GB896306A - A process for improving the thermal oxidative degradation and simultaneous purification of linear polyolefines - Google Patents

A process for improving the thermal oxidative degradation and simultaneous purification of linear polyolefines

Info

Publication number
GB896306A
GB896306A GB37622/60A GB3762260A GB896306A GB 896306 A GB896306 A GB 896306A GB 37622/60 A GB37622/60 A GB 37622/60A GB 3762260 A GB3762260 A GB 3762260A GB 896306 A GB896306 A GB 896306A
Authority
GB
United Kingdom
Prior art keywords
polyolefin
solution
prepared
oxidative degradation
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB37622/60A
Inventor
Alfred Helms
Rudolf Herbeck
Hans Lautenschlager
Hans Georg Trieschmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB896306A publication Critical patent/GB896306A/en
Expired legal-status Critical Current

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Abstract

In an improvement in the process of the parent Specification for the thermal oxidative degradation and simultaneous purification of linear polyolefins prepared by polymerization of olefins containing 2 to 4 carbon atoms with catalysts containing heavy metals of Group IVa, Va or VIa of the Mendeleeff Periodic Table and which contain small amounts of these catalysts, which comprises dissolving the polyolefin in an inert organic solvent and heating the solution in the presence of oxygen or oxygen supplying compounds for 15 to 200 minutes at 70 DEG to 240 DEG C., the solution of the polyolefin is prepared from a suspension of the polyolefin in the solvent by leading in superheated steam. The superheated steam may be under a pressure of 5 to 100 atmospheres, and basic compounds such as ammonia or alkylamines, air or oxygen may be metered into the steam. In an example a solution of polypropylene is prepared from a suspension thereof in heptane by leading in steam at 14 atmospheres into which ammonia and air have been metered.
GB37622/60A 1959-11-04 1960-11-02 A process for improving the thermal oxidative degradation and simultaneous purification of linear polyolefines Expired GB896306A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE896306X 1959-11-04

Publications (1)

Publication Number Publication Date
GB896306A true GB896306A (en) 1962-05-16

Family

ID=6848137

Family Applications (1)

Application Number Title Priority Date Filing Date
GB37622/60A Expired GB896306A (en) 1959-11-04 1960-11-02 A process for improving the thermal oxidative degradation and simultaneous purification of linear polyolefines

Country Status (1)

Country Link
GB (1) GB896306A (en)

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