GB871424A - Polymerisation catalyst combinations - Google Patents
Polymerisation catalyst combinationsInfo
- Publication number
- GB871424A GB871424A GB25908/59A GB2590859A GB871424A GB 871424 A GB871424 A GB 871424A GB 25908/59 A GB25908/59 A GB 25908/59A GB 2590859 A GB2590859 A GB 2590859A GB 871424 A GB871424 A GB 871424A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- aniline
- toluidine
- xylidine
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Polymerization catalysts are prepared by treating solutions of Mn, Co, Co-Mn or Co-Mn-Pb salts of a -alkylalkanoic acids or of cycloaliphatic carboxylic acids (the carboxyl group being attached to a ring-carbon atom) with air or oxygen in the presence of light, and combining the product with an aromatic amine, optionally using as solvent a polymerizable mono-olefinic hydrocarbon such as styrene, or an ether such as isopropyl ether or tetrahydrofuran; a mixture of the latter with xylene may also be used. Suitable amines are aniline, ptoluidine, xylidine, monomethylaniline, monoethyl-aniline or -toluidine, dimethyl-aniline-xylidine or -p-toluidine, or diethylaniline. Specified parent acids of the said salts are trimethylacetic, a -methyl- and a : a -dimethyl-butyric, a : a -dimethylvaleric, hexahydrobenzoic and naphthenic acids and octoic (a -methylheptoic + a -ethylcaproic + a -n-propylvaleric) and nonoic (a -methylcaprylic + a -ethylheptoic + a -n-propylcaproic) acids. In examples a polyester solution derived from maleic and phthalic acids, ethylene glycol and diglycol, in styrene is hardened. Other unsaturated resins mentioned are those derived from (a) unsaturated polyesters from a : b -ethylene dicarboxylic acids (e.g. maleic, fumaric and itaconic acids) and (b) polymerizable ethylene derivatives such as styrene, nuclear substituted styrenes, divinyl benzene, acrylic or methacrylic acid esters or amides, esters of vinyl or alkyl alcohol and vinyl ketones. Specification 757,989 is referred to.ALSO:Polymerization catalysts are prepared by treating solutions of Mn, Co, Co-Mn or Co-Mn-Pb salts of a -alkylalkanoic acids or of cycloaliphatic carboxylic acids (the carboxyl group being attached to a ring-carbon atom) with air or oxygen in the presence of light, and combining the product with an aromatic amine, optionally using as solvent a polymerizable mono-olefinic hydrocarbon such as styrene, or an ether such as isopropyl ether or tetrahydrofuran; a mixture of the latter with xylene may also be used. Suitable amines are aniline, p-toluidine, xylidine, monomethyl-aniline, monoethyl-aniline or-toluidine, dimethyl-aniline, -xylidine or -p-toluidine, or diethylaniline. Specified parent acids of the said salts are trimethylacetic, a -methyl- and a : a -dimethylbutyric, a :a -dimethylvaleric, hexahydrobenzoic and naphthenic acids and octoic (a -methylheptoic + a -ethylcaproic + a -n-propylvaleric) and nonoic (a -methylcaprylic + a -ethylheptoic + a -n-propylcaproic) acids. Specification 757,989 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE871424X | 1958-08-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB871424A true GB871424A (en) | 1961-06-28 |
Family
ID=6813408
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB25908/59A Expired GB871424A (en) | 1958-08-05 | 1959-07-28 | Polymerisation catalyst combinations |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE581239A (en) |
CA (1) | CA637741A (en) |
FR (1) | FR1242899A (en) |
GB (1) | GB871424A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5268436A (en) * | 1988-08-31 | 1993-12-07 | Henkel Kommanditgesellschaft Auf Aktien | Radically polymerizable multi-component mixtures and their use (I) |
US5354821A (en) * | 1988-08-31 | 1994-10-11 | Henkel Kommanditgesellschaft Auf Aktien | Radically polymerizable multicomponent mixtures and their use (III) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3829461A1 (en) * | 1988-08-31 | 1990-04-26 | Henkel Kgaa | NEW RADICALLY POLYMERIZABLE MULTIPURPOSE MIXTURES AND THEIR USE (II) |
-
0
- CA CA637741A patent/CA637741A/en not_active Expired
- BE BE581239D patent/BE581239A/xx unknown
-
1959
- 1959-07-28 GB GB25908/59A patent/GB871424A/en not_active Expired
- 1959-08-04 FR FR801949A patent/FR1242899A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5268436A (en) * | 1988-08-31 | 1993-12-07 | Henkel Kommanditgesellschaft Auf Aktien | Radically polymerizable multi-component mixtures and their use (I) |
US5354821A (en) * | 1988-08-31 | 1994-10-11 | Henkel Kommanditgesellschaft Auf Aktien | Radically polymerizable multicomponent mixtures and their use (III) |
Also Published As
Publication number | Publication date |
---|---|
FR1242899A (en) | 1960-10-07 |
CA637741A (en) | 1962-03-06 |
BE581239A (en) | 1900-01-01 |
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