GB852663A - Improved cellular materials - Google Patents
Improved cellular materialsInfo
- Publication number
- GB852663A GB852663A GB32400/58A GB3240058A GB852663A GB 852663 A GB852663 A GB 852663A GB 32400/58 A GB32400/58 A GB 32400/58A GB 3240058 A GB3240058 A GB 3240058A GB 852663 A GB852663 A GB 852663A
- Authority
- GB
- United Kingdom
- Prior art keywords
- heated
- mixture
- moulds
- pressure
- crystalline polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/26—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/044—Elimination of an inorganic solid phase
- C08J2201/0444—Salts
- C08J2201/0446—Elimination of NaCl only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
A highly crystalline polymer of an alphaolefin, preferably polypropylene, prepared as described in the parent Specification is made cellular and, for example, rigid and porous in the following ways:-(1) The highly crystalline polymer is mixed with a blowing agent, such as dinitrosopentamethylenetetramine, azodicarbonamide or lactose, which decomposes with the evolution of a gas when heated. The mixture is made completely homogeneous by being softened e.g. at a temperature between 140 and 180 DEG C., and is then filled into moulds and heated, for example at a temperature between 140 and 180 DEG C. and is then filled into moulds and heated, for example to between 180 and 190 DEG C., to decompose the blowing agent. The mixture may be heated to 170 DEG C. under the pressure of the gas evolved, cooled until the gas achieves atmospheric pressure and then reheated to between 140 and 160 DEG C. (2) The highly crystalline polymer is mixed with a stabilizer such as 4, 4, 1-thio-bis-3-methyl-6-tertiary butyl phenol. The mixture is heated to between 190 and 200 DEG C. in a vessel containing nitrogen at a pressure of 120 to 130 atmospheres and then discharged into another vessel packed with a plurality of spirally arranged grids. In this vessel, the mixture is heated to 200 DEG C. in nitrogen at a pressure of 15 to 20 atmospheres and then discharged into moulds wherein it is heated to between 130 and 140 DEG C. for at least 20 minutes. (3) A mixture of the highly crystalline polymer and a stabilizer is pulverized and mixed with pulverized sodium chloride. The resulting mixture is filled into moulds and heated therein, for 20 minutes at 190 to 200 DEG C., in nitrogen at a pressure of 100 atmospheres. The moulds are then cooled and the castings produced are washed with water to dissolve out the sodium chloride.ALSO:A highly crystalline polymer of an alpha-olefin, preferably polypropylene, prepared as described in the parent Specification is made cellular and, for example, rigid and porous in the following ways: (1) The highly crystalline polymer is mized with a blowing agent, such as dinitrosopentamethylenetetramine, azodicarbonamide or lactose, which decomposes with the evolution of a gas when heated. The mixture is made completely homogeneous by being softened, e.g. at a temperature between 140 and 180 DEG C. and is then filled into moulds and heated, e.g. to between 180 and 190 DEG C. to decompose the blowing agent. The mixture may be heated to 170 DEG C. under the pressure of the gas evolved, cooled until the gas achieves atmospheric pressure and then reheated to between 140 and 160 DEG C. (2) The highly crystalline polymer is mixed with a stabilizer such as 4, 4, 1-thio-bis-3-methyl-6-tertiary butyl phenol. The mixture is heated to between 190 and 200 DEG C. in a vessel containing nitrogen at a pressure of 120 to 130 atmospheres and then discharged into another vessel packed with a plurality of spirally arranged grids. In this vessel, the mixture is heated to 200 DEG C. in nitrogen at a pressure of 15 to 20 atmospheres and then discharged into moulds wherein it is heated to between 130 and 140 DEG C. for at least 20 minutes. (3) A mixture of the highly crystalline polymer and a stabilizer is pulverised and mixed with pulverised sodium chloride. The resulting mixture is filled into moulds and heated therein, for 20 minutes at 190 to 200 DEG C. in nitrogen at a pressure of 100 atmospheres. The moulds are then cooled and the castings produced are washed with water to dissolve out the sodium chloride.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT852663X | 1958-03-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB852663A true GB852663A (en) | 1960-10-26 |
Family
ID=11327020
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB32400/58A Expired GB852663A (en) | 1958-03-13 | 1958-10-10 | Improved cellular materials |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB852663A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1285722B (en) * | 1964-09-09 | 1968-12-19 | Basf Ag | Process for the production of finely divided foam-shaped olefin polymers |
-
1958
- 1958-10-10 GB GB32400/58A patent/GB852663A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1285722B (en) * | 1964-09-09 | 1968-12-19 | Basf Ag | Process for the production of finely divided foam-shaped olefin polymers |
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