GB879269A - Process for the reaction of halogen-containing organic aluminium compounds with olefines - Google Patents
Process for the reaction of halogen-containing organic aluminium compounds with olefinesInfo
- Publication number
- GB879269A GB879269A GB6362/59A GB636259A GB879269A GB 879269 A GB879269 A GB 879269A GB 6362/59 A GB6362/59 A GB 6362/59A GB 636259 A GB636259 A GB 636259A GB 879269 A GB879269 A GB 879269A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- olefines
- cyclohexene
- reaction
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 3
- 150000001399 aluminium compounds Chemical class 0.000 title abstract 2
- 229940077746 antacid containing aluminium compound Drugs 0.000 title 1
- 229910052736 halogen Inorganic materials 0.000 title 1
- 150000002367 halogens Chemical class 0.000 title 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 3
- 239000005977 Ethylene Substances 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910000091 aluminium hydride Inorganic materials 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 2
- NEFDOOJYBCQHHV-UHFFFAOYSA-N 1-hexylcyclohexene Chemical compound CCCCCCC1=CCCCC1 NEFDOOJYBCQHHV-UHFFFAOYSA-N 0.000 abstract 1
- JVPPGMNHTVHMES-UHFFFAOYSA-N 4-butylcyclohexene Chemical compound CCCCC1CCC=CC1 JVPPGMNHTVHMES-UHFFFAOYSA-N 0.000 abstract 1
- CFOHRCNONSEVOJ-UHFFFAOYSA-N 4-ethylcyclohexene Chemical compound CCC1CCC=CC1 CFOHRCNONSEVOJ-UHFFFAOYSA-N 0.000 abstract 1
- IMJYZXBAEQPEFK-UHFFFAOYSA-N 4-octylcyclohexene Chemical compound C(CCCCCCC)C1CC=CCC1 IMJYZXBAEQPEFK-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- IZMHKHHRLNWLMK-UHFFFAOYSA-M chloridoaluminium Chemical compound Cl[Al] IZMHKHHRLNWLMK-UHFFFAOYSA-M 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- -1 potassium halide Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/064—Aluminium compounds with C-aluminium linkage compounds with an Al-Halogen linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
- C07C1/327—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being an aluminium atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
- C07C2/88—Growth and elimination reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/54—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only starting from compounds containing carbon-to-metal bonds and followed by conversion of the -O- metal to -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ6538A DE1162368B (de) | 1958-02-28 | 1958-02-28 | Verfahren zur Umwandlung von halogenhaltigen Organoaluminiumverbindungen in halogenhaltige Aluminiumverbindungen, die andere Kohlenwasserstoffreste enthalten |
| DEZ7202A DE1170410B (de) | 1958-02-28 | 1959-03-16 | Verfahren zur Umwandlung von halogenhaltigen Organoaluminiumverbindungen in halogenhaltige Aluminiumverbindungen, die andere Kohlenwasserstoffreste enthalten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB879269A true GB879269A (en) | 1961-10-11 |
Family
ID=26003349
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6362/59A Expired GB879269A (en) | 1958-02-28 | 1959-02-24 | Process for the reaction of halogen-containing organic aluminium compounds with olefines |
| GB9153/60A Expired GB888352A (en) | 1958-02-28 | 1960-03-15 | Process for converting halogenous organic aluminium compounds into halogenous dialkylaluminium compounds with other hydrocarbon radicals |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9153/60A Expired GB888352A (en) | 1958-02-28 | 1960-03-15 | Process for converting halogenous organic aluminium compounds into halogenous dialkylaluminium compounds with other hydrocarbon radicals |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US3013043A (enExample) |
| BE (1) | BE575992A (enExample) |
| DE (1) | DE1170410B (enExample) |
| FR (1) | FR1226578A (enExample) |
| GB (2) | GB879269A (enExample) |
| NL (4) | NL121830C (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3148224A (en) * | 1961-07-24 | 1964-09-08 | American Cyanamid Co | Polymerization of conjugated diolefins using nickel complexes and metal hydrides as catalyst |
| US3238265A (en) * | 1960-09-21 | 1966-03-01 | Basf Ag | Production of oligomers of 1, 3-dienes |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1118188B (de) * | 1959-03-17 | 1961-11-30 | E H Karl Ziegler Dr | Kreislaufverfahren zur Herstellung von ª‡-Olefinen durch Umsetzung von halogenhaltigen organischen Aluminiumverbindungen mit Olefinen |
| US3277203A (en) * | 1961-04-28 | 1966-10-04 | Continental Oil Co | Process for reaction of aluminum alkyls to form olefins |
| US3349149A (en) * | 1964-10-21 | 1967-10-24 | Gulf Research Development Co | Process for preparing olefins |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1034169B (de) * | 1954-01-07 | 1958-07-17 | Dr E H Karl Ziegler Dr | Verfahren zur Herstellung von hoeheren Olefinen |
| NL103707C (enExample) * | 1954-02-01 | |||
| US2889385A (en) * | 1956-04-10 | 1959-06-02 | Exxon Research Engineering Co | Preparation of long chain olefins from aluminum trialkyl and ethylene |
-
0
- BE BE575992D patent/BE575992A/xx unknown
- NL NL249483D patent/NL249483A/xx unknown
- NL NL121962D patent/NL121962C/xx active
- NL NL236103D patent/NL236103A/xx unknown
- NL NL121830D patent/NL121830C/xx active
-
1959
- 1959-02-23 FR FR787461A patent/FR1226578A/fr not_active Expired
- 1959-02-24 GB GB6362/59A patent/GB879269A/en not_active Expired
- 1959-02-27 US US795901A patent/US3013043A/en not_active Expired - Lifetime
- 1959-03-16 DE DEZ7202A patent/DE1170410B/de active Pending
-
1960
- 1960-03-09 US US13715A patent/US3074987A/en not_active Expired - Lifetime
- 1960-03-15 GB GB9153/60A patent/GB888352A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3238265A (en) * | 1960-09-21 | 1966-03-01 | Basf Ag | Production of oligomers of 1, 3-dienes |
| US3148224A (en) * | 1961-07-24 | 1964-09-08 | American Cyanamid Co | Polymerization of conjugated diolefins using nickel complexes and metal hydrides as catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| US3074987A (en) | 1963-01-22 |
| NL121962C (enExample) | |
| GB888352A (en) | 1962-01-31 |
| FR1226578A (fr) | 1960-07-13 |
| NL121830C (enExample) | |
| US3013043A (en) | 1961-12-12 |
| NL249483A (enExample) | |
| BE575992A (enExample) | |
| NL236103A (enExample) | |
| DE1170410B (de) | 1964-05-21 |
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