GB634634A - Improvements in or relating to the finishing of fabrics and other fibrous materials - Google Patents

Improvements in or relating to the finishing of fabrics and other fibrous materials

Info

Publication number
GB634634A
GB634634A GB16595/45A GB1659545A GB634634A GB 634634 A GB634634 A GB 634634A GB 16595/45 A GB16595/45 A GB 16595/45A GB 1659545 A GB1659545 A GB 1659545A GB 634634 A GB634634 A GB 634634A
Authority
GB
United Kingdom
Prior art keywords
aldehyde
carbohydrate
formaldehyde
solution
cellulose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16595/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Joseph Bancroft and Sons Co
Original Assignee
Joseph Bancroft and Sons Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Joseph Bancroft and Sons Co filed Critical Joseph Bancroft and Sons Co
Publication of GB634634A publication Critical patent/GB634634A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/11Starch or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

Aqueous solutions of methyl or hydroxy ethyl cellulose contain formaldehyde, paraformaldehyde, other polymerization products of formaldehyde, hexamethylene tetramine, acetaldol, or glyoxal, the aldehyde comprising from 0.5 to 5.0 per cent by weight of the solution. The solutions are used for treating cellulose or regenerated cellulose fibres, fabrics, or paper, to render permanent mechanically imparted lustrous finishes. After application of the solution, the materials are subjected to a heat curing treatment. The solutions may contain other textile finishing agents such as polyethylene glycol, olein oil, sodium salt of sulphonated tallow, or lecithin. A catalyst for assisting the condensation reaction between the aldehyde and cellulose ether may be present. In an example, the aqueous preparation comprises methyl cellulose, formaldehyde, polyethylene glycol, and ammonium di-hydrogen phosphate.ALSO:Cellulose or regenerated cellulose fibres or fabrics are treated, e.g. impregnated, with a polysaccharide carbohydrate or derivative thereof and an aldehyde or aldehyde-yielding substance selected from the group comprising formaldehyde, paraformaldehyde, other polymerization products of formaldehyde, hexamethylene tetramine, acetaldol, and glyoxal, the carbohydrate and the aldehyde being applied in the form of a combined aqueous solution or as separate aqueous solutions, and the aldehyde comprising from 0.5 to 5.0 per cent by weight of the solution in which it is applied. After the impregnation, the material is dried to dampness, and a lustrous mechanical finish is imparted by a pressure mechanical finishing machine and rendered permanent by subjecting the material to a heat-curing treatment at 280 DEG to 400 DEG F. The mechanical finish may be imparted by friction glazing, schreinering, calendering, beetling, or embossing. The curing may be effected with or subsequently to the mechanical finishing treatment. The carbohydrate may be starch, partly acetylated starch, dextrine, glucose, gum arabic, gum tragacanth, gum karaya, or methyl or hydroxy ethyl cellulose. The carbohydrate and the aldehyde may be partially condensed by heating before the sizing of the fibrous material. A catalyst may be present, e.g. ammonium thiocyanate, zinc chloride, ammonium dihydrogen phosphate, or ammonium nitrate. Wetting, softening, or stiffening agents may be added to the treating solution or may be applied before or after the carbohydrate and aldehyde. In examples, the treating solutions contain dextrine, starch, pectin, gum arabic, karaya gum, or methyl cellulose, with formaldehyde or glyoxal and ammonium thiocyanate or ammonium dihydrogen phosphate. Other additions include polyethylene glycol, olein oil, lecithin, and the sodium salt of sulphonated tallow. The aldehyde may be applied before or after the carbohydrate, where separate treating solutions are used and the fabric may be dried between the two applications. Preferably sufficient aldehyde is present to effect reaction with the cellulose of the material treated as well as with the starch or other carbohydrate. The material may be dried before the heat curing treatment. Specifications 452,149, 460,201, and 503,414 are referred to.ALSO:Cellulosic fibres, fabrics, or paper, are impregnated with a polysaccharide carbohydrate or derivative thereof and formaldehyde, paraformaldehyde, hexamethylene tetramine, or other polymerisation product of formaldehyde, or acetaldol, or glyoxal, the carbohydrate and the aldehyde being applied as separate aqueous solutions or in the form of a combined aqueous solution, and the aldehyde comprising from 0.5 to 5.0 per cent by weight of the solution in which it is applied. After application of the solution the materials are subjected to mechanical lustring treatment and to a heat treatment to effect reaction between the p carbohydrate and aldehyde. The carbohydrate may be starch, acetylated starch, dextrine, glucose, gum arabic, gum tragacanth, or gum karaya. The carbohydrate and aldehyde may be partially condensed before the sizing of the fibrous material. A condensation catalyst may be present. Wetting, softening, or other stiffening agents may be added to the treating solution. In examples, the solutions contain dextrine, starch, pectin, gum arabic, or karaya gum, with formaldehyde or glyoxal and ammonium thiocyanate or ammonium dihydrogen phosphate. Polyethylene glycol, olein oil, lecithin, and the sodium salt of sulphonated tallow, may also be present in the solution.
GB16595/45A 1944-12-07 1945-06-29 Improvements in or relating to the finishing of fabrics and other fibrous materials Expired GB634634A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US634634XA 1944-12-07 1944-12-07

Publications (1)

Publication Number Publication Date
GB634634A true GB634634A (en) 1950-03-22

Family

ID=22049370

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16595/45A Expired GB634634A (en) 1944-12-07 1945-06-29 Improvements in or relating to the finishing of fabrics and other fibrous materials

Country Status (2)

Country Link
DE (1) DE971108C (en)
GB (1) GB634634A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2689194A (en) * 1952-02-18 1954-09-14 Sayles Finishing Plants Inc Finishing process and fabric
US2876136A (en) * 1957-03-20 1959-03-03 Bancroft & Sons Co J Method of producing resinous copolymers in situ on fabrics
US3089747A (en) * 1958-04-04 1963-05-14 American Viscose Corp Method of preparing rayon plisse
US3276885A (en) * 1962-04-05 1966-10-04 Nobel Bozel Permanent finishes for cellulosic articles
US3351479A (en) * 1963-05-14 1967-11-07 Kelco Co Paper coating compositions and processes
US3494777A (en) * 1964-05-13 1970-02-10 Nobel Bozel Printing of washable colored wallpapers

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE568425C (en) * 1931-08-12 1933-01-19 I G Farbenindustrie Akt Ges Process for the production of washable finishes
BE400586A (en) * 1932-12-29 1900-01-01
DE696807C (en) * 1932-12-29 1940-09-30 I G Farbenindustrie Akt Ges Process for producing wash-resistant finishes
DE701071C (en) * 1934-01-27 1941-01-08 I G Farbenindustrie Akt Ges ose fibers or fiber mixtures containing them
DE729609C (en) * 1937-07-15 1942-12-22 Diamalt Ag Method for sizing fabrics
US2302309A (en) * 1939-10-19 1942-11-17 Rohm & Haas Stabilization of wet processed starch pastes with urea-formaldehyde
US2302310A (en) * 1939-10-19 1942-11-17 Rohm & Haas Stabilized partially hydrolyzed starch pastes

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2689194A (en) * 1952-02-18 1954-09-14 Sayles Finishing Plants Inc Finishing process and fabric
US2876136A (en) * 1957-03-20 1959-03-03 Bancroft & Sons Co J Method of producing resinous copolymers in situ on fabrics
US3089747A (en) * 1958-04-04 1963-05-14 American Viscose Corp Method of preparing rayon plisse
US3276885A (en) * 1962-04-05 1966-10-04 Nobel Bozel Permanent finishes for cellulosic articles
US3351479A (en) * 1963-05-14 1967-11-07 Kelco Co Paper coating compositions and processes
US3494777A (en) * 1964-05-13 1970-02-10 Nobel Bozel Printing of washable colored wallpapers

Also Published As

Publication number Publication date
DE971108C (en) 1958-12-11

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