GB867820A - A process for reducing the tendency of synthetic filaments, fibres and foils to become electrostatically charged - Google Patents
A process for reducing the tendency of synthetic filaments, fibres and foils to become electrostatically chargedInfo
- Publication number
- GB867820A GB867820A GB40836/59A GB4083659A GB867820A GB 867820 A GB867820 A GB 867820A GB 40836/59 A GB40836/59 A GB 40836/59A GB 4083659 A GB4083659 A GB 4083659A GB 867820 A GB867820 A GB 867820A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphate
- ethyl
- amido
- foils
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011888 foil Substances 0.000 title abstract 5
- -1 phosphoric acid ester chlorides Chemical class 0.000 abstract 7
- 229910019142 PO4 Inorganic materials 0.000 abstract 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 4
- 239000010452 phosphate Substances 0.000 abstract 4
- PTMHPRAIXMAOOB-UHFFFAOYSA-L phosphoramidate Chemical compound NP([O-])([O-])=O PTMHPRAIXMAOOB-UHFFFAOYSA-L 0.000 abstract 4
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- YJFDLEWEPGRDPB-UHFFFAOYSA-N N,N-dicyclohexyl-ethoxyphosphonamidic acid Chemical compound C1CCCCC1N(P(O)(=O)OCC)C1CCCCC1 YJFDLEWEPGRDPB-UHFFFAOYSA-N 0.000 abstract 2
- XGUNFLDGVFDSAV-UHFFFAOYSA-N N,N-dicyclohexyl-phenoxyphosphonamidic acid Chemical compound C1CCCCC1N(C1CCCCC1)P(=O)(O)OC1=CC=CC=C1 XGUNFLDGVFDSAV-UHFFFAOYSA-N 0.000 abstract 2
- CQDAAYGTFXPMJA-UHFFFAOYSA-N N,N-dioctadecyl-phenoxyphosphonamidic acid Chemical compound CCCCCCCCCCCCCCCCCCN(CCCCCCCCCCCCCCCCCC)P(=O)(O)OC1=CC=CC=C1 CQDAAYGTFXPMJA-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- BKIOGPWOQXUBGQ-UHFFFAOYSA-N butoxy-N,N-dioctadecylphosphonamidic acid Chemical compound CCCCCCCCCCCCCCCCCCN(CCCCCCCCCCCCCCCCCC)P(O)(=O)OCCCC BKIOGPWOQXUBGQ-UHFFFAOYSA-N 0.000 abstract 2
- 229920002994 synthetic fiber Polymers 0.000 abstract 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 abstract 2
- FLZGWEQADDLRNR-UHFFFAOYSA-N (18,18-diphenyloctadecylamino)phosphonic acid Chemical compound C1=CC=C(C=C1)C(CCCCCCCCCCCCCCCCCNP(=O)(O)O)C2=CC=CC=C2 FLZGWEQADDLRNR-UHFFFAOYSA-N 0.000 abstract 1
- YDEPJCIDPOQXDF-UHFFFAOYSA-N (cyclohexylamino) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)ONC1CCCCC1 YDEPJCIDPOQXDF-UHFFFAOYSA-N 0.000 abstract 1
- NJZZWUNHIXJFJW-WAYWQWQTSA-N CCC(CC)CCCCCCC/C=C\CCCCCCCCNP(O)(O)=O Chemical compound CCC(CC)CCCCCCC/C=C\CCCCCCCCNP(O)(O)=O NJZZWUNHIXJFJW-WAYWQWQTSA-N 0.000 abstract 1
- OVJPFPQUGFCGLX-WAYWQWQTSA-N CCC(CC)CCCCCCC/C=C\CCCCCCCCOP(N)(O)=O Chemical compound CCC(CC)CCCCCCC/C=C\CCCCCCCCOP(N)(O)=O OVJPFPQUGFCGLX-WAYWQWQTSA-N 0.000 abstract 1
- ACCVTZSHDAFXLW-UHFFFAOYSA-N CCCCC(CC)C(CC)(CC)N.OP(O)(O)=O Chemical compound CCCCC(CC)C(CC)(CC)N.OP(O)(O)=O ACCVTZSHDAFXLW-UHFFFAOYSA-N 0.000 abstract 1
- MDKRHKFHBBYYQV-UHFFFAOYSA-N N,N-didodecyl-phenoxyphosphonamidic acid Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)P(=O)(O)OC1=CC=CC=C1 MDKRHKFHBBYYQV-UHFFFAOYSA-N 0.000 abstract 1
- JXDTXONJCLLPCB-UHFFFAOYSA-N N-diethoxyphosphoryl-2-ethylhexan-1-amine Chemical compound C(C)C(CNP(=O)(OCC)OCC)CCCC JXDTXONJCLLPCB-UHFFFAOYSA-N 0.000 abstract 1
- KEMOLTWPSHHIPE-UHFFFAOYSA-N N-diethoxyphosphoryloctadecan-1-amine Chemical compound C(CCCCCCCCCCCCCCCCC)NP(=O)(OCC)OCC KEMOLTWPSHHIPE-UHFFFAOYSA-N 0.000 abstract 1
- UDXBFFALDXJMAM-UHFFFAOYSA-N NCCCCCCCCCCCCCCCCCC(C1=CC=CC=C1)C1=CC=CC=C1.OP(O)(O)=O Chemical compound NCCCCCCCCCCCCCCCCCC(C1=CC=CC=C1)C1=CC=CC=C1.OP(O)(O)=O UDXBFFALDXJMAM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- KUDUQECSXGZINJ-UHFFFAOYSA-N [(19-methyl-18-propan-2-ylicosyl)amino]phosphonic acid Chemical compound CC(C)C(CCCCCCCCCCCCCCCCCNP(=O)(O)O)C(C)C KUDUQECSXGZINJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 abstract 1
- OXFFWPYPQJHITJ-UHFFFAOYSA-N ethoxy-N,N-dioctadecylphosphonamidic acid Chemical compound C(C)OP(O)(=O)N(CCCCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCCCC OXFFWPYPQJHITJ-UHFFFAOYSA-N 0.000 abstract 1
- SAZWYANVPYDMLE-UHFFFAOYSA-N n-diphenoxyphosphorylcyclohexanamine Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)NC1CCCCC1 SAZWYANVPYDMLE-UHFFFAOYSA-N 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Amidophosphoric acid esters of the general formulae: <FORM:0867820/IV (b)/1> <FORM:0867820/IV (b)/2> in which R and R1 each represent an alkyl, aryl, aralkyl or hydroaryl radical, which are used in the antistatic treatment of synthetic fibres and foils (see Group IV(c)) are prepared by reacting phosphoric acid ester chlorides with primary or secondary amines at a temperature of about 30 DEG C. in the presence of a chlorinated hydrocarbon, e.g. carbon tetrachloride or chloroform, and pyridine. Specified amido phosphoric acid esters are dimethylstearyl amido phosphate, diethyloleyl amidophosphate, diethyl - 2 - ethylhexylamide-phosphate, diisopropylstearyl amido phosphate, ethyl distearylamido phosphate, ethyl 6 di-(coconut-amido)-phosphate, ethyldicyclohexyl-amido-phosphate, diphenylstearylamide phosphate, diphenyl cyclohexylamino phosphate, ethyl di(mono-2-ethyl-hexyl) amido phosphate, ethyl di(di-2-ethylhexyl-) amido phosphate, butyldistearylamidophosphate, phenyldistearylamido-phosphate, phenyldilaurylamido phosphate and phenyldicyclohexylamidophosphate.ALSO:Synthetic filaments, fibres and foils are treated with an amidophosphoric acid ester of the general formula:- <FORM:0867820/IV(c)/1> in which R and R1 each represent an alkyl, aryl, aralkyl or hydroaryl radical, to reduce their tendency to become electrostatically charged. Specified amidophosphoric acid esters are diethyl stearylamidophosphate, diethyloleylamidophosphate, diethyl- 2-ethylhexylamidophosphate, diethyldi- 2-ethylhexylamidophosphate, di-isopropylstearylamidophosphate, ethyldistearylamidophosphate, ethyldi(coconutamido) phosphate, ethyldicyclohexylamidophosphate, diphenylstearylamidophosphate, diphenylcyclohexylamidophosphate, ethyldi(mono- 2-ethyl-hexyl) amidophosphate, ethyl-di-(di-2-ethyl-hexyl) amidophosphate, butyldistearylamidophosphate, phenyldistearylamidophosphate, phenyldilaurylamidophosphate and phenyldicyclohexylamidophosphate. The amidophosphoric acid esters may be applied in solution in an alcohol, e.g. ethanol, or benzene at a temperature of 40 DEG -60 DEG C. in amount of from 0,1-2% by weight, based on the weight of the dry filaments, fibres or foils. Specified synthetic fibres and foils are polyamides and polyesters.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE867820X | 1958-12-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB867820A true GB867820A (en) | 1961-05-10 |
Family
ID=6802214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB40836/59A Expired GB867820A (en) | 1958-12-13 | 1959-12-01 | A process for reducing the tendency of synthetic filaments, fibres and foils to become electrostatically charged |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB867820A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7425352B2 (en) * | 2001-10-19 | 2008-09-16 | Daikyo Chemical Co., Ltd. | Flameproofing agent for polyester-based textile product and method of flameproofing |
-
1959
- 1959-12-01 GB GB40836/59A patent/GB867820A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7425352B2 (en) * | 2001-10-19 | 2008-09-16 | Daikyo Chemical Co., Ltd. | Flameproofing agent for polyester-based textile product and method of flameproofing |
| US7588802B2 (en) | 2001-10-19 | 2009-09-15 | Daikyo Chemical Co., Ltd. | Agent and method for flame-retardant processing of polyester-based fiber products |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB830918A (en) | A method for the preparation of phosphoric acid di-alkyl ester amides | |
| GB867820A (en) | A process for reducing the tendency of synthetic filaments, fibres and foils to become electrostatically charged | |
| GB954984A (en) | Basically substituted amides and a process for preparing them | |
| GB844037A (en) | Compositions for combating rodents | |
| GB898418A (en) | Thiophosphoric acid esters | |
| GB913229A (en) | Phosphonic thionophosphonic phosphinic and thionophosphinic acid esters of ª-- and ª--naphthols and processes for their production | |
| GB845373A (en) | Dithiophosphoric acid esters and process for their production | |
| GB1474579A (en) | Brominated carbamic esters and their use as flameproofing agents | |
| GB741007A (en) | Improvements relating to triorganosilylbenzamides | |
| GB786322A (en) | Pest control agent | |
| JPS5547693A (en) | Organic phosphorus compound having 33hydroxyalkylphosphoric acid ester group* its manufacture and textile material flame retardant containing it | |
| GB831366A (en) | Improvements in and relating to new glutaconimides and their process of preparation | |
| GB849793A (en) | Substituted benzimidazoles | |
| GB890305A (en) | Amide colour couplers for colour photography | |
| ES251414A1 (en) | New iminostilbene derivatives and method of preparing them | |
| GB902365A (en) | Process of preventing electrostatic charges on synthetic polymeric textile materials | |
| GB1224552A (en) | Phosphorus-containing steroid alpha-ketol acylates | |
| GB738415A (en) | Improvements in or relating to chemo-therapeutic agents | |
| ES235178A1 (en) | Insecticides-derivatives of itaconic acid | |
| GB891654A (en) | Isocyanatoaryl esters and amides of phosphoric and thiophosphoric acids | |
| GB746552A (en) | Improvements relating to the preparation of dialkyl aminoacetyl anilides | |
| GB606192A (en) | Improvements in or relating to thiophene compounds and processes of preparing the same | |
| GB678604A (en) | New fatty acid amido-alkyl-amino ester salts and process for the production thereof | |
| GB992736A (en) | Polyamides | |
| GB912289A (en) | New basic ethers and processes for their production |