GB869079A - Improvements in the production of n-substituted polyamides - Google Patents
Improvements in the production of n-substituted polyamidesInfo
- Publication number
- GB869079A GB869079A GB22876/59A GB2287659A GB869079A GB 869079 A GB869079 A GB 869079A GB 22876/59 A GB22876/59 A GB 22876/59A GB 2287659 A GB2287659 A GB 2287659A GB 869079 A GB869079 A GB 869079A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lactam
- acid
- ethyl
- oenanthic
- caprylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
Polyamides are made by heating a lactam of an omega-aminocarboxylic acid with 8 to 13 ring members and which is substituted on nitrogen by an alkyl group or an alkenyl group containing only one ethylenic double bond, the total number of carbon atoms in said substituent being from one to six at 200 DEG C. to 300 DEG C. in the presence of 0,1%-5% by weight, based on the monomer, of a neutral or acid polymerization catalyst. Specified lactams are N-methyl-oenanthic lactam, N-ethyl-oenanthic lactam, N-methylcaprylic lactam, N-ethyl caprylic lactam, N-methyl lauric lactam and said lactams substituted on the nitrogen atom by propyl, butyl, isobutyl, isoamyl, hexyl, vinyl, allyl, crotryl or methallyl groups. Specified catalysts are phosphoric acid, sulphuric acid, hydrobromic acid, hexamethylene diammonium adipate, octamethylene diammonnium sebacate, o -aminocaproic acid and water. The examples describe the preparation of polyamides from: (1), (7) and (8) N-methyl caprylic lactam; (2) and (3) N-ethyl-caprylic lactam; (4) and (5) N-ethyl-oenanthic lactam; (9) N-butyl-caprylic lactam and (10) n-butyl-oenanthic lactam; exemplified catalysts being phosphoric acid, pyrophosphoric acid, hexamethylene diammonium adipate and water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE869079X | 1958-07-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB869079A true GB869079A (en) | 1961-05-31 |
Family
ID=6802773
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22876/59A Expired GB869079A (en) | 1958-07-05 | 1959-07-03 | Improvements in the production of n-substituted polyamides |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB869079A (en) |
NL (1) | NL240839A (en) |
-
0
- NL NL240839D patent/NL240839A/xx unknown
-
1959
- 1959-07-03 GB GB22876/59A patent/GB869079A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL240839A (en) |
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