GB908772A - Activators for the polymerization of pyrrolidone - Google Patents
Activators for the polymerization of pyrrolidoneInfo
- Publication number
- GB908772A GB908772A GB31942/59A GB3194259A GB908772A GB 908772 A GB908772 A GB 908772A GB 31942/59 A GB31942/59 A GB 31942/59A GB 3194259 A GB3194259 A GB 3194259A GB 908772 A GB908772 A GB 908772A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium hydride
- polymerization
- halogen
- alkyl
- pyrrolidone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012190 activator Substances 0.000 title abstract 5
- 238000006116 polymerization reaction Methods 0.000 title abstract 5
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 title abstract 5
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 14
- 229910000104 sodium hydride Inorganic materials 0.000 abstract 14
- 239000012312 sodium hydride Substances 0.000 abstract 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 9
- 229910052783 alkali metal Inorganic materials 0.000 abstract 5
- 150000001340 alkali metals Chemical class 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 229910052736 halogen Inorganic materials 0.000 abstract 5
- 150000002367 halogens Chemical class 0.000 abstract 5
- IMDXZWRLUZPMDH-UHFFFAOYSA-N dichlorophenylphosphine Chemical compound ClP(Cl)C1=CC=CC=C1 IMDXZWRLUZPMDH-UHFFFAOYSA-N 0.000 abstract 4
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 3
- VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 abstract 3
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 abstract 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 3
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 abstract 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 abstract 2
- JAYBZWYBCUJLNQ-UHFFFAOYSA-N dichloro-(chloromethyl)-methylsilane Chemical compound C[Si](Cl)(Cl)CCl JAYBZWYBCUJLNQ-UHFFFAOYSA-N 0.000 abstract 2
- IBDMRHDXAQZJAP-UHFFFAOYSA-N dichlorophosphorylbenzene Chemical compound ClP(Cl)(=O)C1=CC=CC=C1 IBDMRHDXAQZJAP-UHFFFAOYSA-N 0.000 abstract 2
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 abstract 2
- 125000001188 haloalkyl group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- 239000005050 vinyl trichlorosilane Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229920001007 Nylon 4 Polymers 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- 150000001243 acetic acids Chemical class 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003929 acidic solution Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- JROURLWMOZCGJV-UHFFFAOYSA-N alizarin blue Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C1=CC=CN=C1C(O)=C2O JROURLWMOZCGJV-UHFFFAOYSA-N 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical group [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000012662 bulk polymerization Methods 0.000 abstract 1
- 125000004982 dihaloalkyl group Chemical group 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 150000004674 formic acids Chemical class 0.000 abstract 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 abstract 1
- 125000005059 halophenyl group Chemical group 0.000 abstract 1
- -1 halovinyl Chemical group 0.000 abstract 1
- 150000004678 hydrides Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- OHZZTXYKLXZFSZ-UHFFFAOYSA-I manganese(3+) 5,10,15-tris(1-methylpyridin-1-ium-4-yl)-20-(1-methylpyridin-4-ylidene)porphyrin-22-ide pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mn+3].C1=CN(C)C=CC1=C1C(C=C2)=NC2=C(C=2C=C[N+](C)=CC=2)C([N-]2)=CC=C2C(C=2C=C[N+](C)=CC=2)=C(C=C2)N=C2C(C=2C=C[N+](C)=CC=2)=C2N=C1C=C2 OHZZTXYKLXZFSZ-UHFFFAOYSA-I 0.000 abstract 1
- ZFYHTGWRVARNFD-UHFFFAOYSA-I pentaiodo-lambda5-stibane Chemical compound I[Sb](I)(I)(I)I ZFYHTGWRVARNFD-UHFFFAOYSA-I 0.000 abstract 1
- 125000003884 phenylalkyl group Chemical group 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910001950 potassium oxide Inorganic materials 0.000 abstract 1
- 239000005053 propyltrichlorosilane Substances 0.000 abstract 1
- 150000004040 pyrrolidinones Chemical class 0.000 abstract 1
- 239000010703 silicon Chemical group 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- XGEFAQYKJRWNPX-UHFFFAOYSA-N trichloro(1-trichlorosilylethenyl)silane Chemical group Cl[Si](Cl)(Cl)C(=C)[Si](Cl)(Cl)Cl XGEFAQYKJRWNPX-UHFFFAOYSA-N 0.000 abstract 1
- DOEHJNBEOVLHGL-UHFFFAOYSA-N trichloro(propyl)silane Chemical compound CCC[Si](Cl)(Cl)Cl DOEHJNBEOVLHGL-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
- C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
- C08J3/095—Oxygen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/24—Pyrrolidones or piperidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Polyamides (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US763209A US3210324A (en) | 1958-09-25 | 1958-09-25 | Benzenephosphorus dichloride and benzenephosphorus oxydichloride as activators for the polymerization of pyrrolidone |
| US763208A US3383367A (en) | 1958-09-25 | 1958-09-25 | Activators for the polymerization of pyrroldione |
| US763207A US3180855A (en) | 1958-09-25 | 1958-09-25 | Halo-silanes as activators for the polymerization of pyrrolidone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB908772A true GB908772A (en) | 1962-10-24 |
Family
ID=27419566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31942/59A Expired GB908772A (en) | 1958-09-25 | 1959-09-18 | Activators for the polymerization of pyrrolidone |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US3383367A (en, 2012) |
| BE (1) | BE582869A (en, 2012) |
| CH (1) | CH401480A (en, 2012) |
| DK (1) | DK105558C (en, 2012) |
| FR (1) | FR1236744A (en, 2012) |
| GB (1) | GB908772A (en, 2012) |
| NL (2) | NL126761C (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3341501A (en) * | 1963-05-31 | 1967-09-12 | Monsanto Co | Polyamides containing silane end groups |
| US3890280A (en) * | 1969-04-07 | 1975-06-17 | Chevron Res | Polymerization of 2-pyrrolidone with alkali metal bicarbonate as catalyst |
| US3968087A (en) * | 1972-11-24 | 1976-07-06 | Chevron Research Company | Polymerization of 2-pyrrolidone |
| US3954738A (en) * | 1974-01-04 | 1976-05-04 | M&T Chemicals Inc. | Stabilized epsilon caprolactam composition and method for preparing same |
| US4124468A (en) * | 1975-12-08 | 1978-11-07 | Serenkov Vasily I | Process for the production of polyamides |
| US4448954A (en) * | 1982-08-17 | 1984-05-15 | Celanese Corporation | Single stage production of improved high molecular weight polybenzimidazole with organosilicon halide catalyst. |
| DE3400237A1 (de) * | 1983-12-30 | 1985-07-11 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung aromatischer polyamide |
| USD813060S1 (en) | 2016-10-06 | 2018-03-20 | Diamond Tech LLC | Wood level with block vials |
| JP7177969B2 (ja) * | 2020-06-09 | 2022-11-24 | 株式会社クレハ | ポリアミド樹脂組成物、ポリアミド樹脂成形品、およびその製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR870844A (fr) * | 1940-03-23 | 1942-03-25 | Heinrich Lanz Ag | Mode d'entraînement pour presses à paille, en particulier celles actionnées individuellement |
| BE494129A (en, 2012) * | 1949-07-22 | |||
| US2806841A (en) * | 1953-02-24 | 1957-09-17 | Arnold Hoffman & Co Inc | Polymers of alpha-piperidone |
| US2739959A (en) * | 1953-02-24 | 1956-03-27 | Arnold Hoffman & Co Inc | Polymerization of pyrolidone and piperidone |
-
0
- NL NL243725D patent/NL243725A/xx unknown
-
1958
- 1958-09-25 US US763208A patent/US3383367A/en not_active Expired - Lifetime
- 1958-09-25 US US763209A patent/US3210324A/en not_active Expired - Lifetime
- 1958-09-25 US US763207A patent/US3180855A/en not_active Expired - Lifetime
-
1959
- 1959-09-18 CH CH7836459A patent/CH401480A/fr unknown
- 1959-09-18 GB GB31942/59A patent/GB908772A/en not_active Expired
- 1959-09-21 BE BE582869D patent/BE582869A/xx unknown
- 1959-09-23 FR FR805848A patent/FR1236744A/fr not_active Expired
- 1959-09-24 DK DK342159AA patent/DK105558C/da active
- 1959-09-24 NL NL243725A patent/NL126761C/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| NL243725A (en, 2012) | |
| FR1236744A (fr) | 1960-11-18 |
| BE582869A (en, 2012) | 1960-03-21 |
| US3180855A (en) | 1965-04-27 |
| CH401480A (fr) | 1965-10-31 |
| US3210324A (en) | 1965-10-05 |
| US3383367A (en) | 1968-05-14 |
| NL126761C (en, 2012) | 1969-06-16 |
| DK105558C (da) | 1966-10-10 |
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