GB921549A - Process for improving the stability of catalytically cracked gasoline - Google Patents
Process for improving the stability of catalytically cracked gasolineInfo
- Publication number
- GB921549A GB921549A GB4189560A GB4189560A GB921549A GB 921549 A GB921549 A GB 921549A GB 4189560 A GB4189560 A GB 4189560A GB 4189560 A GB4189560 A GB 4189560A GB 921549 A GB921549 A GB 921549A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkaline solution
- suitably
- treating
- phenols
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The stability of catalytically cracked gasoline containing phenols and thiophenols is improved by first oxidizing the thiophenols to diphenyl sulphides in the presence of an organic oxidation catalyst (usually at ambient temperatures and pressures), and then treating the thiophenol-free gasoline with an alkaline solution, suitably having a strength below 25 DEG B<\>ae., suitably 2 DEG -20 DEG B<\>ae., so that at least a portion of the phenols are removed, separating the treated gasoline and then preferably treating it with a further alkaline solution of strength greater than 25 DEG B<\>ae., suitably 30 DEG -50 DEG B<\>ae., so that 10-90%, generally 30-70%, of the phenols still present are removed. The preferred catalyst is cobalt or vanadium phthalocyanine sulphonate, but metal free phthalocyanine, unsulphonated metal phthalocyanines or carboxylated metal phthalocyanines and metal chelates of disalicyladiaminoalkanes may also be used. Preferred alkaline solution are aqueous and/or C1-4-alkanolic solutions of sodium and potassium hydroxide. The catalyst may be prepared by treating a carrier with an alkaline solution of the substance; suitable carriers are charcoal, coke, carbon Raschig rings, and solica and/or alumina and may take any suitable form.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85859359A | 1959-12-10 | 1959-12-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB921549A true GB921549A (en) | 1963-03-20 |
Family
ID=25328666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4189560A Expired GB921549A (en) | 1959-12-10 | 1960-12-06 | Process for improving the stability of catalytically cracked gasoline |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1279873B (en) |
| ES (1) | ES263101A1 (en) |
| GB (1) | GB921549A (en) |
| NL (1) | NL258849A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0307146A1 (en) * | 1987-09-10 | 1989-03-15 | Mobil Oil Corporation | Process for improving the thermal stability of jet fuels sweetened by catalytic oxidation |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL70825C (en) * | 1949-08-26 | |||
| US2853432A (en) * | 1954-12-28 | 1958-09-23 | Universal Oil Prod Co | Regeneration of used alkaline reagents by oxidizing the same in the presence of a phthalocyanine catalyst |
-
0
- NL NL258849D patent/NL258849A/xx unknown
-
1960
- 1960-12-06 GB GB4189560A patent/GB921549A/en not_active Expired
- 1960-12-09 DE DEU7640A patent/DE1279873B/en active Pending
- 1960-12-09 ES ES0263101A patent/ES263101A1/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0307146A1 (en) * | 1987-09-10 | 1989-03-15 | Mobil Oil Corporation | Process for improving the thermal stability of jet fuels sweetened by catalytic oxidation |
| US4906354A (en) * | 1987-09-10 | 1990-03-06 | Mobil Oil Corporation | Process for improving the thermal stability of jet fuels sweetened by oxidation |
Also Published As
| Publication number | Publication date |
|---|---|
| ES263101A1 (en) | 1961-05-16 |
| DE1279873B (en) | 1968-10-10 |
| NL258849A (en) |
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