GB900150A - A process for the alkaline polymerisation of lactams - Google Patents
A process for the alkaline polymerisation of lactamsInfo
- Publication number
- GB900150A GB900150A GB24220/60A GB2422060A GB900150A GB 900150 A GB900150 A GB 900150A GB 24220/60 A GB24220/60 A GB 24220/60A GB 2422060 A GB2422060 A GB 2422060A GB 900150 A GB900150 A GB 900150A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- carbamido
- lactam
- pyrrolidone
- tris
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003951 lactams Chemical class 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 8
- -1 hydrocarbon radicals Chemical class 0.000 abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 abstract 4
- 239000012190 activator Substances 0.000 abstract 4
- 229930195733 hydrocarbon Natural products 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 abstract 3
- 150000003254 radicals Chemical class 0.000 abstract 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical class NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 125000001033 ether group Chemical group 0.000 abstract 2
- 229910052731 fluorine Inorganic materials 0.000 abstract 2
- 239000011737 fluorine Substances 0.000 abstract 2
- 125000001153 fluoro group Chemical group F* 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 abstract 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical class NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 abstract 2
- HLLFDAUUFNJYLI-UHFFFAOYSA-N 1-(4-ethoxyphenyl)-1-phenylurea Chemical compound C(C)OC1=CC=C(C=C1)N(C(=O)N)C1=CC=CC=C1 HLLFDAUUFNJYLI-UHFFFAOYSA-N 0.000 abstract 1
- QMOJOTUPVIJOCI-UHFFFAOYSA-N 1-(4-fluorophenyl)-1-(4-methoxyphenyl)urea Chemical compound COC1=CC=C(C=C1)N(C(N)=O)C1=CC=C(F)C=C1 QMOJOTUPVIJOCI-UHFFFAOYSA-N 0.000 abstract 1
- HTVJVSDUXWPOHE-UHFFFAOYSA-N 1-(4-fluorophenyl)-1-phenylurea Chemical compound C=1C=C(F)C=CC=1N(C(=O)N)C1=CC=CC=C1 HTVJVSDUXWPOHE-UHFFFAOYSA-N 0.000 abstract 1
- FAAVQMPIVGKIMO-UHFFFAOYSA-N 1-[10-[(N-carbamothioylanilino)methyl]octadecyl]-1-phenylthiourea Chemical compound C1(=CC=CC=C1)N(C(=S)N)CC(CCCCCCCCCN(C(=S)N)C1=CC=CC=C1)CCCCCCCC FAAVQMPIVGKIMO-UHFFFAOYSA-N 0.000 abstract 1
- VSQIEGPVSVWHJP-UHFFFAOYSA-N 1-[3-(N-carbamothioylanilino)-4-methylphenyl]-1-phenylthiourea Chemical compound C1(=CC=CC=C1)N(C(=S)N)C1=CC(=C(C=C1)C)N(C(=S)N)C1=CC=CC=C1 VSQIEGPVSVWHJP-UHFFFAOYSA-N 0.000 abstract 1
- VKKXITJIHZISRU-UHFFFAOYSA-N 1-[3-(n-carbamoylanilino)-4-methylphenyl]-1-phenylurea Chemical compound CC1=CC=C(N(C(N)=O)C=2C=CC=CC=2)C=C1N(C(N)=O)C1=CC=CC=C1 VKKXITJIHZISRU-UHFFFAOYSA-N 0.000 abstract 1
- QETDOAYAZTXVEM-UHFFFAOYSA-N 1-[9-[(N-carbamoylanilino)methyl]octadecyl]-1-phenylurea Chemical compound C1(=CC=CC=C1)N(C(=O)N)CC(CCCCCCCCN(C(=O)N)C1=CC=CC=C1)CCCCCCCCC QETDOAYAZTXVEM-UHFFFAOYSA-N 0.000 abstract 1
- PDYBINSXQLDRPO-UHFFFAOYSA-N 1-butyl-1-phenylthiourea Chemical compound CCCCN(C(N)=S)C1=CC=CC=C1 PDYBINSXQLDRPO-UHFFFAOYSA-N 0.000 abstract 1
- GOGYHVOOMHFPAC-UHFFFAOYSA-N 1-butyl-1-phenylurea Chemical compound CCCCN(C(N)=O)C1=CC=CC=C1 GOGYHVOOMHFPAC-UHFFFAOYSA-N 0.000 abstract 1
- JGXNGCUACVIHHA-UHFFFAOYSA-N 1-octadecyl-1-phenylurea Chemical compound CCCCCCCCCCCCCCCCCCN(C(N)=O)C1=CC=CC=C1 JGXNGCUACVIHHA-UHFFFAOYSA-N 0.000 abstract 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Chemical class CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 150000005840 aryl radicals Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Chemical class CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 150000003672 ureas Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C08G69/18—Anionic polymerisation
- C08G69/20—Anionic polymerisation characterised by the catalysts used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Hydrogenated Pyridines (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB0053999 | 1959-07-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB900150A true GB900150A (en) | 1962-07-04 |
Family
ID=6970450
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB24220/60A Expired GB900150A (en) | 1959-07-14 | 1960-07-12 | A process for the alkaline polymerisation of lactams |
| GB24367/60A Expired GB900151A (en) | 1959-07-14 | 1960-07-13 | A process for the alkaline polymerisation of lactams |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB24367/60A Expired GB900151A (en) | 1959-07-14 | 1960-07-13 | A process for the alkaline polymerisation of lactams |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3304291A (enExample) |
| BE (1) | BE592979A (enExample) |
| CH (1) | CH393741A (enExample) |
| DE (1) | DE1420241B2 (enExample) |
| FR (1) | FR1262436A (enExample) |
| GB (2) | GB900150A (enExample) |
| NL (2) | NL124646C (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3216977A (en) * | 1962-12-13 | 1965-11-09 | Du Pont | Anionic polymerization of lactams with methylene oxazolidine-4, 5-dione compounds as activators |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1222254B (de) * | 1961-08-31 | 1966-08-04 | Basf Ag | Verfahren zur anionischen Polymerisation von Lactamen |
| BE623840A (enExample) * | 1961-10-20 | |||
| NL287941A (enExample) * | 1962-01-20 | |||
| BE631857A (enExample) * | 1962-05-04 | |||
| US3316221A (en) * | 1963-07-01 | 1967-04-25 | Du Pont | Aromatic ester cocatalysts for lactam polymerization |
| US3320335A (en) * | 1963-04-22 | 1967-05-16 | Monsanto Co | Process for polymerizing higher lactams in the presence of urethane polymer promoters |
| GB1039113A (en) * | 1964-08-06 | 1966-08-17 | Ucb Sa | New n-substituted lactams |
| US3366608A (en) * | 1965-04-15 | 1968-01-30 | British Celanese | Anionic polymerization of caprolactam |
| US3440227A (en) * | 1966-03-31 | 1969-04-22 | Budd Co | Polymerization of higher lactams |
| US3621001A (en) * | 1967-07-06 | 1971-11-16 | Basf Ag | Accelerating anionic polymerization of lactams |
| DE2507549A1 (de) * | 1974-05-21 | 1975-12-04 | Bhnf Ag | Poly-laurinlactam, verfahren zur herstellung hoeherer poly-lactame und deren verwendung |
| DE2637010A1 (de) | 1976-08-17 | 1978-02-23 | Bayer Ag | Aktivierte anionische polymerisation |
| US4374771A (en) * | 1982-03-08 | 1983-02-22 | American Cyanamid Company | Blocked isocyanate |
| US4507465A (en) * | 1982-12-29 | 1985-03-26 | Toray Industries, Inc. | Process for producing lactam/polyol block copolymer |
| CA1214012A (en) * | 1983-01-27 | 1986-11-18 | Wei-Yeih W. Yang | Rim process using single component composition |
| US4501821A (en) * | 1983-07-28 | 1985-02-26 | Ppg Industries, Inc. | Property enhancement of anionically polymerized nylon with dual initiators |
| US4582879A (en) * | 1984-03-22 | 1986-04-15 | Frisch Kurt C | Reaction injection molding process and reaction injection molded products |
| DE3425318A1 (de) * | 1984-07-10 | 1986-01-16 | Bayer Ag, 5090 Leverkusen | Verzweigte, thermoplastisch verarbeitbare, schlagzaehe polyamide |
| WO2011144602A1 (de) | 2010-05-19 | 2011-11-24 | Basf Se | Quervernetztes polyamid |
| US8957133B2 (en) | 2010-07-20 | 2015-02-17 | Basf Se | Polyamide moldings comprising microencapsulated latent-heat-accumulator material |
| JP2013538251A (ja) | 2010-07-20 | 2013-10-10 | ビーエーエスエフ ソシエタス・ヨーロピア | マイクロカプセル化した潜熱アキュムレータ材料を含有するポリアミド成形品 |
| JP5857055B2 (ja) | 2010-10-07 | 2016-02-10 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | モノマー−組成物を製造するための方法、及びこの方法をポリアミド成形物を製造するために使用する方法 |
| US9139692B2 (en) | 2010-12-03 | 2015-09-22 | Basf Se | Process for polymerizing lactam |
| EP2460838A1 (de) | 2010-12-03 | 2012-06-06 | Basf Se | Verfahren zur Polymerisation von Lactam |
| KR20130126944A (ko) | 2010-12-03 | 2013-11-21 | 바스프 에스이 | 가교결합된 폴리아미드 |
| WO2013004645A1 (de) | 2011-07-05 | 2013-01-10 | Basf Se | Feste partikel, enthaltend lactam, aktivator und katalysator, sowie verfahren zu deren herstellung und deren verwendung |
| MY163324A (en) | 2011-08-23 | 2017-09-15 | Basf Se | Method for producing molded articles |
| US8957180B2 (en) | 2011-08-23 | 2015-02-17 | Basf Se | Process for producing moldings |
| EP2748228B1 (de) | 2011-08-23 | 2019-10-09 | Basf Se | Verfahren zur herstellung von formkörpern |
| JP2015514831A (ja) | 2012-03-27 | 2015-05-21 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 重合可能な組成物から、回転溶融法でポリアミド成形体を製造する方法 |
| US20160068679A1 (en) | 2013-04-04 | 2016-03-10 | Basf Se | Polymerizable lactam composition containing a sulfonated polyaryl sulfone |
| US20180029291A1 (en) | 2015-02-05 | 2018-02-01 | Stratasys Ltd. | Digitally-controlled three-dimensional printing of polymerizable materials |
| WO2017134672A2 (en) | 2016-02-05 | 2017-08-10 | Stratasys Ltd. | Three-dimensional inkjet printing using polyamide-forming materials |
| CN109749077A (zh) * | 2018-12-09 | 2019-05-14 | 中山大学 | 一种利用（硫）脲/碱金属化合物催化剂制备高分子量聚酰胺的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB863859A (en) * | 1956-07-23 | 1961-03-29 | Monsanto Chemicals | Polymerisation of lactams |
| US3017391A (en) * | 1956-12-13 | 1962-01-16 | Monsanto Chemicals | Preparation of polycaprolactam using n-acyl activators |
| US3148174A (en) * | 1958-04-04 | 1964-09-08 | Gen Aniline & Film Corp | Polymerization of pyrrolidone and piperidone employing nu, nu-disubstituted ureas aschain initiators |
| US3086962A (en) * | 1958-10-03 | 1963-04-23 | Monsanto Chemicals | Process for polymerizing higher lactams |
-
0
- NL NL253790D patent/NL253790A/xx unknown
- BE BE592979D patent/BE592979A/xx unknown
- NL NL124646D patent/NL124646C/xx active
-
1959
- 1959-07-14 DE DE19591420241 patent/DE1420241B2/de active Pending
-
1960
- 1960-07-12 GB GB24220/60A patent/GB900150A/en not_active Expired
- 1960-07-12 CH CH795660A patent/CH393741A/de unknown
- 1960-07-13 GB GB24367/60A patent/GB900151A/en not_active Expired
- 1960-07-15 FR FR833021A patent/FR1262436A/fr not_active Expired
-
1965
- 1965-03-22 US US441860A patent/US3304291A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3216977A (en) * | 1962-12-13 | 1965-11-09 | Du Pont | Anionic polymerization of lactams with methylene oxazolidine-4, 5-dione compounds as activators |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1262436A (fr) | 1961-05-26 |
| US3304291A (en) | 1967-02-14 |
| DE1420241A1 (de) | 1969-02-13 |
| CH393741A (de) | 1965-06-15 |
| NL124646C (enExample) | |
| DE1420241B2 (de) | 1972-01-27 |
| GB900151A (en) | 1962-07-04 |
| BE592979A (enExample) | |
| NL253790A (enExample) |
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