GB905809A - An improved method for the continuous selective hydrofining of crude petroleum in the liquid phase - Google Patents
An improved method for the continuous selective hydrofining of crude petroleum in the liquid phaseInfo
- Publication number
- GB905809A GB905809A GB34570/59A GB3457059A GB905809A GB 905809 A GB905809 A GB 905809A GB 34570/59 A GB34570/59 A GB 34570/59A GB 3457059 A GB3457059 A GB 3457059A GB 905809 A GB905809 A GB 905809A
- Authority
- GB
- United Kingdom
- Prior art keywords
- crude petroleum
- liquid phase
- mixture
- improved method
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/22—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen dissolved or suspended in the oil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Crude petroleum is hydrofined in the liquid phase by contacting a mixture of hydrogen and the crude oil with a catalyst selected from the oxides and sulphides of chromium, molybdenum, tungsten, iron, cobalt and nickel at 300 DEG -395 DEG C. and a pressure of 55 - 120 kg./cm2. Best results are obtained by employing the higher pressures in the quoted range with the lower temperatures. The mixture to be treated most suitably comprises a saturated solution of hydrogen in the crude petroleum, and the catalyst may be mounted in a fixed bed or suspended in the oil. The catalyst, which is preferably a mixture and/or compound of the oxides of molybdenum and cobalt, may be supported on silica, magnesium oxide, kieselguhr, activated carbon, or, most suitably, alumina, usually has a grain size of 0,1 - 10 mm., preferably 1 - 5 mm., when used in a fixed bed and a grain size of 0,05 - 0,5 mm. when used in solution.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR776811A FR1313057A (en) | 1958-10-16 | 1958-10-16 | Continuous process for the selective hydrotreatment of crude oils in the liquid phase |
Publications (1)
Publication Number | Publication Date |
---|---|
GB905809A true GB905809A (en) | 1962-09-12 |
Family
ID=8707747
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB34570/59A Expired GB905809A (en) | 1958-10-16 | 1959-10-12 | An improved method for the continuous selective hydrofining of crude petroleum in the liquid phase |
Country Status (5)
Country | Link |
---|---|
DE (1) | DE1161373B (en) |
ES (1) | ES252619A1 (en) |
FR (1) | FR1313057A (en) |
GB (1) | GB905809A (en) |
OA (1) | OA01279A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE29315E (en) * | 1968-10-25 | 1977-07-19 | Gulf Research & Development Company | Asphaltene hydrodesulfurization with small catalyst particles utilizing a hydrogen quench for the reaction |
USRE29314E (en) * | 1968-10-25 | 1977-07-19 | Gulf Research & Development Company | Asphaltene hydrodesulfurization with small catalyst particles in a parallel reactor system |
EP0534046A2 (en) * | 1991-09-19 | 1993-03-31 | Wolfdieter Klein | Process for the treatment of contaminated liquid, liquefactable or solid hydrocarbons or hydrocarbon compounds |
WO2003091363A1 (en) * | 2002-04-23 | 2003-11-06 | Bp Oil International Limited | Purification process |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1950308A (en) * | 1929-08-14 | 1934-03-06 | Standard Ig Co | Improved process for producing lubricants |
US2073578A (en) * | 1933-01-10 | 1937-03-09 | Gwynn Marion Hayes | Method of refining hydrocarbon distillates |
US2145657A (en) * | 1936-12-30 | 1939-01-31 | Universal Oil Prod Co | Process for the hydrogenation of hydrocarbon oils |
FR977868A (en) * | 1947-12-22 | 1951-04-06 | Bataafsche Petroleum | Catalytic refining process for distillable hydrocarbon oils |
US2608521A (en) * | 1948-01-06 | 1952-08-26 | Shell Dev | Process for refining carbonaceous material |
NL71604C (en) * | 1948-01-06 | |||
DE869198C (en) * | 1950-05-21 | 1953-03-05 | Basf Ag | Process for purifying crude benzene |
BE505693A (en) * | 1950-09-07 | |||
DE930889C (en) * | 1953-08-18 | 1955-07-28 | Basf Ag | Process for the production of gasoline from petroleum |
DE954634C (en) * | 1954-03-19 | 1956-12-20 | Basf Ag | Process for the catalytic pressure refining of low-boiling hydrocarbons |
DE956539C (en) * | 1954-09-04 | 1957-01-17 | Metallgesellschaft Ag | Process for refining hydrocarbons which are liquid under normal conditions by catalytic treatment with hydrogen or hydrogen-containing gases |
DE1012718B (en) * | 1955-09-01 | 1957-07-25 | Metallgesellschaft Ag | Process for the production of mixed diesel fuels |
-
1958
- 1958-10-16 FR FR776811A patent/FR1313057A/en not_active Expired
-
1959
- 1959-10-12 GB GB34570/59A patent/GB905809A/en not_active Expired
- 1959-10-13 ES ES0252619A patent/ES252619A1/en not_active Expired
- 1959-10-14 DE DEI17111A patent/DE1161373B/en active Pending
-
1964
- 1964-12-31 OA OA51628A patent/OA01279A/en unknown
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE29315E (en) * | 1968-10-25 | 1977-07-19 | Gulf Research & Development Company | Asphaltene hydrodesulfurization with small catalyst particles utilizing a hydrogen quench for the reaction |
USRE29314E (en) * | 1968-10-25 | 1977-07-19 | Gulf Research & Development Company | Asphaltene hydrodesulfurization with small catalyst particles in a parallel reactor system |
EP0534046A2 (en) * | 1991-09-19 | 1993-03-31 | Wolfdieter Klein | Process for the treatment of contaminated liquid, liquefactable or solid hydrocarbons or hydrocarbon compounds |
EP0534046A3 (en) * | 1991-09-19 | 1993-04-14 | Wolfdieter Klein | Process for the treatment of contaminated liquid, liquefactable or solid hydrocarbons or hydrocarbon compounds |
WO2003091363A1 (en) * | 2002-04-23 | 2003-11-06 | Bp Oil International Limited | Purification process |
Also Published As
Publication number | Publication date |
---|---|
OA01279A (en) | 1969-02-15 |
FR1313057A (en) | 1962-12-28 |
ES252619A1 (en) | 1960-02-01 |
DE1161373B (en) | 1964-01-16 |
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