GB873656A - Polymerization process and catalysts therefor - Google Patents
Polymerization process and catalysts thereforInfo
- Publication number
- GB873656A GB873656A GB12920/57A GB1292057A GB873656A GB 873656 A GB873656 A GB 873656A GB 12920/57 A GB12920/57 A GB 12920/57A GB 1292057 A GB1292057 A GB 1292057A GB 873656 A GB873656 A GB 873656A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- component
- metal
- olefines
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 8
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 12
- 229910052751 metal Inorganic materials 0.000 abstract 12
- 239000002184 metal Substances 0.000 abstract 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- 229910052749 magnesium Inorganic materials 0.000 abstract 6
- 239000000178 monomer Substances 0.000 abstract 6
- -1 halogen acids Chemical class 0.000 abstract 5
- 229910052700 potassium Inorganic materials 0.000 abstract 5
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 abstract 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 4
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 abstract 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- 125000004429 atom Chemical group 0.000 abstract 4
- 229910052793 cadmium Inorganic materials 0.000 abstract 4
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 4
- 239000003085 diluting agent Substances 0.000 abstract 4
- 150000004820 halides Chemical class 0.000 abstract 4
- 229910052736 halogen Inorganic materials 0.000 abstract 4
- 150000002430 hydrocarbons Chemical group 0.000 abstract 4
- 229910052745 lead Inorganic materials 0.000 abstract 4
- 150000002739 metals Chemical class 0.000 abstract 4
- 150000002894 organic compounds Chemical class 0.000 abstract 4
- 229910052708 sodium Inorganic materials 0.000 abstract 4
- 229910052718 tin Inorganic materials 0.000 abstract 4
- 229910052719 titanium Inorganic materials 0.000 abstract 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 4
- 229910052725 zinc Inorganic materials 0.000 abstract 4
- 229910052726 zirconium Inorganic materials 0.000 abstract 4
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 229910019929 CrO2Cl2 Inorganic materials 0.000 abstract 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052776 Thorium Inorganic materials 0.000 abstract 2
- 229910052770 Uranium Inorganic materials 0.000 abstract 2
- 229910052769 Ytterbium Inorganic materials 0.000 abstract 2
- 150000000475 acetylene derivatives Chemical class 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 229910001508 alkali metal halide Inorganic materials 0.000 abstract 2
- 150000008045 alkali metal halides Chemical class 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 229910052787 antimony Inorganic materials 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- 229910052790 beryllium Inorganic materials 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052792 caesium Inorganic materials 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 239000000470 constituent Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 230000001627 detrimental effect Effects 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 125000001153 fluoro group Chemical group F* 0.000 abstract 2
- 229910052733 gallium Inorganic materials 0.000 abstract 2
- 229910052732 germanium Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 150000004678 hydrides Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 229910052738 indium Inorganic materials 0.000 abstract 2
- 229910003480 inorganic solid Inorganic materials 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 abstract 2
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 229910052758 niobium Inorganic materials 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 150000002978 peroxides Chemical class 0.000 abstract 2
- 229920001195 polyisoprene Polymers 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 229920002102 polyvinyl toluene Polymers 0.000 abstract 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052701 rubidium Inorganic materials 0.000 abstract 2
- 229910052706 scandium Inorganic materials 0.000 abstract 2
- 229910052711 selenium Inorganic materials 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 229910052715 tantalum Inorganic materials 0.000 abstract 2
- 229910052714 tellurium Inorganic materials 0.000 abstract 2
- 229910052716 thallium Inorganic materials 0.000 abstract 2
- 150000005671 trienes Chemical class 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- 239000008096 xylene Substances 0.000 abstract 2
- 150000003738 xylenes Chemical class 0.000 abstract 2
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 abstract 1
- 229910007932 ZrCl4 Inorganic materials 0.000 abstract 1
- 125000001246 bromo group Chemical group Br* 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 abstract 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US873656XA | 1956-04-25 | 1956-04-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB873656A true GB873656A (en) | 1961-07-26 |
Family
ID=22204745
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB12920/57A Expired GB873656A (en) | 1956-04-25 | 1957-04-25 | Polymerization process and catalysts therefor |
| GB1234/61A Expired GB873663A (en) | 1956-04-25 | 1957-04-25 | Polymerization process and catalyst therefor |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1234/61A Expired GB873663A (en) | 1956-04-25 | 1957-04-25 | Polymerization process and catalyst therefor |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE556976A (enrdf_load_stackoverflow) |
| FR (1) | FR1187678A (enrdf_load_stackoverflow) |
| GB (2) | GB873656A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3627837A (en) * | 1968-11-25 | 1971-12-14 | Firestone Tire & Rubber Co | Grafting of preformed polymer side chains on metalated backbone polymer |
| US3817967A (en) * | 1968-02-05 | 1974-06-18 | Aquitaine Petrole | Modification of organic polymers |
| US3931126A (en) * | 1967-10-04 | 1976-01-06 | Phillips Petroleum Company | Modification of conjugated diene polymers by treatment with organolithium and n,n,n',n'-tetramethylalkylenediamine compounds |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3078263A (en) * | 1960-10-10 | 1963-02-19 | Firestone Tire & Rubber Co | New polymerization catalyst, its preparation and use |
| GB1208242A (en) * | 1968-02-03 | 1970-10-07 | Chisso Corp | Improvements in and relating to the polymerisation of alpha-olefins |
| DE2008015C3 (de) * | 1969-02-26 | 1974-02-14 | Chisso Corp., Osaka (Japan) | Verfahren zur Herstellung von Äthylenpolymerisaten |
| US4238354A (en) * | 1979-01-15 | 1980-12-09 | Phillips Petroleum Company | Polymerization of olefins |
-
0
- BE BE556976D patent/BE556976A/xx unknown
-
1957
- 1957-04-25 FR FR1187678D patent/FR1187678A/fr not_active Expired
- 1957-04-25 GB GB12920/57A patent/GB873656A/en not_active Expired
- 1957-04-25 GB GB1234/61A patent/GB873663A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3931126A (en) * | 1967-10-04 | 1976-01-06 | Phillips Petroleum Company | Modification of conjugated diene polymers by treatment with organolithium and n,n,n',n'-tetramethylalkylenediamine compounds |
| US3817967A (en) * | 1968-02-05 | 1974-06-18 | Aquitaine Petrole | Modification of organic polymers |
| US3627837A (en) * | 1968-11-25 | 1971-12-14 | Firestone Tire & Rubber Co | Grafting of preformed polymer side chains on metalated backbone polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| BE556976A (enrdf_load_stackoverflow) | |
| FR1187678A (fr) | 1959-09-15 |
| GB873663A (en) | 1961-07-26 |
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