A (en) * 1964-10-19 1972-02-01 Dan River Inc Process of treating direct dyed cellulosic textiles with a mixture of aminoplast creaseproofing agents and products resulting therefrom
US3420702A (en) * 1965-05-11 1969-01-07 Dan River Mills Inc Double bath treatment of cellulosic fabrics to impart crease resistance and high abrasion resistance thereto
NL136360C (en) * 1966-08-04
CH1258167D (en) * 1966-09-08
US3890095A (en) * 1967-04-05 1975-06-17 American Cyanamid Co Cellulosic textile finish with 1,3-dimethylol-4,5-dihydroxy-2-imidazolidinone, zinc nitrate and a sequestering agent
US3505097A (en) * 1967-04-20 1970-04-07 Hercules Inc Lustrous pile fabric based on polypropylene
US3911181A (en) * 1968-09-27 1975-10-07 American Cyanamid Co Permanent press textile finish
BE756805A (en) * 1969-09-29 1971-03-29 Dow Chemical Co METHOD AND COMPOSITIONS FOR PROCESSING FLEXIBLE SUBSTRATES SUCH AS FABRICS OR PAPER
US3632422A (en) * 1969-12-04 1972-01-04 Burlington Industries Inc Textile fabric having soil release finish and method of making same
US3768969A (en) * 1971-12-21 1973-10-30 Us Agriculture Sensitized textiles with decreased formaldehyde odor
DE2163853B2 (en) * 1971-12-22 1974-09-19 Basf Ag, 6700 Ludwigshafen Process for the production of textile finishing agents
US3920881A (en) * 1973-07-02 1975-11-18 American Cyanamid Co Textile finish using a combination of an aminoplast resin and monomethyloldicyandiamide
CA2599431A1 (en) * 2005-03-04 2006-09-08 Basf Aktiengesellschaft Production of moulded bodies from lignocellulose-based fine particle materials

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2588640A (en) * 1948-04-26 1952-03-11 Bozel Maletra Prod Chimiques Hydrofugation of textile materials
US2574114A (en) * 1948-04-26 1951-11-06 Bozel Maletra Prod Chimiques Amide-glyoxal-formaldehyde reaction product and shrinkproofing cellulose textile fibers therewith
US2504857A (en) * 1948-06-03 1950-04-18 Bancroft & Sons Co J Art of imparting crease resistance to cotton fabrics

Also Published As

Publication number Publication date
US2731364A (en) 1956-01-17
FR1061107A (en) 1954-04-08
BE513352A (en)
CH310796A (en) 1955-11-15
FR1061311A (en) 1954-04-12

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