GB898309A - Tetrafluoroethylene telomers - Google Patents

Tetrafluoroethylene telomers

Info

Publication number
GB898309A
GB898309A GB3396059A GB3396059A GB898309A GB 898309 A GB898309 A GB 898309A GB 3396059 A GB3396059 A GB 3396059A GB 3396059 A GB3396059 A GB 3396059A GB 898309 A GB898309 A GB 898309A
Authority
GB
United Kingdom
Prior art keywords
telomers
mixture
tetrafluoroethylene
less
sf5cl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3396059A
Inventor
Hugh Leithead Roberts
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL120196D priority Critical patent/NL120196C/xx
Priority to BE595768D priority patent/BE595768A/xx
Priority to NL256615D priority patent/NL256615A/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3396059A priority patent/GB898309A/en
Priority to FR840602A priority patent/FR1272200A/en
Publication of GB898309A publication Critical patent/GB898309A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Telomers of the formula SF5(C2F4)nCl, where n is less than 12 are prepared by subjecting a mixture of tetrafluoroethylene and sulphur chloride pentafluoride to the action of heat in the absence of ultra-violet radiation. Telomerization may be effected at normal pressure, e.g. by passing the mixed vapours through a nickel tube heated to 200 DEG to 300 DEG C., and condensing the product in a series of traps, or at autogenous pressure in a sealed vessel, e.g. 150 to 250 atmospheres at 250 DEG C. Higher telomers may also be obtained when the mixture contains less than 3 molar per cent SF5Cl. Specification 877,961 is referred to.ALSO:Telomers of the formula SF5(C2F4)nCl, where n is less than 12, are prepared by subjecting a mixture of tetrafluoroethylene and sulphur chloride pentafluoride to the action of heat in the absence of ultraviolet radiation. Telomerisation may be effected at normal pressure, e.g. by passing the mixed vapours through a nickel tube heated to 200 DEG C. to 300 DEG C. and condensing the product in a series of traps, or at autogenous pressure in a sealed vessel, e.g. 150 to 250 atmospheres at 250 DEG C. The mixture should contain at least 3 molar per cent SF5Cl, lower concentrations giving higher telomers. Specification 877,961 is referred to.
GB3396059A 1959-10-07 1959-10-07 Tetrafluoroethylene telomers Expired GB898309A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
NL120196D NL120196C (en) 1959-10-07
BE595768D BE595768A (en) 1959-10-07
NL256615D NL256615A (en) 1959-10-07
GB3396059A GB898309A (en) 1959-10-07 1959-10-07 Tetrafluoroethylene telomers
FR840602A FR1272200A (en) 1959-10-07 1960-10-07 Production of tetrafluoroethylene and pentafluoro-sulfur chloride telomers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3396059A GB898309A (en) 1959-10-07 1959-10-07 Tetrafluoroethylene telomers

Publications (1)

Publication Number Publication Date
GB898309A true GB898309A (en) 1962-06-06

Family

ID=10359601

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3396059A Expired GB898309A (en) 1959-10-07 1959-10-07 Tetrafluoroethylene telomers

Country Status (3)

Country Link
BE (1) BE595768A (en)
GB (1) GB898309A (en)
NL (2) NL256615A (en)

Also Published As

Publication number Publication date
BE595768A (en)
NL120196C (en)
NL256615A (en)

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