GB866971A - Polymerization method - Google Patents

Polymerization method

Info

Publication number
GB866971A
GB866971A GB238760A GB238760A GB866971A GB 866971 A GB866971 A GB 866971A GB 238760 A GB238760 A GB 238760A GB 238760 A GB238760 A GB 238760A GB 866971 A GB866971 A GB 866971A
Authority
GB
United Kingdom
Prior art keywords
reactor
stream
velocity
solution
circulating stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB238760A
Inventor
Henry Kirkpatrick Arnold
Earle Rieth Gurtler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US801936A priority Critical patent/US2999084A/en
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB238760A priority patent/GB866971A/en
Priority to DE1960E0018874 priority patent/DE1245598B/en
Publication of GB866971A publication Critical patent/GB866971A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1868Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1875Stationary reactors having moving elements inside resulting in a loop-type movement internally, i.e. the mixture circulating inside the vessel such that the upwards stream is separated physically from the downwards stream(s)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00085Plates; Jackets; Cylinders

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

<PICT:0866971/IV (a)/1> In a continuous method for the low temperature Friedel-Crafts catalyzed polymerization of an isoolefin in solution in a circulating stream in a reactor with agitation, mass fouling is inhibited by continuously injecting a solution of fresh olefinic feed into the circulating stream at a zone of maximized stream velocity and at an angle within 30 degrees of and including the direction normal to the direction of flow of said stream in the reactor and at an injection velocity equal to at least 80% of the average flow velocity in the reactor. Fig. 2 of the accompanying drawings illustrates part of a suitable apparatus for effecting the method claimed, whereby feed supply from line 48 passes to reservoir 44 and then flows into the reactor at an angle normal to the circulating stream, as shown by the arrows in the Figure.
GB238760A 1959-03-25 1960-01-22 Polymerization method Expired GB866971A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US801936A US2999084A (en) 1959-03-25 1959-03-25 Polymerization method
GB238760A GB866971A (en) 1960-01-22 1960-01-22 Polymerization method
DE1960E0018874 DE1245598B (en) 1960-01-22 1960-02-11 Process for the continuous polymerization of isoolefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB238760A GB866971A (en) 1960-01-22 1960-01-22 Polymerization method

Publications (1)

Publication Number Publication Date
GB866971A true GB866971A (en) 1961-05-03

Family

ID=9738657

Family Applications (1)

Application Number Title Priority Date Filing Date
GB238760A Expired GB866971A (en) 1959-03-25 1960-01-22 Polymerization method

Country Status (1)

Country Link
GB (1) GB866971A (en)

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