GB914022A - Production of a finely divided polymer - Google Patents
Production of a finely divided polymerInfo
- Publication number
- GB914022A GB914022A GB2846959A GB2846959A GB914022A GB 914022 A GB914022 A GB 914022A GB 2846959 A GB2846959 A GB 2846959A GB 2846959 A GB2846959 A GB 2846959A GB 914022 A GB914022 A GB 914022A
- Authority
- GB
- United Kingdom
- Prior art keywords
- caprolactam
- sulphonyl
- phosphinyl
- nitroso
- acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C08G69/18—Anionic polymerisation
Abstract
S -caprolactam is polymerized by heating at 80 DEG to 125 DEG C. under substantially anhydrous conditions in the presence of (a) a catalytic amount of an alkali or alkaline earth metal including magnesium, or of a compound of such a metal or of an organo-metallic compound of aluminium or zinc which acts as an anionic polymerization catalyst and (b) a compound containing at least one tertiary nitrogen atom, one group linked to the nitrogen atom being a carbonyl, thiocarbonyl, sulphonyl, phosphinyl or thiophosphinyl group and a second being a carbonyl, thiocarbonyl, sulphonyl, phosphinyl, thiophosphinyl or nitroso group. In a modification of the process there is also present a primary or secondary amine. Specified catalysts include sodium, potassium, lithium, calcium, strontium and barium and hydrides, borohydrides, oxides, hydroxides, amides and carbonates thereof, lithium butyl, di-iso-butyl aluminium chloride and phenyl magnesium bromide. Specified compounds containing tertiary nitrogen atoms include N-substituted imides, e.g. N-acetyl-2-pyrrolidone; N-substituted cyclic imides of dicarboxylic acids, e.g. N-phenyl-succinimide; N:N-diacyl primary alkyl and aryl amines and N:N-diacyl acyl amides, e.g. N:N-diacetyl methylamine; the N:N1:N11-triphenyl ester of isocyanuric acid; N-acyl sulphonamides and N-acyl sulphonimides, e.g. N-acetyl-N-ethyl-p-toluene sulphonamide; disulphonamides of primary alkyl and aryl amines, e.g. N:N-di (p-toluene sulphonyl) amide; N-nitrosoamides, e.g. N-nitroso-2-pyrrolidone; N-nitrososulphonamides, e.g. N-nitroso-N-methyl benzene sulphonamide and N-(dimethyl phosphinyl)-S -caprolactam. Specified primary and secondary amines include methylamine, n-propylamine, iso-propylamine, n-butylamine, t-butylamine, n-pentylamine, t-amylamine, n-hexylamine, stearylamine, benzylamine, cyclohexylamine, dicyclohexylamine and morpholine. The examples disclose the polymerization of S -caprolactam in the presence of N-acetylcaprolactam and sodium hydride. The products of the process may be admixed with glass fibres, clays, calcium carbonate, titanium dioxide, carbon black, molybdenum disulphide, dyes or metallic powders and used as moulding compositions.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US75607558A | 1958-08-20 | 1958-08-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB914022A true GB914022A (en) | 1962-12-28 |
Family
ID=25041931
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2846959A Expired GB914022A (en) | 1958-08-20 | 1959-08-20 | Production of a finely divided polymer |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1420604A1 (en) |
GB (1) | GB914022A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4518765A (en) * | 1984-03-19 | 1985-05-21 | The Upjohn Company | Anionic polymerization of lactam with azetidine-2,4-dione promoter |
-
1959
- 1959-08-19 DE DE19591420604 patent/DE1420604A1/en active Pending
- 1959-08-20 GB GB2846959A patent/GB914022A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1420604A1 (en) | 1968-10-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB875994A (en) | Production of polyamides | |
GB914022A (en) | Production of a finely divided polymer | |
GB1361305A (en) | Process for the manufacture of tetra substituted ureas | |
GB1478477A (en) | Adamantylamidines and processes for making them | |
GB872328A (en) | Production of stabilised polyamides | |
GB1298617A (en) | POLYMERISATION OF alpha-AMINO ACID N-CARBOXYANHYDRIDES | |
ES253961A1 (en) | 3 - chloro - 5 - (alpha - dimethylaminopropyl)-iminodibenzyl and its acid addition salts | |
ES470738A1 (en) | Glucofuranos-6-yl-nitroso urea derivatives, processes for their preparation and pharmaceuticals containing them. | |
GB807757A (en) | Manufacture of basic carboxylic esters | |
GB1343426A (en) | Acylated lactams | |
GB1071239A (en) | 2-phenoxy-2-phenylacetamide derivatives, and the manufacture thereof | |
GB1241589A (en) | Amides derived from trichlorothiophene | |
GB608969A (en) | Biotin and its analogues and methods for obtaining the same | |
GB752692A (en) | Improvements in aminoacetic acid derivatives | |
GB976531A (en) | Process for making polypyrrolidone | |
GB1109308A (en) | Heterocyclic alkanoic acid amides | |
US2773093A (en) | Process for the production of aminocarboxylic acids and their n-substituted derivatives | |
GB846377A (en) | 2-substituted-2-propargyl propanediol dicarbamates | |
GB737195A (en) | Improvements in or relating to production of unsaturated amides | |
GB940371A (en) | Improved lactam polymerisation process | |
ZA919554B (en) | 38-decarboxy-38-hydroxymethyl derivatives of tetcoplanin antibiotics,and a process for preparing them | |
GB928312A (en) | Process for the polymerisation of lactams | |
GB1173826A (en) | Phenanthridine Derivatives | |
GB819455A (en) | Process for the preparation of boric acid tri-amides | |
GB841626A (en) | Improvements in and relating to the preparation of organic carbamate compounds |