GB857387A - Tertiary amine salts of chlorinated carboxylic acids and their use as weed-killing and weed growth inhibiting agents - Google Patents

Tertiary amine salts of chlorinated carboxylic acids and their use as weed-killing and weed growth inhibiting agents

Info

Publication number
GB857387A
GB857387A GB162359A GB162359A GB857387A GB 857387 A GB857387 A GB 857387A GB 162359 A GB162359 A GB 162359A GB 162359 A GB162359 A GB 162359A GB 857387 A GB857387 A GB 857387A
Authority
GB
United Kingdom
Prior art keywords
acid
salts
methyl
salt
propionic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB162359A
Inventor
Adolf Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB857387A publication Critical patent/GB857387A/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/04—Nitrogen directly attached to aliphatic or cycloaliphatic carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises a salt of a tertiary amine of the general formula: <FORM:0857387/IV(b)/1> in which R1 represents an alkyl radical with from 8 to 18 carbon atoms and R2 and R3 represents alkyl radicals with from 1 to 7 carbon atoms with a chlorinated fatty acid other than a , a -dichloro-isovaleric acid) a chlorinated benzoic acid, 2,4-dichlorophenoxy-acetic acid, 2-methyl-4-chlorphenoxy acetic acid, 2,4-dichlorophenoxy-a -propionic acid, 2-methyl-4-chlorophenoxy-a -propionic acid or 2,4,5-trichlorophenoxyacetic acid. In a modification R2 and R3 are joined together to form an alkylene chain system containing 2 to 6 methylene groups and form a heterocyclic ring with the nitrogen atom. Additional acids specified include a , a -dichloropropionic acid, a , a -dichlorobutyric acid, a , a , b -isobutyric and butyric acids, a , a , g -trichlorobutyric acid, 2, 3, 6-tri- and 2, 3, 5, 6-tetrachloro benzoic acids. Amines specified include dodecyl, nonyl-and decyl hexamethylene imines, N-nonyl pyrrolidine-N-hexyldecylpiperidine, N-decylpyrrolidine, and dimethyloctylamine. The salts are prepared by mixing equivalent amounts of the acid and liquid amine and mixtures of several acids and amines may be reacted. The products are employed in herbicidal compositions (see Group VI). Specification 805,260 is referred to.ALSO:Herbicidal compositions comprise a salt of a tertiary amine of the general formula: <FORM:0857387/VI/1> in which R1 represents an alkyl radical with from 8 to 18 carbon atoms and R2 and R3 represent alkyl radical with 1 to 7 carbon atoms with a chlorinated fatty acid (other than a , a -dichloroisovaleric acid), a chlorinated benzoic acid, 2:4-dichlorophenoxyacetic acid, 2-methyl-4-chlorophenoxy acetic acid, 2:4-dichlorophenoxy a -propionic acid, 2 - methyl - 4 - chloro - phenoxy - a - propionic acid or 2 : 4 : 5 tri - chlorophenoxy acetic acid together with a carrier. In a modification salts of amines of the above formula wherein R2 and R3 are joined together to form an alkylene chain containing 2 to 6 methylene groups and forming a heterocyclic ring with the nitrogen atom are employed. Amine salts specified include the dodecylhexamethyleneimine salt of 2 - methyl - 4 - chlorphenoxy - a - propionic acid, dimethyloctylamine, C8 to C10 alkyl pyrrolidine and C16 to C18 alkyl piperidine salts of a mixture of 2 - methyl - 4 - chloro - phenoxy a - propionic acid and 2, 3, 5, 6 - tetrachlorobenzoic acid, the N - decylpyrrolidine salt of a , a - dichloropropionic acid, the nonylhexamethylene salt of a , a -dichlorobutyric acid and the N-dodedyl hexamethylimine salts of a , a , - dichloro - propionic acid - butyric acids. The salts may be employed in aqueous solution or mixed with any known dry inert carrier. Specification 805,260 is referred to.
GB162359A 1958-01-17 1959-01-16 Tertiary amine salts of chlorinated carboxylic acids and their use as weed-killing and weed growth inhibiting agents Expired GB857387A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB47481A DE1057382B (en) 1958-01-17 1958-01-17 Herbicides

Publications (1)

Publication Number Publication Date
GB857387A true GB857387A (en) 1960-12-29

Family

ID=6968286

Family Applications (1)

Application Number Title Priority Date Filing Date
GB162359A Expired GB857387A (en) 1958-01-17 1959-01-16 Tertiary amine salts of chlorinated carboxylic acids and their use as weed-killing and weed growth inhibiting agents

Country Status (4)

Country Link
BE (1) BE574445A (en)
DE (1) DE1057382B (en)
FR (1) FR1213313A (en)
GB (1) GB857387A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3276856A (en) * 1965-03-22 1966-10-04 Amchem Prod Herbicidal compositions
US3539613A (en) * 1964-04-15 1970-11-10 Atlas Chem Ind Plant hormone carboxylic acid salt of an aminated polyoxyethylene aliphatic amine or aliphatic alcohol

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL67490C (en) * 1944-03-18
GB751308A (en) * 1953-09-18 1956-06-27 Dow Chemical Co Trinormalbutyl amine salt of -a,-a-dichloropropionic acid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3539613A (en) * 1964-04-15 1970-11-10 Atlas Chem Ind Plant hormone carboxylic acid salt of an aminated polyoxyethylene aliphatic amine or aliphatic alcohol
US3276856A (en) * 1965-03-22 1966-10-04 Amchem Prod Herbicidal compositions

Also Published As

Publication number Publication date
FR1213313A (en) 1960-03-31
BE574445A (en)
DE1057382B (en) 1959-05-14

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