GB910814A - Improvements in or relating to polymerization of alpha-olefins - Google Patents

Improvements in or relating to polymerization of alpha-olefins

Info

Publication number
GB910814A
GB910814A GB2746461A GB2746461A GB910814A GB 910814 A GB910814 A GB 910814A GB 2746461 A GB2746461 A GB 2746461A GB 2746461 A GB2746461 A GB 2746461A GB 910814 A GB910814 A GB 910814A
Authority
GB
United Kingdom
Prior art keywords
catalyst
vanadium
alpha
oxydichloride
cyclopentadienyl vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2746461A
Inventor
Maseh Osgan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hercules Powder Co
Original Assignee
Hercules Powder Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US24884A priority Critical patent/US3052660A/en
Application filed by Hercules Powder Co filed Critical Hercules Powder Co
Priority to GB2746461A priority patent/GB910814A/en
Publication of GB910814A publication Critical patent/GB910814A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Polymers of alpha-olefines are made by polymerizing one or more olefines in the presence of a catalyst formed by mixing (1) a cyclopentadienyl vanadium oxydihalide or an alkyl cyclopentadienyl vanadium oxydihalide with (2) an alkyl metal compound of a metal of Group 1a, IIa or IIIa of the Periodic Table. Specified alpha-olefins are ethylene, propylene, butene-1, 2-methylbutene-1, pentene-1, 3-methylbutene-1, and mixtures thereof, e.g. ethylene and propylene. The catalyst may be preformed, or made in situ. The polymerization is preferably effected in a hydrocarbon or halogenated aromatic hydrocarbon diluent, using batch or continuous techniques. Component (1) of the catalyst may be cyclopentadienyl vanadium oxydichloride, dibromide, or difluoride, methyl, propyl, or methylethylcyclopentadienyl vanadium oxydichloride, ethylcyclopentadienyl vanadium oxydibromide, or dimethyl cyclopentadienyl vanadium oxydichloride. Component (2) of the catalyst may be selected from alkali and alkaline metal alkyls, aluminium alkyls and hydrides, and halogen-containing aluminium alkyls. Specifications 799,392, 799,823, 801,031 and 806,904 are referred to.
GB2746461A 1960-04-27 1961-07-28 Improvements in or relating to polymerization of alpha-olefins Expired GB910814A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US24884A US3052660A (en) 1960-04-27 1960-04-27 Polymerization of olefins with catalysts of metal alkyls and cyclopentadienyl vanadium oxydihalides
GB2746461A GB910814A (en) 1961-07-28 1961-07-28 Improvements in or relating to polymerization of alpha-olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2746461A GB910814A (en) 1961-07-28 1961-07-28 Improvements in or relating to polymerization of alpha-olefins

Publications (1)

Publication Number Publication Date
GB910814A true GB910814A (en) 1962-11-21

Family

ID=10260022

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2746461A Expired GB910814A (en) 1960-04-27 1961-07-28 Improvements in or relating to polymerization of alpha-olefins

Country Status (1)

Country Link
GB (1) GB910814A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4564647A (en) * 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4564647A (en) * 1983-11-14 1986-01-14 Idemitsu Kosan Company Limited Process for the production of polyethylene compositions

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