GB884748A - Improvements in or relating to solid oxidizing compositions and solutions containing monopersulphate ions - Google Patents

Improvements in or relating to solid oxidizing compositions and solutions containing monopersulphate ions

Info

Publication number
GB884748A
GB884748A GB7765/59A GB776559A GB884748A GB 884748 A GB884748 A GB 884748A GB 7765/59 A GB7765/59 A GB 7765/59A GB 776559 A GB776559 A GB 776559A GB 884748 A GB884748 A GB 884748A
Authority
GB
United Kingdom
Prior art keywords
alkali
contain
metal
carbonates
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7765/59A
Inventor
Walter Klabunde
Donald Bixby Lake
Stephen Emmanuel Stephanou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB7765/59A priority Critical patent/GB884748A/en
Priority to FR790249A priority patent/FR1221393A/en
Publication of GB884748A publication Critical patent/GB884748A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/13Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

A solid detergent composition which, when dissolved in water, may be used for washing and bleaching fibrous materials comprises (1) a soap, e.g. the sodium or potassium salts of fatty acids, or other detergent, e.g. sodium hydrocarbon sulphonates, (2) at least one alkali-metal monopersulphate and (3) at least one of the following alkaline water-soluble extenders, i.e. alkali-metal phosphates, silicates and carbonates, with or without at least one alkaline water-soluble boron compound, e.g. borax, in amount not exceeding the total weight of phosphate, silicate, and carbonate extender, the proportions of the components being such that, when the composition is dissolved in water, the resulting solution has a pH of 8-12. The aqueous bleaching and washing solutions which have pH values of 8-12, comprises a soap or other detergent, monopersulphuric acid or at least one alkali-metal monopersulphate and at least one alkaline water-soluble extender and contain 30-700 parts per million of active oxygen, calculated on the weight of the solution. Suitable alkaline extenders are meta- and ortho-silicates, tripolyphosphates, pyro-, ortho- and meta-phosphates, normal carbonates, bicarbonates and sesqui-carbonates. The alkali metal monopersulphates may contain the corresponding sulphates and bisulphates in the mole ratios of MHSO5:MHSO4:M2SO4 of 2:1:1. The compositions, which preferably contain at least 1% of active oxygen, may also contain anti-caking agents, e.g. magnesium oxide, hydroxide or carbonate. Specifications 172,667 and 797,701 are referred to.ALSO:A solid oxidising composition which, when dissolved in water may be used for bleaching fibrous materials, e.g. cotton, wool, linen, silk and polyester fibres, comprises at least one alkali-metal monopersulphate and at least one of the following alkaline water-soluble extenders, i.e. alkali-metal phosphates, silicates and carbonates, with or without at least one alkaline watersoluble boron compound, e.g. borax, in amount not exceeding the total weight of phosphate, silicate and carbonate extender, the proportions of the components being such that, when the composition is dissolved in water, the resulting solution has a pH of. 8-12. The aqueous bleaching solutions which have pH values of 8-12, comprise monopersulphuric acid or at least one alkali-metal monopersulphate and at least one alkaline water-soluble extender and contain 30-700 parts per million of active oxygen, calculated on the weight of the solution. Suitable alkaline extenders are meta- and ortho-silicates, tripolyphosphates, pyro-, ortho- and meta-phosphates, normal carbonates, bicarbonates and sesqui-carbonates. The alkali-metal monopersulphates may contain the corresponding sulphates and bisulphates in the mole ratios of MHSO5 : MHSO4 M2SO4 of 2 : 1 : 1. The compositions, which preferably contain at least 1% of active oxygen, may also contain anticaking agents, e.g. magnesium oxide, hydroxide or carbonate, and a soap, e.g. the sodium or potassium salts of fatty acids, or other detergent, e.g. sodium hydrocarbon sulphonates. The fibres may be treated with the aqueous bleaching solution at a temperature between 120 DEG F. and the boiling point of the solution. Specifications 172,667 and 797,701 are referred to.
GB7765/59A 1959-03-05 1959-03-05 Improvements in or relating to solid oxidizing compositions and solutions containing monopersulphate ions Expired GB884748A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB7765/59A GB884748A (en) 1959-03-05 1959-03-05 Improvements in or relating to solid oxidizing compositions and solutions containing monopersulphate ions
FR790249A FR1221393A (en) 1959-03-05 1959-03-24 Monopersulfate based bleaches

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB7765/59A GB884748A (en) 1959-03-05 1959-03-05 Improvements in or relating to solid oxidizing compositions and solutions containing monopersulphate ions

Publications (1)

Publication Number Publication Date
GB884748A true GB884748A (en) 1961-12-13

Family

ID=9839289

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7765/59A Expired GB884748A (en) 1959-03-05 1959-03-05 Improvements in or relating to solid oxidizing compositions and solutions containing monopersulphate ions

Country Status (1)

Country Link
GB (1) GB884748A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4475984A (en) * 1981-08-17 1984-10-09 International Paper Co. Process for pretreating wood chips with monoperoxy sulfuric acid or its salts prior to alkaline pulping
US5183473A (en) * 1991-04-26 1993-02-02 Monsanto Company Enzyme activated peroxydisulfate bleach composition
US12054689B2 (en) 2020-03-16 2024-08-06 Chemische Fabrik Budenheim Kg Composition for lubricating and/or descaling during hot working of metals

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4475984A (en) * 1981-08-17 1984-10-09 International Paper Co. Process for pretreating wood chips with monoperoxy sulfuric acid or its salts prior to alkaline pulping
US5183473A (en) * 1991-04-26 1993-02-02 Monsanto Company Enzyme activated peroxydisulfate bleach composition
US12054689B2 (en) 2020-03-16 2024-08-06 Chemische Fabrik Budenheim Kg Composition for lubricating and/or descaling during hot working of metals

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