GB846634A - Lubricating oils and process of preparing the same - Google Patents

Lubricating oils and process of preparing the same

Info

Publication number
GB846634A
GB846634A GB24173/58A GB2417358A GB846634A GB 846634 A GB846634 A GB 846634A GB 24173/58 A GB24173/58 A GB 24173/58A GB 2417358 A GB2417358 A GB 2417358A GB 846634 A GB846634 A GB 846634A
Authority
GB
United Kingdom
Prior art keywords
sulphide
hydrogen
oil
viscosity
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24173/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Research and Development Co
Original Assignee
Gulf Research and Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gulf Research and Development Co filed Critical Gulf Research and Development Co
Publication of GB846634A publication Critical patent/GB846634A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104—Aromatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027—Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/086—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing sulfur atoms bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A multi-grade lubricating oil is produced by treating a deasphalted residuum having a V.I. between 75 and 100 and a viscosity at 99 DEG C. of between 90 and 200 S.U.S. with hydrogen at a temperature between 391 DEG C. and 441 DEG C. at a pressure above 175 kgs. per sq. cm. at a space velocity between 0.4 and 1.5 v/v/hr. and in the presence of a catalyst which promotes aromatic hydrogenation and ring sciosion and subjecting the product from the hydrogen treatment to distillation to separate fractions having a viscosity index of at least 115 and within the maximum and minimum viscosity limits for a multi-grade lubricating oil, i.e. an oil which has the minimum and maximum viscosities for two or more viscosity grades of oil ordinarily used in automotive or internal combustion engines at different times of the year or at different temperatures. The fuel is preferably obtained by vacuum distillation of a Pennsylvania, Mid-continent, West Texas, or Kuwait crude and subsequent deasphalting with a low-boiling hydrocarbon such as propane, propylene or butane, or less satisfactorily with sulphuric acid, phenol or sulphur dioxide. The catalyst employed for the hydrogenation may be a sulphide of any metal of the Group VI left hand column of the Periodic System mixed with a sulphide of an iron metal group. Specified catalysts are molybdenum sulphide, tungsten sulphide or chromium sulphide mixed with a sulphide of iron, cobalt or nickel. Dewaxing may be effected before or after the hydrogenation step using a solvent such as methyl ethyl ketone, toluene or propane and cooling and filtering off the wax. Additives which may be blended with the product include Acryloid, a detergent comprising a mixture of barium thiophenate and calcium sulphonate, zinc dialkyl dithiophosphate, metal phenates, metal naphthenates, alkylated phenols and P2S5-terpene reaction products. In a typical Example, (No. 1) an Ordovician reduced enide was deasphalted and preheated to 382 DEG C. and passed over a mixed nickel sulphide-tungsten sulphide catalyst at 393 DEG C. and 0.5 liquid hourly space velocity, using 140 standard cubic metres of hydrogen per barrel. The product after a high pressure separation of hydrogen was topped at atmospheric pressure and fractionated to remove a gasoline and furnace oil. The remainder was dewaxed with methyl ethyl ketone and then 10 W/20 and 20 W/30 multi-grade oils separated.
GB24173/58A 1957-08-02 1958-07-28 Lubricating oils and process of preparing the same Expired GB846634A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US676039A US2960458A (en) 1957-08-02 1957-08-02 Process for preparing a multi-grade lubricating oil and product

Publications (1)

Publication Number Publication Date
GB846634A true GB846634A (en) 1960-08-31

Family

ID=24712974

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24173/58A Expired GB846634A (en) 1957-08-02 1958-07-28 Lubricating oils and process of preparing the same

Country Status (3)

Country Link
US (1) US2960458A (en)
BE (1) BE569980A (en)
GB (1) GB846634A (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3078238A (en) * 1959-07-24 1963-02-19 Gulf Research Development Co Hydrogenation catalyst and method of preparation
US3078221A (en) * 1959-07-24 1963-02-19 Gulf Research Development Co Hydrogenation process for preparation of lubricating oils
US3046218A (en) * 1959-08-10 1962-07-24 Gulf Research Development Co Process for preparing an improved lubricating oil
US3078222A (en) * 1960-07-27 1963-02-19 Gulf Research Development Co Preparation of multi-grade lubricating oil by severe hydrogenation and urea adduction
US3142634A (en) * 1961-12-14 1964-07-28 Socony Mobil Oil Co Inc Preparation of multi-grade lubricating oil
US3328287A (en) * 1966-06-02 1967-06-27 Mobil Oil Corp Production of lubricating oils from resin extracts
US3617484A (en) * 1968-11-29 1971-11-02 Sun Oil Co Increasing the v.i. of hydrocracked light lubes
US3619414A (en) * 1969-02-19 1971-11-09 Sun Oil Co Catalytic hydrofinishing of petroleum distillates in the lubricating oil boiling range
US3617482A (en) * 1969-11-10 1971-11-02 Chevron Res Process for the production of lubricating oils
US3902989A (en) * 1970-01-14 1975-09-02 Mobil Oil Corp Method for producing hydrocracked lube oil products
US3617475A (en) * 1970-01-15 1971-11-02 Gulf Research Development Co Process for producing lubricating oils with good low temperature hazing properties
US3730876A (en) * 1970-12-18 1973-05-01 A Sequeira Production of naphthenic oils
GB1402821A (en) * 1973-02-09 1975-08-13 British Petroleum Co Production of lubricating oils
US3852207A (en) * 1973-03-26 1974-12-03 Chevron Res Production of stable lubricating oils by sequential hydrocracking and hydrogenation
US20030096713A1 (en) * 1994-04-19 2003-05-22 Eric R. Schnur Lubricating compositions with improved oxidation resistance containing a dispersant and an antioxidant

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2554282A (en) * 1946-09-12 1951-05-22 Standard Oil Dev Co Lubricating oil manufacture
US2779711A (en) * 1955-02-28 1957-01-29 Standard Oil Co Refining of lubricating oils
US2787582A (en) * 1955-04-12 1957-04-02 Universal Oil Prod Co Production of lubricating oils
US2904505A (en) * 1955-06-16 1959-09-15 Texaco Inc Mild hydrogenation process for lubricating oils

Also Published As

Publication number Publication date
US2960458A (en) 1960-11-15
BE569980A (en)

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