GB922024A - The antistatic treatment of synthetic fibres - Google Patents

The antistatic treatment of synthetic fibres

Info

Publication number
GB922024A
GB922024A GB24015/59A GB2401559A GB922024A GB 922024 A GB922024 A GB 922024A GB 24015/59 A GB24015/59 A GB 24015/59A GB 2401559 A GB2401559 A GB 2401559A GB 922024 A GB922024 A GB 922024A
Authority
GB
United Kingdom
Prior art keywords
weight
amine
parts
water
fibres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24015/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB922024A publication Critical patent/GB922024A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/385—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing epoxy groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/16—Anti-static materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/92—Fire or heat protection feature
    • Y10S428/921—Fire or flameproofing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2221—Coating or impregnation is specified as water proof
    • Y10T442/2246—Nitrogen containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2418—Coating or impregnation increases electrical conductivity or anti-static quality
    • Y10T442/2434—Linear polyether group chain containing

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Epoxy Resins (AREA)

Abstract

A composition suitable for use in the antistatic treatment of synthetic fibres comprises an aqueous solution containing, per 1,000 parts by weight of water, (a) 3-25 parts by weight of a water-soluble diglycidyl ether of polyethylene glycol having an average molecular weight of 300-1,500 which contains 0,75-4,5 epoxide equivalents per kg. and (b) 0,4-15 parts by weight of a primary, secondary or tertiary mono-or polyamine which is water-soluble to the extent of at least 1,5% by weight. Suitable amines are ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine, 1,2-diamino-2-methyl propane, N-N-dimethyl1,3-propylene diamine, N,N,N1,N1-tetramethyl ethylene diamine, N,N,N1,N11,N11-pentamethyl-diethylenetriamine, di(aminoethyl)ether, di-(aminoethyl) sulphide, dibutylamine, benzyldimethylamine, triethanolamine, cyclohexylamine, m-phenylenediamine, 2,4,6-tri(N,N-dimethylaminomethyl)-phenol, N,N-diethyl-1,3-diaminopropane and substituted alkylene polyamines comprising -CN radicals, radicals of the formula -(CH2CH2O)n-R in which n is an integer of 1-10 and R is a hydrogen atom or an alkyl or acyl radical or aliphatically saturated or unsaturated hydrocarbon radicals containing 12-22 carbon atoms which are attached to a nitrogen atom of the amine either directly or through bridge members, e.g. -CO-groups. Mixtures of amines and mixtures of diglycidyl ethers may be used. One active hydrogen atom of an amine is preferably present per epoxide group of the diglycidyl ether or if an amine is used which contains no active hydrogen atoms attached to nitrogen, 0,5-2 tertiary amino groups are preferably present per epoxide group of the diglycidyl ether. After treatment the fibres are dried, e.g. at 30 DEG -50 DEG C., and the impregnation hardened by heating, e.g. at 110 DEG -130 DEG C. Specification 911,227 is referred to.ALSO:Synthetic fibres, e.g. cellulose acetate fibres having a degree of acetyl substitution of two and a half to three, polyacrylonitrile, polyamide, polyester, polyvinyl chloride and polyvinylidene chloride fibres, are rendered antistatic by impregnating them with an aqueous preparation containing, per 1,000 parts by weight of water, (a) 3-25 parts by weight of a water solublediglycidyl ether of a polyethylene glycol having an average molecular weight of 300-1,500 which contains 0,75-4,5 epoxide equivalents per kg. and (b) 0,4-15 parts by weight of a primary, secondary or tertiary mono- or poly amine which is water-soluble to the extent of at least 1,5% by weight, squeezing them to such an extent that 0,5-2% by weight of solids calculated on the dry weight of the fibres are deposited, drying them, e.g. at 30 DEG -50 DEG C., and hardening the impregnation by heating, e.g. at 110 DEG -130 DEG C. Suitable amines are ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine, 1,2-diamino-2-methyl propane, N-N dimethyl-1,3-propylene diamine, N,N,N1,N1-tetramethyl ethylene diamine, N,N,N1,N11,N11-pentamethyl-diethylene triamine, di(aminoethyl)ether, di(aminoethyl)sulphide, dibutylamine, benzyl dimethylamine, triethanolamine, cyclohexylamine, m-phenylenediamine, 2,4,6-tri(N,N-dimethylaminomethyl)phenol, N,N-diethyl-1,3-diamino propane and substituted alkylene polyamines comprising -CN radicals, radicals of the formula -(CH2CH2O)n-in which n is an integer of 1-10 and R is a hydrogen atom or an alkyl or acyl radical or aliphatically saturated or unsaturated hydrocarbon radicals containing 12-22 carbon atoms which are attached to a nitrogen atom of the amine either directly or through bridge members, e.g. -CO-ggroups. Mixtures of amines and mixtures of diglycidyl ethers may be used. One active hydrogen atom of an amine is preferably present per epoxide group of the diglycidyl ether or if an amine is used which contains no active hydrogen atoms attached to nitrogen, 0,5-2 tertiary amino groups are preferably present per epoxide group of the diglycidyl ether. Specification 911,227 is referred to.
GB24015/59A 1958-07-29 1959-07-13 The antistatic treatment of synthetic fibres Expired GB922024A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH6235558 1958-07-29

Publications (1)

Publication Number Publication Date
GB922024A true GB922024A (en) 1963-03-27

Family

ID=4524239

Family Applications (2)

Application Number Title Priority Date Filing Date
GB24015/59A Expired GB922024A (en) 1958-07-29 1959-07-13 The antistatic treatment of synthetic fibres
GB37979/59A Expired GB931733A (en) 1958-07-29 1959-11-09 Process for producing an antistatic finish on synthetic fibers

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB37979/59A Expired GB931733A (en) 1958-07-29 1959-11-09 Process for producing an antistatic finish on synthetic fibers

Country Status (7)

Country Link
US (1) US3154429A (en)
BE (2) BE581122A (en)
DE (1) DE1109133B (en)
ES (1) ES251101A1 (en)
FR (1) FR1231399A (en)
GB (2) GB922024A (en)
NL (3) NL134270C (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3227456A (en) * 1961-12-15 1966-01-04 Eric O Sonneman Golf ball coated with a surface active chemical agent
US3383242A (en) * 1963-01-22 1968-05-14 Glanzstoff Ag Pretreatment of polyethylene terephthalate filaments for subsequent rubber adhesion
BE634185A (en) * 1963-04-11
DE1469344C3 (en) * 1964-04-08 1973-10-31 Bayer Ag, 5090 Leverkusen Process for the antistatic finish of fibrous materials
US3411945A (en) * 1965-03-15 1968-11-19 American Cyanamid Co Process for providing a durable antistatic finish for synthetic textile materials
US3503795A (en) * 1967-05-04 1970-03-31 American Cyanamid Co Durable resinous antistatic textile finish
US4151139A (en) * 1971-08-25 1979-04-24 Sandoz Ltd. Water soluble polyglycol diepoxide-polyamine amide reaction products as antistatic agents
CH548481A (en) * 1971-12-03 1974-04-30
US4197389A (en) * 1977-07-18 1980-04-08 Hoechst Aktiengesellschaft Hardening agent for aqueous epoxy resin compositions
US4847360A (en) * 1987-03-02 1989-07-11 The Firestone Tire & Rubber Company Adhesive active finish for reinforcing members and related methods

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2903381A (en) * 1954-09-03 1959-09-08 Shell Dev Treatment of synthetic textiles with a polyepoxide having a plurality of 1,2 epoxy groups
DE1010736B (en) * 1952-11-19 1957-06-19 Bayer Ag Process for the production of high molecular weight, water-soluble, basic condensation products
US2829071A (en) * 1954-04-26 1958-04-01 Shell Dev Treatment of wool containing textiles
BE538464A (en) * 1954-05-26
DE1006828B (en) * 1954-09-03 1957-04-25 Bataafsche Petroleum Process for increasing the dyeability of textiles made from synthetic fibers and fabrics
US2817602A (en) * 1956-09-18 1957-12-24 Jr Clay E Pardo Shrinkproofing of wool with epoxy resins and polyalkyleneimines
BE574922A (en) * 1958-01-21

Also Published As

Publication number Publication date
NL241737A (en) 1900-01-01
ES251101A1 (en) 1960-01-16
NL134270C (en) 1900-01-01
DE1109133B (en) 1961-06-22
GB931733A (en) 1963-07-17
NL247736A (en) 1900-01-01
FR1231399A (en) 1960-09-28
US3154429A (en) 1964-10-27
BE581122A (en) 1900-01-01
BE584640A (en) 1900-01-01

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