GB976531A - Process for making polypyrrolidone - Google Patents

Process for making polypyrrolidone

Info

Publication number
GB976531A
GB976531A GB5043/61A GB504361A GB976531A GB 976531 A GB976531 A GB 976531A GB 5043/61 A GB5043/61 A GB 5043/61A GB 504361 A GB504361 A GB 504361A GB 976531 A GB976531 A GB 976531A
Authority
GB
United Kingdom
Prior art keywords
polypyrrolidone
making
acetylpyrrolidone
phenyltrimethylammonium
benzyltrimethylammonium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5043/61A
Inventor
William O Ney
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL261650D priority Critical patent/NL261650A/xx
Priority claimed from US718393A external-priority patent/US2973343A/en
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Priority to GB5043/61A priority patent/GB976531A/en
Priority claimed from DEM48030A external-priority patent/DE1300687B/en
Priority to FR853495A priority patent/FR1284752A/en
Publication of GB976531A publication Critical patent/GB976531A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14Lactams
    • C08G69/24Pyrrolidones or piperidones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Polypyrrolidone, which has a basic inorganic retained ash content of less than 0.005% by weight, is prepared by polymerizing 2-pyrrolidone under substantially anhydrous conditions in the presence of a quaternary ammonium hydroxide catalyst, e.g. of formula R1R2R3R4NOH, wherein R1, R2 and R3 are methyl, ethyl, propyl, butyl, pentyl or hexyl groups and R4 is an alkyl, aryl or aralkyl group. Catalysts specified include tetramethylammonium, benzyltrimethylammonium, and phenyltrimethylammonium hydroxides, and may be present in a proportion of 0.25 to 10 mole per cent. An acyl activator such as acetylpyrrolidone may be added, and polymerization effected at 25 DEG -80 DEG C. Specifications 731,294, 749,332 and 754,944 are referred to.
GB5043/61A 1958-03-03 1961-02-10 Process for making polypyrrolidone Expired GB976531A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NL261650D NL261650A (en) 1958-03-03
GB5043/61A GB976531A (en) 1958-03-03 1961-02-10 Process for making polypyrrolidone
FR853495A FR1284752A (en) 1958-03-03 1961-02-22 Process for the polymerization of 2-pyrrolidone by organic catalysis

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US718393A US2973343A (en) 1958-03-03 1958-03-03 Pyrrolidone polymerization
GB5043/61A GB976531A (en) 1958-03-03 1961-02-10 Process for making polypyrrolidone
DEM48030A DE1300687B (en) 1958-03-03 1961-02-15 Process for the production of polypyrrolidone
FR853495A FR1284752A (en) 1958-03-03 1961-02-22 Process for the polymerization of 2-pyrrolidone by organic catalysis

Publications (1)

Publication Number Publication Date
GB976531A true GB976531A (en) 1964-11-25

Family

ID=29424597

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5043/61A Expired GB976531A (en) 1958-03-03 1961-02-10 Process for making polypyrrolidone

Country Status (3)

Country Link
FR (1) FR1284752A (en)
GB (1) GB976531A (en)
NL (1) NL261650A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2121395A1 (en) * 1971-01-08 1972-08-25 Anvar Anionic polymerisation of pyrrolidone and piperidone - using non metallic catalysts destroyable by heat

Also Published As

Publication number Publication date
FR1284752A (en) 1962-02-16
NL261650A (en)

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