GB976531A - Process for making polypyrrolidone - Google Patents
Process for making polypyrrolidoneInfo
- Publication number
- GB976531A GB976531A GB5043/61A GB504361A GB976531A GB 976531 A GB976531 A GB 976531A GB 5043/61 A GB5043/61 A GB 5043/61A GB 504361 A GB504361 A GB 504361A GB 976531 A GB976531 A GB 976531A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polypyrrolidone
- making
- acetylpyrrolidone
- phenyltrimethylammonium
- benzyltrimethylammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/24—Pyrrolidones or piperidones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Polypyrrolidone, which has a basic inorganic retained ash content of less than 0.005% by weight, is prepared by polymerizing 2-pyrrolidone under substantially anhydrous conditions in the presence of a quaternary ammonium hydroxide catalyst, e.g. of formula R1R2R3R4NOH, wherein R1, R2 and R3 are methyl, ethyl, propyl, butyl, pentyl or hexyl groups and R4 is an alkyl, aryl or aralkyl group. Catalysts specified include tetramethylammonium, benzyltrimethylammonium, and phenyltrimethylammonium hydroxides, and may be present in a proportion of 0.25 to 10 mole per cent. An acyl activator such as acetylpyrrolidone may be added, and polymerization effected at 25 DEG -80 DEG C. Specifications 731,294, 749,332 and 754,944 are referred to.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL261650D NL261650A (en) | 1958-03-03 | ||
GB5043/61A GB976531A (en) | 1958-03-03 | 1961-02-10 | Process for making polypyrrolidone |
FR853495A FR1284752A (en) | 1958-03-03 | 1961-02-22 | Process for the polymerization of 2-pyrrolidone by organic catalysis |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US718393A US2973343A (en) | 1958-03-03 | 1958-03-03 | Pyrrolidone polymerization |
GB5043/61A GB976531A (en) | 1958-03-03 | 1961-02-10 | Process for making polypyrrolidone |
DEM48030A DE1300687B (en) | 1958-03-03 | 1961-02-15 | Process for the production of polypyrrolidone |
FR853495A FR1284752A (en) | 1958-03-03 | 1961-02-22 | Process for the polymerization of 2-pyrrolidone by organic catalysis |
Publications (1)
Publication Number | Publication Date |
---|---|
GB976531A true GB976531A (en) | 1964-11-25 |
Family
ID=29424597
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5043/61A Expired GB976531A (en) | 1958-03-03 | 1961-02-10 | Process for making polypyrrolidone |
Country Status (3)
Country | Link |
---|---|
FR (1) | FR1284752A (en) |
GB (1) | GB976531A (en) |
NL (1) | NL261650A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2121395A1 (en) * | 1971-01-08 | 1972-08-25 | Anvar | Anionic polymerisation of pyrrolidone and piperidone - using non metallic catalysts destroyable by heat |
-
0
- NL NL261650D patent/NL261650A/xx unknown
-
1961
- 1961-02-10 GB GB5043/61A patent/GB976531A/en not_active Expired
- 1961-02-22 FR FR853495A patent/FR1284752A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1284752A (en) | 1962-02-16 |
NL261650A (en) |
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